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Liquid Mass Transfer (liquid + mass_transfer)
Selected AbstractsMass Transfer in a Flat Gas/Liquid Interface using non-Newtonian MediaCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 10 2003D. Gómez-Díaz Abstract Gas/liquid mass transfer has been investigated using a stirred vessel gas/liquid contactor using non-Newtonian media and carbon dioxide as absorbent and gas phase, respectively. The volumetric mass transfer coefficients at different operational variables have been determined. Non-Newtonian media (liquid phase) were prepared as aqueous solutions of sodium carboxymethyl cellulose salt. The influence of the rheological properties, polymer concentration, stirring rate, and gas flow rate on mass transfer was studied for these liquid phases. Kinematic viscosity and density experimental data were used to calculate the average molecular weight corresponding to the polymer employed. The Ostwald model has been used to fit the rheological behavior of aqueous solutions of the polymer employed as absorbent phase. Reasonably good agreement was found between the predictions of the proposed models and the experimental data of mass transfer coefficients. [source] EFFECTS OF RETORTING AND STORAGE ON LIQUID MASS TRANSFER IN CANNED SKIPJACK (KATSUWONAS PELAMIS) MUSCLEJOURNAL OF FOOD PROCESSING AND PRESERVATION, Issue 4 2002J. W. BELL Mass loss of precooked tuna muscle during retorting and storage in cans impacts cannery yield and throughput. Changes in moisture content and mass of frozen, thawed, precooked tuna muscle chunks, canned in water, were determined after retorting and through five weeks of subsequent storage. Canned tuna pieces were retorted to equivalent lethality (Fo -value of four) for different time and temperature processes. Retorting at a lower temperature, longer time resulted in less mass loss than higher temperature, shorter time processes. Canned storage of up to five weeks had no effect on muscle mass or moisture content. [source] Investigation of multiphase hydrogenation in a catalyst-trap microreactorJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 3 2009S. McGovern BACKGROUND: Multiphase hydrogenation plays a critical role in the pharmaceutical industry. A significant portion of the reaction steps in a typical fine chemical synthesis are catalytic hydrogenations, generally limited by resistances to mass and heat transport. To this end, the small-scale and large surface-to-volume ratios of microreactor technology would greatly benefit chemical processing in the pharmaceutical and other industries. A silicon microreactor has been developed to investigate mass transfer in a catalytic hydrogenation reaction. The reactor design is such that solid catalyst is suspended in the reaction channel by an arrangement of catalyst traps. The design supports the use of commercial catalyst and allows control of pressure drop across the bed by engineering the packing density. RESULTS: This paper discusses the design and operation of the reactor in the context of the liquid-phase hydrogenation of o-nitroanisole to o-anisidine. A two-phase ,flow map' is generated across a range of conditions depicting three flow regimes, termed gas-dominated, liquid-dominated, and transitional, all with distinctly different mass transfer behavior. Conversion is measured across the flow map and then reconciled against the mass transfer characteristics of the prevailing flow regime. The highest conversion is achieved in the transitional flow regime, where competition between phases induces the most favorable gas,liquid mass transfer. CONCLUSION: The results are used to associate a mass transfer coefficient with each flow regime to quantify differences in performance. This reactor architecture may be useful for catalyst evaluation through rapid screening, or in large numbers as an alternative to macro-scale production reactors. Copyright © 2008 Society of Chemical Industry [source] Influence of transverse rotating magnetic field on enhancement of solid dissolution processAICHE JOURNAL, Issue 6 2010Rakoczy Abstract The main objective of this work is to study the effect of transverse rotating magnetic field (TRMF) on the enhancement of solid dissolution process in the novel type reactor (TRMFR). The application of magnetically driven fluidization (MDF with homogeneous and heterogeneous systems) on mass transfer process is presented. A study of the effect of ferromagnetic particles content on solid,liquid mass transfer has been made. The experimental investigations are provided for the explanation of the influence on the dissolution process of a solid body to surrounding its dilute solution in a novel type reactor with the ferromagnetic particles suspended. The mass transfer coefficient is calculated from a kinetic equation and correlated in the relationship including standard and magnetic dimensionless numbers. The overall enhancements due to TRMF and MDF were compared. Unique correlating relations were obtained to generalize the experimental database. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Influence of elevated pressure and particle lyophobicity on hydrodynamics and gas,liquid mass transfer in slurry bubble columnsAICHE JOURNAL, Issue 3 2010Vinit P. Chilekar Abstract This article reports on the influence of elevated pressure and catalyst particle lyophobicity at particle concentrations up to 3 vol % on the hydrodynamics and the gas-to-liquid mass transfer in a slurry bubble column. The study was done with demineralized water (aqueous phase) and Isopar-M oil (organic phase) slurries in a 0.15 m internal diameter bubble column operated at pressures ranging from 0.1 to 1.3 MPa. The overall gas hold-up, the flow regime transition point, the average large bubble diameter, and the centerline liquid velocity were measured along with the gas,liquid mass transfer coefficient. The gas hold-up and the flow regime transition point are not influenced by the presence of lyophilic