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Long Column (long + column)

Distribution by Scientific Domains

Chemistry	42%
Engineering	28%

Selected Abstracts

Modelling of cement suspension flow in granular porous media

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 7 2005
Z. Saada
Abstract A theoretical model of cement suspensions flow in granular porous media considering particle filtration is presented in this paper. Two phenomenological laws have been retained for the filtration rate and the intrinsic permeability evolution. A linear evolution with respect to the volume fraction of cement in the grout has been retained for the filtration rate. The intrinsic permeability of the porous medium is looked for in the form of a hyperbolic function of the porosity change. The model depends on two phenomenological parameters only. The equations of this model are solved analytically in the one-dimensional case. Besides, a numerical resolution based on the finite element method is also presented. It could be implemented easily in situations where no analytical solution is available. Finally, the predictions of the model are compared to the results of a grout injection test on a long column of sand. Copyright © 2005 John Wiley & Sons, Ltd. [source]

Gas Classification of Particles Using a Packed Bed

PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, Issue 4 2008
Wei Yang
Abstract Gas classification of particles using a packed bed is, for the first time, proposed and tested for two materials, i.e., glass ballotini and microcrystalline cellulose (MCC). A 2,m long column with 9.5,mm diameter is packed with 2,mm spherical particles. The particles to be classified are injected into the inlet of the packed bed by a carrier gas. Measurements of the breakthrough curves of the particles are carried out at the outlet of the packed bed. The results show that the particle elution order is particle size dependent with large particles elutriated faster than small ones. Taking the particle size into account, the retention time of irregular MCC particles is much longer than that of spherical glass beads and the difference is attributed to the particle shape and cohesiveness. Based on the findings, binary mixtures of both, glass and MCC beads are injected into the packed bed for the classification experiments. The results show different dependence on the superficial gas velocity of the particle classification efficiency. The particle classification efficiency of glass particles increases with decreasing superficial gas velocity, whereas that of MCC particles increases with increasing superficial gas velocity. [source]

Structure of d(GCGAAAGC) (hexagonal form): a base-intercalated duplex as a stable structure

ACTA CRYSTALLOGRAPHICA SECTION D, Issue 1 2004
d(GCGAAAGC)
A DNA fragment d(GCGAAAGC), postulated to adopt a stable mini-hairpin structure on the basis of its extraordinary properties, has been X-ray analyzed. Two octamers related by a crystallographic twofold symmetry are aligned in an antiparallel fashion and associate to form a duplex, which is maintained by two Watson,Crick G·C base pairs and a subsequent sheared G·A pair at both ends. The central two A residues are free from base-pair formation. The corresponding base moieties of the two strands are intercalated and stacked on each other, forming a long column of G1 -C2 -G3 -A4 -A -A5 -A -G -C -G (asterisks indicate the counter-strand). The Watson,Crick and major-groove sites of the four stacked adenine bases are exposed to the solvent region, suggesting a functional role. Since this structural motif is similar to those found in the nonamers d(GBrCGAAAGCT) and d(GICGAAAGCT), the base-intercalated duplex may be a stable form of the specific sequence. Electrophoresis results suggest that the octamer has two states, monomeric and dimeric, in solution depending on the Mg2+ concentration. The present duplex is preferred under the crystallization conditions, which correspond to physiologically allowed conditions. [source]

Preparation of a super-long two column chromatography system and its application in separating glycosylated puerarin

BIOMEDICAL CHROMATOGRAPHY, Issue 12 2009
Shouchuang Zhu
Abstract Separation of Puerarin-7- O -glucoside from its precursor, puerarin, using a common chromatography column packed with AB-8 macroporous resin was unsuccessful. Therefore, in this study a 8,m super-long flexible reinforced PVC column was externally added to the common column in order to improve the chromatography efficiency by increasing the number of theoretical plates. Both the PVC and common columns were separately packed with AB-8 macroporous resin slurry. The packed PVC column was coiled after washing and stored until use. The microbial transformation mixture with puerarin-7- O -glucoside and puerarin (250,mL) was loaded onto the common column, followed by washing with 2000,mL H2O. After attaching the coiled external PVC column to the common column, a linear gradient of 10,30% ethanol was applied to elute the target compound. Two peaks appeared: peak I contained puerarin-7- O -glucoside at 97.9% purity and 88.1% recovery rate, and peak II was puerarin at 98.7% purity and 87.0% recovery rate. The use of the coiled external flexible reinforced PVC column avoided spatial restriction for long columns, which made it much more convenient for column packing and chromatography operations. Furthermore, this method eliminated the resin blockage problem caused by stationary water pressure in a rigid vertical long column. Using an external super-long column, the PVC tube was connected with the common column only during elution, which avoided delay in time period during sample loading and column washes associated with the use of long external columns. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Heavy-metal displacement in chelate-treated soil with sludge during phytoremediation

JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 6 2006
Stanley Liphadzi
Abstract Heavy metals (HMs) in domestic sewage sludge, applied to land, contaminate soils. Phytoremediation is the use of plants to clean-up toxic HMs from soil. Chelating agents are added to soil to solubilize the metals for enhanced uptake. Yet no studies report the displacement of HMs in soil with sludge following solubilization with chelates. The objective of this work was to determine the uptake or leaching of HMs due to a chelate added to a soil from a sludge farm that had received sludge for 25 y. The soil was placed in long columns (105,cm long; , 39,cm) in a greenhouse. Columns either had a plant (hybrid poplar; Populus deltoides Marsh. × P. nigra L.) or no plant. After the poplar seedlings had grown for 144 d, the tetrasodium salt of the chelating agent EDTA was irrigated onto the surface of the soil at a rate of 1 g per,kg of soil. Drainage water, soil, and plants were analyzed for three toxic HMs (Cd, Ni, Pb) and four essential HMs (Cu, Fe, Mn, Zn). At harvest, extractable and total concentrations of each HM in the soil with EDTA were similar to those in soil without EDTA. The chelate did not affect the concentrations of HMs in the roots or leaves. With or without plants, EDTA mobilized all seven HMs and increased their concentrations in drainage water. Lower concentrations of Cd, Cu, Fe, Ni, and Zn in leachate from columns with EDTA and plants compared to columns with EDTA and no plants showed that poplars can reduce groundwater contamination by intercepting these HMs in the soil. But the poplar plants did not reduce Pb and Mn in the leachate from columns with EDTA. Concentrations of Cd and Pb in the leachate mobilized by EDTA remained above drinking-water standards with or without plants. The results showed that a chelate (EDTA) should not be added to a soil at a sludge farm to enhance phytoremediation. The chelate mobilized HMs that leached to drainage water and contaminated it. [source]

Verstärken von Stahlbetonstützen mit textilbewehrtem Beton

BETON- UND STAHLBETONBAU, Issue 10 2009
Regine Ortlepp Dr.-Ing.
Versuche; Bewehrung Abstract Der Aufsatz beschreibt die Ergebnisse experimenteller Untersuchungen zur Wirkung einer Textilbetonverstärkung an 2 m langen Stützen mit und ohne innen liegender Stahlbewehrung. Die Verstärkung mit textilbewehrtem Beton wurde auf zwei verschiedene Weisen ausgeführt, sowohl als vollständige Umwicklung über die gesamte Länge der Stützen als auch als teilweise Verstärkung über eine Länge von 30 cm in den Lasteinleitungsbereichen. Die einzelnen Anteile am Tragverhalten der verstärkten Stützen wurden untersucht. Ein einfaches Berechnungsmodell wird angegeben. Strengthening of Columns using Textile Reinforced Concrete (TRC) In the context of rehabilitation and repair works or in the course of usage changes of existing buildings the planning engineer frequently is confronted with the task of strengthening the loadbearing structure. This can become necessary, for example, if live loads are increased because of changes of use or if the structural safety of a building must be restored after a fire or earthquake. Particularly columns represent important components and elements of the static system for many buildings, whose main task is bearing normal forces. The results of experimental tests on the effect of a strengthening from textile reinforced concrete at 2 m long columns, both with and without internal steel reinforcement, are described in this article. The strengthening with textile reinforced concrete was made both wrapping round completely along the full height of the columns and partly wrapping round the columns along 300 mm in the load introduction ranges. Related to the unstrengthened reference columns ultimate load increasings by up to 85% could thereby be achieved. The individual components of the load bearing properties are analysed. A simple calculation model is indicated. [source]