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Selected AbstractsSpin-lattice relaxation of spin-½ nuclei in solids containing diluted paramagnetic impurity centers.CONCEPTS IN MAGNETIC RESONANCE, Issue 1 2003Abstract Dynamic nuclear polarization of nuclear spins via the solid-state and thermal mixing effects is discussed. Continuous-wave S- and X-band microwave radiation have been employed to measure 13C signal enhancements and polarization times for 13C nuclei in a natural type Ib diamond as a function of magnetic field. It was found that thermal mixing plays an important role in the 13C signal enhancement because the central electron spin resonance (ESR) line width HL , H0,C/,e, resulting in flip-flip and flip-flop forbidden transitions taking place simultaneously. On the other hand, the 13C spin-lattice relaxation rate is determined to a large extent by the solid-state effect (forbidden transitions). 13C polarization rates have also been measured for a suite of natural diamonds. It is shown that the polarization rate is proportional to the paramagnetic impurity concentration, in agreement with the theory. © 2003 Wiley Periodicals, Inc. Concepts Magn Reson 19A: 36,43, 2003. [source] Does female board representation influence firm performance?CORPORATE GOVERNANCE, Issue 2 2007The Danish evidence Board diversity has become a major issue within corporate governance where a number of studies seek to explore the impact of diversity on firm performance. The debate focuses on questions such as whether a corporation's board should reflect the firm's stakeholders or be more in line with society in general. This article uses a sample of listed Danish firms during the period of 1998,2001 in a cross sectional analysis. Despite that fact that Denmark has gone very far in the liberalisation of women, Danish board rooms are still to a large extent dominated by men. Contrary to a number of other studies, this article does not find any significant link between firm performance as measured by Tobin's Q and female board representation. This is also the case for board members' educational background as well as the proportion of foreigners. It is argued that board members with an unconventional background are socialised unconsciously adopting the ideas of the majority of conventional board members, which entails that a potential performance effect does not materialise. [source] An investigation into dentists' management methods of dental trauma to maxillary permanent incisors in Victoria, AustraliaDENTAL TRAUMATOLOGY, Issue 4 2008Thai Yeng To a large extent, the management actions of the dentists involved will determine the clinical outcome and, in turn, these actions will be related to their levels of knowledge. The aim of this study was to investigate dentists' knowledge of managing traumatic injuries to maxillary permanent incisors in children. A self-completion questionnaire containing 19 questions on management methods of treating dental trauma was mailed to 693 dentists in Victoria, Australia. The response rate achieved was 61%. This survey found that some of the respondents had adequate management knowledge for the different types of traumatic injuries, while others did not have the correct information. Approximately half the dentists considered milk as the preferred extraoral storage medium of choice for avulsed teeth and a period of 7,10 days splinting after replantation. A large proportion of dentists showed inadequate knowledge with regard to understanding the biological mechanisms causing replacement root resorption (61%) and external inflammatory root resorption (74%). Overall, the respondents to this survey demonstrated only a moderate level of knowledge in management of traumatic injuries to maxillary permanent incisors in children. Continuing professional development programmes may be a means of improving this deficient knowledge base. [source] Inflamed adipose tissue, insulin resistance and vascular injuryDIABETES/METABOLISM: RESEARCH AND REVIEWS, Issue 8 2008Christian X. Andersson Abstract Type 2 diabetes is the most common metabolic disorder today and has reached epidemic proportions in many countries. Insulin resistance and inflammation play a central role in the pathogenesis of type 2 diabetes and are present long before the onset of the disease. During this time, many of the complications associated with type 2 diabetes are initiated. Of major concern is the two- to fourfold increase in cardiovascular morbidity and mortality in this group compared to a nondiabetic population. Obesity, characterized by enlarged fat cells, and insulin resistance are, like type 2 diabetes, associated with impaired adipogenesis and a low-grade chronic inflammation that to a large extent emanates from the adipose tissue. Both these processes contribute to unfavourable alterations of the circulating levels of several bioactive molecules (adipokines) that are secreted from the adipose tissue, many of which have documented inhibitory effects on insulin sensitivity in the liver and peripheral tissues and, in addition, have negative effects on the cardiovascular system. Here we review current knowledge of the adipose tissue as an endocrine organ, the local and systemic effects of a chronic state of low-grade inflammation residing in the adipose tissue, and, in particular, the effects of inflammation and circulating adipokines on the vascular wall. Copyright © 2008 John Wiley & Sons, Ltd. [source] Effects of column axial force , bending moment interaction on inelastic seismic response of steel framesEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 12 2003Marina Como Abstract It is well known that axial force , bending moment interaction (N,M interaction) affects to a large extent the cyclic inelastic behaviour of structural elements, especially columns in framed structures, with reduction in bending capacity and loss of available ductility. A few studies have also shown that significant inelastic axial shortening affects the response of column elements subjected to medium,high levels of axial loads and cyclic bending. This paper is primarily aimed at evaluating the effects of column N,M interaction on the inelastic seismic response of steel