particles. Lyophobic particles shift the regime transition to a higher gas velocity and cause foam formation. Increasing operating pressure significantly increases the gas hold-up and the regime transition velocity, irrespective of the particle lyophobicity. The gas,liquid mass transfer coefficient is proportional to the gas hold-up for all investigated slurries and is not affected by the particle lyophobicity, the particle concentration, and the operating pressure. A correlation is presented to estimate the gas,liquid mass transfer coefficient as a function of the measured gas hold-up: . © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Bubble shape, gas flow and gas,liquid mass transfer in pulp fibre suspensionsTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2010L. K. Ishkintana Abstract Gas,liquid mass transfer in pulp fibre suspensions in a batch-operated bubble column is explained by observations of bubble size and shape made in a 2D column. Two pulp fibre suspensions (hardwood and softwood kraft) were studied over a range of suspension mass concentrations and gas flow rates. For a given gas flow rate, bubble size was found to increase as suspension concentration increased, moving from smaller spherical/elliptical bubbles to larger spherical-capped/dimpled-elliptical bubbles. At relatively low mass concentrations (Cm,=,2,3% for the softwood and Cm,,,7% for the hardwood pulp) distinct bubbles were no longer observed in the suspension. Instead, a network of channels formed through which gas flowed. In the bubble column, the volumetric gas,liquid mass transfer rate, kLa, decreased with increasing suspension concentration. From the 2D studies, this occurred as bubble size and rise velocity increased, which would decrease overall bubble surface area and gas holdup in the column. A minimum in kLa occurred between Cm,=,2% and 4% which depended on pulp type and was reached near the mass concentration where the flow channels first formed. le transfert de masse gaz-liquide dans des suspensions de fibres de pulpe, dans une colonne à bulles de traitement en lot, est expliqué par des observations faites dans une colonne 2D de la taille et de la forme des bulles. Deux suspensions de fibres de pulpe (pulpes kraft de bois dur et de bois tendre) ont été étudiées sur un intervalle de concentrations en masse des suspensions et sur un intervalle de débits de gaz. Pour un débit de gaz donné, on a observé que la taille des bulles augmentait avec l'augmentation de la concentration de la suspension, passant de petites bulles sphériques/elliptiques à des bulles plus grosses de forme quasi-sphérique avec capuchon à elliptique avec dépression. À des concentrations en masse relativement basses (Cm,=,2,3% pour le bois tendre et Cm,=,,7% pour la pulpe de bois dur), des bulles distinctes n'étaient plus observées dans la suspension. Au lieu de cela, un réseau de canaux se formait, au travers duquel le gaz s'écoulait. Dans la colonne à bulles, le taux de transfert de masse volumétrique gaz-liquide, kLa, diminuait avec l'augmentation de la concentration de la suspension. À partir des études 2D, cela se produisait lorsque la taille des bulles et la vélocité ascendante augmentaient, ce qui devrait faire diminuer la surface d'ensemble des bulles et la retenue de gaz dans la colonne. Un minimum de kLa a été observé avec Cm,=,2% et 4% (selon le type de pulpe) et était atteint à proximité de la concentration en masse pour laquelle les canaux d'écoulement commençaient à se former. [source] Gas,liquid mass transfer in three-phase inverse fluidized bed reactor with Newtonian and non-Newtonian fluidsASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 2 2010V. Sivasubramanian Abstract Liquid-phase volumetric mass transfer coefficients, kLa were determined in three-phase inverse fluidized beds of low-density polyethylene (LDPE) and polypropylene (PP) spheres fluidized by a countercurrent flow of air and Newtonian (water and glycerol solutions) or non-Newtonian liquids [carboxy methyl cellulose (CMC) solutions]. The effects of liquid and gas velocities, particle size, solid loading and addition of organic additives (glycerol and CMC) on the volumetric mass transfer coefficient, kLa were determined. The superficial liquid velocity had a weak effect on the mass transfer whereas the gas flow rate affected the mass transfer positively. kLa increased with increase in particle diameter and decreased with increase in initial bed height (solid loading). kLa decreased as the concentration of glycerol (viscosity) and CMC increased. Empirical correlations are presented to predict the gas,liquid volumetric mass transfer coefficient in terms of operating variables. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] An overview of the mathematical modelling of liquid membrane separation processes in hollow fibre contactorsJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 11 2009E Bringas Abstract Liquid membranes have traditionally been employed for liquid/liquid mass transfer and have found applications in industrial, biomedical and analytical fields as well as in hydrometallurgical processes, wastewater treatment and remediation of polluted groundwater. However, in spite of the known advantages of liquid membranes, there are few examples of industrial application. The development of reliable mathematical models and design parameters (mass transport coefficients and equilibrium or kinetic parameters associated with the interfacial reactions) is a necessary step for design, cost estimation, process optimisation and scale-up. This work reports an overview of the different approaches that have been proposed in the literature to the mathematical modelling of liquid membrane separation processes in hollow fibre contactors providing, at the same time, a useful guideline to characterise the mass transport phenomena and a tool for the optimal design and intensification of separation processes. Copyright © 2009 Society of Chemical Industry [source] | ||||||||||