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Linear Alcohols (linear + alcohol)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

Titelbild: High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System (Angew. Chem.

ANGEWANDTE CHEMIE, Issue 26 2010
26/2010)
Ein Volleyball fliegt von der akademischen zur industriellen Seite des Netzes als Symbol für die potenzielle Nützlichkeit eines neuen dualen Katalysatorsystems , einer Kombination aus Xantphos/[Rh(acac)(CO)2] und dem Shvo-Katalysator , auf beiden Gebieten. In der Zuschrift auf S.,4590,ff. beschreiben K. Nozaki et,al. die hoch effiziente Erzeugung von n -Undecanol aus Synthesegas mit diesem Katalysatorsystem. Das Eintopfverfahren umfasst eine rhodiumkatalysierte Hydroformylierung und eine rutheniumkatalysierte Hydrierung. [source]

High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System,

ANGEWANDTE CHEMIE, Issue 26 2010
Kohei Takahashi
Beim Test dualer Katalysatorsysteme für die Tandemsequenz aus Hydroformylierung und Hydrierung zur einstufigen Herstellung von n -Undecanol aus 1-Decen ergab die Kombination von Xantphos/[Rh(acac)(CO)2] mit dem Shvo-Katalysator 1 das beste Resultat (siehe Schema; acac=Acetylacetonat, DMA=N,N -Dimethylacetamid). Der Einsatz polarer Lösungsmittel verhindert die Bildung von Undecylformiat. [source]

Solvent Effects on Catalytic Epoxidation of Alkenes by Tetra- n -butylammonium Periodate and (Tetraarylporphyrinato)manganese(III)

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 20 2008
Daryoush Mohajer
Abstract The epoxidation of cyclooctene and cis -stilbene was performed by tetra- n -butylammonium periodate (nBu4NIO4)in the presence of (tetraarylporphyrinato)manganese(III) [Mn(por)] and imidazole (im) in various CH2Cl2/alcohol solvents (alcohol = CH3OH, C2H5OH, n -C3H7OH, i -C3H7OH, t -C4H9OH). In accord with the coordinating abilities of the alcohols to [Mn(por)], the epoxidation yields increased from CH2Cl2/CH3OH to CH2Cl2/t -C4H9OH. In the epoxidation of cis -stilbene in the presence of (acetato)(tetraphenylporphyrinato)manganese(III) [Mn(tpp)(OAc)], the cis - to trans -stilbene oxide ratio increased consistently with the bulk of the alcohol in CH2Cl2/alcohol solvents. Also, it was found that the interaction of [Mn(tpp)(OAc)] and (acetato)(tetramesitylporphyrinato)manganese(III) [Mn(tmp)(OAc)] with nBu4NIO4 in the presence of imidazole but in the absence of alkenes yields [Mn(tpp)(O)(im)]+ and [Mn(tmp)(O)(im)]+ complexes. The formation of the Mn=O species for the small linear alcohols was faster than that for the larger ones, whereas the stability of the Mn=O complex was greater in the presence of the bulkier alcohols. Attempts were made to explain these effects.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]

2,3-Di- n -undecylanthracene and 2,3-Di- n -decyloxyanthracene (DDOA) , on the Connecting Link between the Aromatic Substrate and the Aliphatic Chain in Self-Assembling Systems

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 12 2009
Henning Hopf
Abstract In contrast to its bis(oxa) analog 1 (DDOA), the hydrocarbon 11 was not found to form organogels with linear alcohols, alkanes, toluene, acetonitrile and other solvents. Whereas the photoreactivity of 1 did not follow the usual behaviour of anthracene derivatives, compound 11, irradiated in cyclohexane, produced the two expected [4+4]cycloadducts 12 and 13 (anti and syn photodimers, respectively). These facts point to the role of the connecting link between the rigid core and the flexible chain for some self-assembled systems.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) [source]

ZSM-11 membranes: Characterization and pervaporation performance

AICHE JOURNAL, Issue 2 2002
Shiguang Li
High-quality boron and aluminium-substituted ZSM-11 membranes were prepared on porous tubular supports to separate alcohols from water by pervaporation. The C1,C3 alcohols were preferentially separated from aqueous solutions through the B-ZSM-11 membrane, and the maximum flux was 1.7 kg/m2·h for a 5 wt.% methanol/water mixture. The alcohol fluxes decreased as the carbon number increased. The methanol/water separation selectivity decreased with pervaporation temperature, but other alcohol/water selectivities increased. All selectivities increased with decreasing alcohol feed concentration. In a range of 1 to 50 wt. % alcohol, the separation selectivities at 333 K for the C1,C3 linear alcohols were higher than vapor/liquid equilibrium selectivities. The highest selectivities observed for methanol/water, ethanol/water, 1-propanol/water, and 2-propanol/water were 28, 97, 34, and 26, respectively, at 1 wt. % alcohol feed concentrations. The separation selectivities were based on both preferential adsorption of alcohols and differences in diffusion rates. [source]