frames. By considering the contemporaneous action of vertical loads, due to gravity, and of horizontal seismic excitation, it is shown that the progressive axial shortening of adjacent columns may differ substantially, thus inducing significant relative settlements at the ends of the connecting beams and, then, remarkable amplifications in beam plastic rotations. An evaluation of additional beam plastic rotations induced by column N,M interaction is carried out for real structures by investigating the inelastic response of steel frames designed according to European standards under horizontal and vertical earthquake excitations. Copyright © 2003 John Wiley & Sons, Ltd. [source] What shapes Eurasian lynx distribution in human dominated landscapes: selecting prey or avoiding people?ECOGRAPHY, Issue 4 2009Mathieu Basille In the multi-use landscape of southern Norway, the distribution of lynx is likely to be determined both by the abundance of their favoured prey , the roe deer , and the risk associated with the presence of humans because most lynx mortalities are caused by humans (recreational harvest, poaching, vehicle collisions). We described the distribution of the reproductive portion of the lynx population based on snow-track observations of females with dependent kittens collected over 10,yr (1997,2006) in southern Norway. We used the ecological-niche factor analysis to examine how lynx distribution was influenced by roe deer, human activity, habitat type, environmental productivity and elevation. Our first prediction that lynx should be found in areas of relatively high roe deer abundance was supported. However, our second prediction that lynx should avoid human activity was rejected, and lynx instead occupied areas more disturbed in average than those available (with the exception of the most densely occupied areas). Lynx, however, avoided the most disturbed areas and our third prediction of a trade-off between abundance of prey and avoidance of human activity was supported. On the one hand, roe deer in the most disturbed areas benefit to a large extent from current human land use practices, potentially allowing them to escape predation from lynx. On the other hand, the situation is not so favourable for the predators who are restricted in competition refuges with medium to low prey densities. The consequence is that lynx conservation will have to be achieved in a human modifed environment where the potential for a range of conflicts and high human-caused mortality will remain a constant threat. [source] Could the tree diversity pattern in Europe be generated by postglacial dispersal limitation?ECOLOGY LETTERS, Issue 6 2007Jens-Christian Svenning Abstract The relative importance of contemporary climate and history as controls of geographical diversity patterns is intensely debated. A key example is the controversy over the extent to which temperate tree distributions and diversity patterns reflect postglacial dispersal limitation. Here, we focus on Central and Northern Europe, and show that recent estimates of tree migration rates < 100 m year,1 imply that many species have probably not reached equilibrium with climate in this region. We then demonstrate that geographical accessibility from glacial refuges explains 78% of the geographical variation in the region's tree diversity and is a much stronger diversity predictor than climate. Finally, we show that realistic estimates of migration rates can be derived from the observed tree diversity pattern by assuming it to be purely dispersal driven. In conclusion, the tree diversity pattern in Central and Northern Europe could, to a large extent, be a result of postglacial dispersal limitation. [source] Mechanical preparation of root canals: shaping goals, techniques and meansENDODONTIC TOPICS, Issue 1 2005Michael Hülsmann Preparation of root canal systems includes both enlargement and shaping of the complex endodontic space together with its disinfection. A variety of instruments and techniques have been developed and described for this critical stage of root canal treatment. Although many reports on root canal preparation can be found in the literature, definitive scientific evidence on the quality and clinical appropriateness of different instruments and techniques remains elusive. To a large extent this is because of methodological problems, making comparisons among different investigations difficult if not impossible. The first section of this paper discusses the main problems with the methodology of research relating to root canal preparation while the remaining section critically reviews current endodontic instruments and shaping techniques. [source] Treatment of Process Water Containing Heavy Metals with a Two-Stage Electrolysis Procedure in a Membrane Electrolysis CellENGINEERING IN LIFE SCIENCES (ELECTRONIC), Issue 2 2005R. Fischer Abstract The capability of a two-stage electrochemical treatment for the regeneration of acidic heavy-metal containing process water was examined. The process water came from sediment bioleaching and was characterized by a wide spectrum of dissolved metals, a high sulfate content, and a pH of about 3. In the modular laboratory model cell used, the anode chamber and the cathode chamber were separated by a central chamber fitted with an ion exchanger membrane on either side. The experiments were carried out applying a platinum anode and a graphite cathode at a current density of 0.1,A/cm2. The circulation flow of the process water in the batch process amounted to 35,L/h, the electrolysis duration was 5.5,h at maximum and the total electrolysis current was about 1,A. In the first stage, the acidic process water containing metals passed through the cathode chamber. In the second stage, the cathodically pretreated process water was electrolyzed anodically. In the cathode chamber the main load of dissolved Cu, Zn, Cr and Pb was eliminated. The sulfuric acid surplus of 3,4,g/L decreased to about 1,g/L, the pH rose from initially 3.0 to 4,5, but the desired pH of 9,10 was not achieved. Precipitation in the proximity to the cathode evidently takes place at a higher pH than farther away. The dominant process in the anode chamber was the precipitation of amorphous MnO2 owing to the oxidation of dissolved Mn(II). The further depletion of the remaining heavy metals in the cathodically pretreated process water by subsequent anodic treatment was nearly exhaustive, more than 99,% of Cd, Cr, Cu, Mn, Ni, Pb, and Zn were removed from the leachate. The high depletion of heavy metals might be due to both the sorption on MnO2 precipitates and/or basic ferrous sulfate formed anodically, and the migration of metal ions through the cation exchanger membrane via the middle chamber into the cathode chamber. In the anode chamber, the sulfuric acid content increased to 6,7,g/L and the pH sank to 1.7. All heavy metals contained, with the exception of Zn, were removed to levels below the German limits for discharging industrial wastewaters into the receiving water. Moreover, the metal-depleted and acid-enriched process waters could be returned to the leaching process, hence reducing the output of wastewater. The results indicated that heavy metals could be removed from acidic process waters by two-stage electrochemical treatment to a large extent. However, to improve the efficiency of metal removal and to establish the electrochemical treatment in practice, further work is necessary to optimize the operation of the process with respect to current density, energy consumption, discharging of metal precipitates deposited in the electrode chambers and preventing membrane clogging. [source] 3.2 Ensuring research productivity in the future facultyEUROPEAN JOURNAL OF DENTAL EDUCATION, Issue 2002Pål Brodin The group concluded that the research productivity of a dental school depended to a large extent on the availability of resources, human and economic. Firstly it requires a group of individuals trained and educated to conduct independent research. Secondly, it requires that these individuals had time to spend on research activities. Thirdly, appropriate space and equipment in which to conduct the research were considered prerequisites. Fourthly, they require an ongoing and appropriate budget. Fifthly, it is essential to have an appropriate climate in the school that encourages and rewards research achievement. [source] Basicity of Guanidines with Heteroalkyl Side Chains in AcetonitrileEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 30 2008Mirjana Eckert-Maksi Abstract The pKa values of seven novel guanidine derivatives, six of them possessing heteroalkyl substituents capable of forming intramolecular hydrogen bonds, were determined in acetonitrile (MeCN) by using the UV/Vis spectrophotometric titration method. The obtained pKa values range from 24.7 to 27.2. The most basic among the studied guanidines was found to be by ca. 4 pKa units more basic than thewell-known superbase N1,N1,N3,N3 -tetramethylguanidine (TMG). The trends in the changes in the measured pKa values were compared with the experimental (determined by the extended kinetic method) and theoretical [B3LYP/6-311+G(2df,p)//B3LYP/6-31G(d)] gas-phase proton affinities. It was shown that basicity ordering of the bases with dimethylaminopropyl substituents in acetonitrile follows the trend encountered in the gas phase. However, this is not the case for the methoxypropyl-substituted guanidines indicating that in these molecules formation of the intramolecular hydrogen bonds is to large extent hindered due to solvation by acetonitrile.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source] The effect of aging biosolids on the availability of cadmium and zinc in soilEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2001S. Stacey Summary A major concern with the safe re-use of biosolids on land is the potential for release of metals from organic matter in the biosolids, due to decomposition proceeding as biosolids age. To quantify the effects of biosolid aging on Cd and Zn bioavailability, two sewage sludges (Lagoon sludge and Filtered sludge) and a garden compost were incubated at 25°C and 35°C for 100 days. Changes in availability of Cd and Zn were determined using isotope dilution principles, with the materials being labelled with carrier-free 109Cd and 65Zn. We determined isotopically exchangeable metal pools (E values) and plant available metal pools (L values) by measuring specific activities of Cd and Zn in soil extracts and in wheat plants, respectively. Changes in carbon content over time were determined using 13C-NMR spectroscopy and chemical extraction methods, and related to changes in availability of metal pools as determined by isotopic procedures. Hot-water-extractable carbon content, assumed to represent easily decomposable organic matter, decreased during the 100 days by 80,190 mg kg,1. The Compost and Lagoon sludge showed no change in L values for Cd or Zn with time, but in the Filtered sludge the L values for Cd and Zn increased significantly, by 43% and 56%, respectively. The isotopically exchangeable pools of Cd and Zn did not change with incubation treatment of the biosolids. These data indicate that the potential for metal release from biosolids as organic matter decomposes depends to a large extent on the biosolid composition. [source] ECOLOGICAL DIFFERENTIATION AND DIPLOID SUPERIORITY ACROSS A MOVING PLOIDY CONTACT ZONEEVOLUTION, Issue 1 2007Richard J. A. Buggs Plant polyploid complexes provide useful model systems for distinguishing between adaptive and nonadaptive causes of parapatric distributions in closely related lineages. Polyploidy often gives rise to morphological and physiological changes, which may be adaptive to different environments, but separate distributions may also be maintained by reproductive interference caused by postzygotic reproductive isolation. Here, we test the hypothesis that diploid and descendent polyploid races of the wind-pollinated herb Mercurialis annua, which are found in parapatry over an environmental gradient in northeast Spain, are differentiated in their ecophysiology and life history. We also ask whether any such differences represent adaptations to their different natural environments. On the basis of a series of reciprocal transplant experiments in the field, and experiments under controlled conditions, we found that diploid and polyploid populations of M. annua are ecologically differentiated, but that they do not show local adaptation; rather, the diploids have higher fitness than the polyploids across both diploid- and polyploid-occupied regions. In fact, diploids are currently displacing polyploids by advancing south on two separate fronts in Spain, and previous work has shown that this displacement is being driven to a large extent by asymmetrical pollen swamping. Our results here suggest that ecophysiological superiority of the diploids may also be contributing to their expansion. [source] Effect of test frequency on fatigue strength of low carbon steelFATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 6 2009N. TSUTSUMI ABSTRACT Ultrasonic fatigue tests (test frequency: 20 kHz) and conventional tension,compression fatigue tests (10 Hz) have been conducted on annealed and 10% pre-strained specimens of 0.13% carbon steel. Small holes were introduced on the specimen surface to investigate the effect of test frequency on small crack growth. The dynamic stress concentration factor and the stress intensity factor under ultrasonic fatigue tests were checked to be almost the same as those of conventional tension,compression fatigue tests. However, the fatigue properties were dependent on the test frequency. Ultrasonic fatigue tests showed longer fatigue life and lower fatigue crack growth rate for the annealed and 10% pre-strained specimens. Slip bands were scarce in the neighbourhood of cracks under ultrasonic fatigue tests, while many slip bands were observed in a wide area around the crack under conventional fatigue tests. In order to explain the effect of test frequency on fatigue strength, dynamic compression tests with Split Hopkinson bars were carried out. The stress level increases substantially with the strain rate. Thus, the increase in fatigue strength might be, to a large extent, due to a reduction in crack tip cyclic plasticity during ultrasonic fatigue tests. [source] Going Public: An Empirical Investigation of U.S. Bound Israeli IPOsFINANCIAL MARKETS, INSTITUTIONS & INSTRUMENTS, Issue 3 2010Iftekhar Hasan Between 1985,2003, more than 120 Israeli companies went public in the U.S., bringing the accumulated number of U.S. bound, Israeli initial public offerings (IPOs) to a figure greater than all other foreign countries combined. In this study, we compare the short and long run performance of Israeli IPOs to that of similar international and U.S. IPOs. Holding all else equal, we find that Israeli IPOs are significantly less underpriced than their local and foreign counterparts. As we examine the characteristics of Israeli issuers, we find that they differ than those of other foreign and local issuers in some important dimensions that compensate investors for information asymmetry and risk. First, compared to their home market capitalization size, U.S. bound Israeli IPOs, are significantly larger than the IPOs conducted by their foreign counterparts. Second, Israeli issuers tend to perform better than other foreign and U.S. local IPOs during our entire period of observation. Third, to a large extent, the Israeli firms in our sample have products, licensing or franchising relationships or venture capital funds with strong roots in the U.S. prior to the IPO. And fourth, the relevant investor community of Israeli IPOs, at least at the early stages, is small and overwhelmingly American. Our findings are consistent with prior studies documenting that firms raising capital outside of their domicile country are typically a select group of high quality firms in need of external financing that cannot be sufficiently provided in their home market. [source] Resource quality and stoichiometric constraints on stream ecosystem functioningFRESHWATER BIOLOGY, Issue 5 2009SALLY HLADYZ Summary 1. Resource quality and stoichiometric imbalances in carbon : nutrient ratios between consumers and resources can influence key ecosystem processes. In many streams, this has important implications for food webs that are based largely upon the utilization of terrestrial leaf-litter, which varies widely among litter types in its value as a food source for detritivores and as a substrate for microbial decomposers. 2. We measured breakdown rates and macroinvertebrate colonization of leaf-litter from a range of native and exotic plants of differing resource quality and palatability to consumers [e.g. carbon : nitrogen : phosphorus (C : N : P) ratios, lignin and cellulose content], in a field experiment. We also measured C : N : P ratios of the principal leaf-shredding invertebrates, which revealed strong stoichiometric imbalances across trophic levels: C : N and C : P ratios typically differed by at least one order of magnitude between consumers and resources, whereas N : P imbalances were less marked. Application of the threshold elemental ratio approach, which integrates animal bioenergetics and body elemental composition in examining nutrient deficiency between consumers and resources, revealed less marked C : P imbalances than those based on the simpler arithmetic differences described above. 3. Litter breakdown rates declined as nutrient imbalances widened and resource quality fell, but they were independent of whether resources were exotic or native. The principal drivers of total, microbial and invertebrate-mediated breakdown rates were lignin : N, lignin : P and fungal biomass, respectively. However, multiple regression using orthogonal predictors yielded even more efficient models of litter breakdown, as consumers responded to more than one aspect of resource quality. For example, fungal biomass and litter C : N both influenced invertebrate-mediated breakdown. 4. Large stoichiometric imbalances and changes in resource quality are likely to have serious consequences for stream ecosystem functioning, especially when riparian zones have been invaded by exotic plant species whose chemical composition differs markedly from that of the native flora. Consequently, the magnitude and direction of change in breakdown rates and, thus, resource depletion, will be driven to a large extent by the biochemical traits (rather than taxonomic identity per se) of the resident and invading flora. [source] Genetic and environmental influences on Anxious/Depression during childhood: a study from the Netherlands Twin RegisterGENES, BRAIN AND BEHAVIOR, Issue 8 2005D. I. Boomsma For a large sample of twin pairs from the Netherlands Twins Register who were recruited at birth and followed through childhood, we obtained parental ratings of Anxious/Depression (A/D). Maternal ratings were obtained at ages 3 years (for 9025 twin pairs), 5 years (9222 pairs), 7 years (7331 pairs), 10 years (4430 pairs) and 12 years (2363 pairs). For 60,90% of the pairs, father ratings were also available. Multivariate genetic models were used to test for rater-independent and rater-specific assessments of A/D and to determine the genetic and environmental influences on individual differences in A/D at different ages. At all ages, monozygotic twins resembled each other more closely for A/D than dizygotic twins, implying genetic influences on variation in A/D. Opposite sex twin pairs resembled each other to same extent as same-sex dizygotic twins, suggesting that the same genes are expressed in boys and girls. Heritability estimates for rater-independent A/D were high in 3-year olds (76%) and decreased in size as children grew up [60% at age 5, 67% at age 7, 53% at age 10 (60% in boys) and 48% at age 12 years]. The decrease in genetic influences was accompanied by an increase in the influence of the shared family environment [absent at ages 3 and 7, 16% at age 5, 20% at age 10 (5% in boys) and 18% at age 12 years]. The agreement between parental A/D ratings was between 0.5 and 0.7, with somewhat higher correlations for the youngest group. Disagreement in ratings between the parents was not merely the result of unreliability or rater bias. Both the parents provided unique information from their own perspective on the behavior of their children. Significant influences of genetic and shared environmental factors were found for the unique parental views. At all ages, the contribution of shared environmental factors to variation in rater-specific views was higher for father ratings. Also, at all ages except age 12, the heritability estimates for the rater-specific phenotype were higher for mother ratings (59% at age 3 and decreasing to 27% at age 12 years) than for father ratings (between 14 and 29%). Differences between children, even as young as 3 years, in A/D are to a large extent due to genetic differences. As children grow up, the variation in A/D is due in equal parts to genetic and environmental influences. Anxious/Depression, unlike many other common childhood psychopathologies, is influenced by the shared family environment. These findings may provide support for why certain family therapeutic approaches are effective in the A/D spectrum of illnesses. [source] Micro-scale sulphur isotope evidence for sulphur cycling in the late Archean shallow oceanGEOBIOLOGY, Issue 1 2007B. S. KAMBER ABSTRACT We report in situ secondary ion mass spectrometer sulphur isotope data for sedimentary pyrite from the 2.52 Ga Upper Campbellrand Subgroup, Transvaal, South Africa. The analysed sedimentary rocks represent a transition in depositional environment from very shallow to deeper water, with strong sedimentological, facies distribution and geochemical evidence for the presence of a shallow redox chemocline. Data were obtained directly in thin section in order to preserve petrographic context. They reveal a very large extent of isotopic fractionation both in mass-independent (MIF) and in mass-dependent fractionation (MDF) on unprecedentedly small scale. In the shallow-water microbical carbonates, three types of pyrite were identified. The texturally oldest pyrite is found as small, isotopically little fractionated grains in the microbial mats. Large (several mm) spheroidal pyrite concretions, which postdate the mat pyrite, record strong evidence for an origin by bacterial sulphate reduction. Rare pyrite surrounding late fenestral calcite is inferred to have formed from recycled bacterial pyrite on account of the slope of its correlated MIF and MDF array. This latter type of pyrite was also found in an interbedded black shale and a carbonate laminite. In a deeper water chert, pyrite with very heavy sulphur indicates partial to almost complete sulphate reduction across a chemocline whose existence has been inferred independently. The combined picture from all the studied samples is that of a sulphate availability-limited environment, in which sulphur was cycled between reservoirs according to changing redox conditions established across the chemocline. Cycling apparently reduced the extent of recorded sulphur isotope fractionation relative to what is expected from projection in the correlated MIF and MDF arrays. This is consistent with regionally relatively high free oxygen concentrations in the shallow water, permitting locally strong MDF. Our new observations add to the growing evidence for a complex, fluctuating evolution of free atmospheric oxygen between c. 2.7 Ga and 2.3 Ga. [source] Contemporary kinematics of the southern Aegean and the Mediterranean RidgeGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 3 2004Corné Kreemer SUMMARY This study focuses on the kinematics of the southern Aegean and the Mediterranean Ridge (MR). A quantification of the deformation of the MR is essential for both evaluating physical models of accretionary wedges in general and for obtaining a self-consistent model of the surface deformation over the entire Nubia,Eurasia (NU,EU) plate boundary zone in the eastern Mediterranean. Previous kinematic studies have not properly considered the deformation field south of the Hellenic arc. Although this study focuses on the deformation field of the MR, we also discuss the kinematics of the southern Aegean, because the geometry and movement of the Hellenic arc determine to a large extent the kinematic boundary conditions for kinematic studies of the MR. We calculate a continuous velocity and strain rate field by interpolating model velocities that are fitted in a least-squares sense to published Global Positioning System (GPS) velocities. In the interpolation, we use information from a detailed data set of onshore and offshore active faulting to place constraints on the expected style and direction of the model strain rate field. In addition, we use the orientations of tracks left by seamounts travelling into the wedge to further constrain the offshore deformation pattern. Our model results highlight the presence of active shear partitioning within the Mediterranean ridge. High compressional strain rates between the ridge crest and the deformation front accommodate approximately 60,70 per cent of the total motion over the wedge, and the outward growth rate of the frontal thrust is , 4 mm yr,1. Strain partitioning within the wedge leads to 19,23 mm yr,1 of dextral motion at the wedge,backstop contact of the western MR, whereas the Pliny and Strabo trenches in the eastern MR accommodate 21,23 mm yr,1 of sinistral motion. The backstop of the western MR is kinematically part of the southern Aegean, which moves as a single block [the Aegean block (AE)] at 33,34 mm yr,1 in the direction of S24°W ± 1° towards stable Nubia (NU). Our model confirms that there is a clear divergence between the western and eastern Hellenic arc and we argue for a causal relation between the outward motion of the arc and the gradient in the regional geoid anomaly. Our results suggest that a significant driving source of the surface velocity field lies south of the Hellenic arc and only for the southeastern Aegean could there be some effect as a result of gravitational collapse associated with density differences within the overriding plate. [source] Responses of dryland soil respiration and soil carbon pool size to abrupt vs. gradual and individual vs. combined changes in soil temperature, precipitation, and atmospheric [CO2]: a simulation analysisGLOBAL CHANGE BIOLOGY, Issue 9 2009WEIJUN SHEN Abstract With the large extent and great amount of soil carbon (C) storage, drylands play an important role in terrestrial C balance and feedbacks to climate change. Yet, how dryland soils respond to gradual and concomitant changes in multiple global change drivers [e.g., temperature (Ts), precipitation (Ppt), and atmospheric [CO2] (CO2)] has rarely been studied. We used a process-based ecosystem model patch arid land simulator to simulate dryland soil respiration (Rs) and C pool size (Cs) changes to abrupt vs. gradual and single vs. combined alterations in Ts, Ppt and CO2 at multiple treatment levels. Results showed that abrupt perturbations generally resulted in larger Rs and had longer differentiated impacts than did gradual perturbations. Rs was stimulated by increases in Ts, Ppt, and CO2 in a nonlinear fashion (e.g., parabolically or asymptotically) but suppressed by Ppt reduction. Warming mainly stimulated heterotrophic Rs (i.e., Rh) whereas Ppt and CO2 influenced autotrophic Rs (i.e., Ra). The combined effects of warming, Ppt, and CO2 were nonadditive of primary single-factor effects as a result of substantial interactions among these factors. Warming amplified the effects of both Ppt addition and CO2 elevation whereas Ppt addition and CO2 elevation counteracted with each other. Precipitation reduction either magnified or suppressed warming and CO2 effects, depending on the magnitude of factor's alteration and the components of Rs (Ra or Rh) being examined. Overall, Ppt had dominant influence on dryland Rs and Cs over Ts and CO2. Increasing Ppt individually or in combination with Ts and CO2 benefited soil C sequestration. We therefore suggested that global change experimental studies for dryland ecosystems should focus more on the effects of precipitation regime changes and the combined effects of Ppt with other global change factors (e.g., Ts, CO2, and N deposition). [source] Effects of wildfire and permafrost on soil organic matter and soil climate in interior AlaskaGLOBAL CHANGE BIOLOGY, Issue 12 2006JENNIFER W. HARDEN Abstract The influence of discontinuous permafrost on ground-fuel storage, combustion losses, and postfire soil climates was examined after a wildfire near Delta Junction, AK in July 1999. At this site, we sampled soils from a four-way site comparison of burning (burned and unburned) and permafrost (permafrost and nonpermafrost). Soil organic layers (which comprise ground-fuel storage) were thicker in permafrost than nonpermafrost soils both in burned and unburned sites. While we expected fire severity to be greater in the drier site (without permafrost), combustion losses were not significantly different between the two burned sites. Overall, permafrost and burning had significant effects on physical soil variables. Most notably, unburned permafrost sites with the thickest organic mats consistently had the coldest temperatures and wettest mineral soil, while soils in the burned nonpermafrost sites were warmer and drier than the other soils. For every centimeter of organic mat thickness, temperature at 5 cm depth was about 0.5°C cooler during summer months. We propose that organic soil layers determine to a large extent the physical and thermal setting for variations in vegetation, decomposition, and carbon balance across these landscapes. In particular, the deep organic layers maintain the legacies of thermal and nutrient cycling governed by fire and revegetation. We further propose that the thermal influence of deep organic soil layers may be an underlying mechanism responsible for large regional patterns of burning and regrowth, detected in fractal analyses of burn frequency and area. Thus, fractal geometry can potentially be used to analyze changes in state of these fire prone systems. [source] Distant warriors, distant peace workers?GLOBAL NETWORKS, Issue 4 2008Multiple diaspora roles in Sri Lanka's violent conflict Abstract This article provides a critical, empirically based analysis of the multiple ways in which diaspora communities participate in transnational politics related to their war-affected former home countries. The case of Sri Lanka , and the Tamil and Sinhalese diasporas in the West , is used to illustrate how contemporary armed conflicts are increasingly waged in an international arena. Active diaspora groups have enabled an extension of nationalist mobilization, hostilities and polarization across the globe. Diaspora actors take part in propaganda work and fundraising in support of the belligerent parties in Sri Lanka, while the polarization between Sinhalese and Tamils is to a large extent replicated in the diaspora. However, there are also examples of diaspora groups that challenge war and militarism, for instance by calling for non-violent conflict resolution, condemning atrocities by both sides, and engaging in cross-ethnic dialogue. The article also argues that diaspora engagement in reconstruction of war-torn areas can be a double-edged sword, as it can reproduce , or reduce , grievances and inequalities that fuel the conflict. By discussing the many ways in which diasporas engage in homeland politics, the article challenges simplified understandings of diasporas as either,warriors'or,peace workers' in relation to their homeland conflicts. [source] How does the vertical and horizontal structure of a perennial ryegrass and white clover sward influence grazing?GRASS & FORAGE SCIENCE, Issue 2 2001P. Carrère Mixtures of perennial ryegrass (Lolium perenne L.) and white clover (Trifolium repens L.) sown in alternate rows or in a thoroughly mixed matrix were grazed by sheep, either continuously or during short grazing tests, and were used to investigate the influence of the vertical and horizontal components of the sward structure on defoliation by sheep. In an experiment under continuous grazing, the defoliation intensity was greater for white clover compared with perennial ryegrass leaves (0·80 and 0·58 respectively). In spring, perennial ryegrass leaves were more defoliated than white clover leaves, whereas the reverse was observed in summer. The ratio of the proportion of white clover to perennial ryegrass leaves grazed was negatively correlated with the difference between the surface height of the perennial ryegrass and white clover rows in spring. In both spring and summer, white clover leaves of the same extended leaf length had a higher proportion of them grazed than perennial ryegrass leaves. In another experiment, during short grazing tests with perennial ryegrass,white clover swards that were grazed at the same sward surface height and at the same white clover content as in the previous experiment, there were no significant differences in the proportion of white clover and perennial ryegrass leaves grazed between strips of the two species and thoroughly mixed structures. The proportion of white clover leaves grazed was higher than that of perennial ryegrass leaves. These results show that the differential defoliation by sheep of perennial ryegrass and white clover leaves varies according to their vertical distribution in the mixed canopy, but is little affected by their horizontal distribution. Even small differences in sward surface height between mixed perennial ryegrass and white clover can affect diet selection by sheep to a rather large extent. [source] Karst Spring Responses Examined by Process-Based ModelingGROUND WATER, Issue 6 2006Steffen Birk Ground water in karst terrains is highly vulnerable to contamination due to the rapid transport of contaminants through the highly conductive conduit system. For contamination risk assessment purposes, information about hydraulic and geometric characteristics of the conduits and their hydraulic interaction with the fissured porous rock is an important prerequisite. The relationship between aquifer characteristics and short-term responses to recharge events of both spring discharge and physicochemical parameters of the discharged water was examined using a process-based flow and transport model. In the respective software, a pipe-network model, representing fast conduit flow, is coupled to MODFLOW, which simulates flow in the fissured porous rock. This hybrid flow model was extended to include modules simulating heat and reactive solute transport in conduits. The application of this modeling tool demonstrates that variations of physicochemical parameters, such as solute concentration and water temperature, depend to a large extent on the intensity and duration of recharge events and provide information about the structure and geometry of the conduit system as well as about the interaction between conduits and fissured porous rock. Moreover, the responses of solute concentration and temperature of spring discharge appear to reflect different processes, thus complementing each other in the aquifer characterization. [source] Influence of Transient Flow on Contaminant BiodegradationGROUND WATER, Issue 2 2001Mario Schirmer The rate of biodegradation in contaminated aquifers depends to a large extent on dispersive mixing processes that are now generally accepted to result from spatial variations in the velocity field. It has been shown, however, that transient flow fields can also contribute to dispersive mixing. The influence of transient flow on biodegrading contaminants is particularly important since it can enhance mixing with electron acceptors, further promoting the reactive process. Using numerical simulations, the effect of transient flow on the behavior of a biodegradable contaminant is evaluated here both with respect to the development of apparently large horizontal transverse dispersion and also with respect to enhanced mixing between the substrate (electron donor) and electron acceptor. The numerical model BIO3D, which solves for advective-dispersive transport coupled with Monod-type biodegradation of substrates in the presence of an electron acceptor, was used for the simulations. The model was applied in a two-dimensional plan view mode considering a single substrate. Transient flow fields were found to yield larger apparent transverse dispersion because the longitudinal dispersivity also acts transverse to the mean flow direction. In the reactive case, the transient flow field increases substrate-oxygen mixing, which in turn enhances the overall rate of biodegradation. The results suggest that in the case of moderate changes of flow directions, a steady-state flow field can be justified, thereby avoiding the higher computational costs of a fully transient simulation. The use of a higher transverse horizontal dispersivity in a steady flow field can, under these conditions, adequately forecast plume development. [source] Reactivity and Selectivity of Captodative Olefins as Dienes in Hetero -Diels,Alder ReactionsHELVETICA CHIMICA ACTA, Issue 10 2008Rubén Sanabria Abstract The reactivity and selectivity of the the captodative olefins 1-acylvinyl benzoates 1a,1f and 3a as heterodienes in hetero -Diels,Alder reactions in the presence of electron-rich dienophiles is described. Heterodienes 1 undergo regioselective cycloaddition with the alkyl vinyl etherdienophiles 6a,b and 9 to give the corresponding dihydro-2H -pyrans 7, 8, and 10 under thermal conditions. The reactivity of these cycloadditions depends, to a large extent, on the electronic demand of the substituent in the aroyloxy group of the heterodiene. Frontier-molecular-orbital (FMO; ab initio) and density-functional-theory (DFT) calculations of the ground and transition states account for the reactivity and regioselectivity observed in these processes. [source] Modulation of glycosphingolipid metabolism significantly improves hepatic insulin sensitivity and reverses hepatic steatosis in mice,HEPATOLOGY, Issue 5 2009Nora Bijl Nonalcoholic fatty liver disease (NAFLD) is associated with obesity, insulin resistance, and type 2 diabetes. The hyperinsulinemia that occurs as a consequence of insulin resistance is thought to be an important contributor to the development of fatty liver. We have shown that the iminosugar N-(5'-adamantane-1'-yl-methoxy)-pentyl-1-deoxynojirimycin (AMP-DNM), an inhibitor of the enzyme glucosylceramide synthase, is a potent enhancer of insulin signaling in rodent models for insulin resistance and type 2 diabetes. The present study was designed to assess the impact of AMP-DNM on insulin levels, liver triglyceride synthesis, and gene expression profile. Treatment of ob/ob mice with AMP-DNM restored insulin signaling in the liver, corrected blood glucose values to levels found in lean mice, and decreased insulin concentration. The expression of sterol regulatory element-binding protein 1c target genes involved in fatty acid synthesis normalized. AMP-DNM treatment significantly reduced liver to body weight ratio and reversed hepatic steatosis, comprising fat as well as inflammatory markers. In addition, AMP-DNM treatment corrected to a large extent the gene expression profile of ob/ob mice livers toward the profile of lean mice. Conclusion: Pharmacological lowering of glycosphingolipids with the iminosugar AMP-DNM is a promising approach to restore insulin signaling and improve glucose homeostasis as well as hepatic steatosis. (HEPATOLOGY 2009.) [source] 1. THE DEFINING CHARACTER OF CHINESE HISTORICAL THINKING1HISTORY AND THEORY, Issue 2 2007CHUN-CHIEH HUANG ABSTRACT Imbued with profound historical consciousness, the Chinese people are Homo historiens in every sense of the term. To be human in China, to a very large extent, is to be historical, which means to live up to the paradigmatic past. Therefore, historical thinking in traditional China is moral thinking. The Chinese historico-moral thinking centers around the notion of Dao, a notion that connotes both Heavenly principle and human norm. In view of its practical orientation, Chinese historical thinking is, on the one hand, concrete thinking and, on the other, analogical thinking. Thinking concretely and analogically, the Chinese people are able to communicate with the past and to extrapolate meanings from history. In this way, historical experience in China becomes a library in which modern readers may engage in creative dialogues with the past. [source] Marine and human activity influences on the groundwater quality of southern Korinthos area (Greece)HYDROLOGICAL PROCESSES, Issue 12 2003G. Stamatis Abstract In this paper the groundwater quality of the southern part of Korinthos region (north-east Peloponnese) is discussed. The geology is characterized by a thick sequence of Neogene marls alternating with sandstones, overlain by superficial Quaternary deposits. The latter consist of a mixture of loose materials such as conglomerates, marly sandstones, sands and clay to silty sands. The area is crossed by a fault system parallel to the coastline, and the Quaternary sediments have formed extended Tyrrhenian marine terraces. Two aquifers have been identified in the area. The first is unconfined and occurs within the Quaternary sediments whereas the other is a deep confined aquifer occurring within the underlying Neogene marl series. Analysis of hydrochemical evolution over the past 30 years has indicated significant deterioration of quality owing to seawater intrusion and nitrate pollution. The various sources of pollution have rendered, to a large extent, shallow groundwater unsuitable not only for potable water supply but also for irrigation purposes. However, this is not the case for the deeper confined aquifer. Statistical analysis was used to explore the evolution of salinization during the years 1968 and 1998. In view of the alarming conditions caused by the documented groundwater quality deterioration, the need for integrated water resources management is stressed to maintain the socio-economic growth of the region studied. Copyright © 2003 John Wiley & Sons, Ltd. [source] Erosion models: quality of spatial predictionsHYDROLOGICAL PROCESSES, Issue 5 2003Victor Jetten Abstract An Erratum has been published for this article in Hydrological Processes 18(3) 2004, 595. An overview is given on the predictive quality of spatially distributed runoff and erosion models. A summary is given of the results of model comparison workshops organized by the Global Change and Terrestrial Ecosystems Focus 3 programme, as well as other results obtained by individual researchers. The results concur with the generally held viewpoint in the literature that the predictive quality of distributed models is moderately good for total discharge at the outlet, and not very good for net soil loss. This is only true if extensive calibration is done: uncalibrated results are generally bad. The more simple lumped models seem to perform equally well as the more complex distributed models, although the latter produce more detailed spatially distributed results that can aid the researcher. All these results are outlet based: models are tested on lumped discharge and soil loss or on hydrographs and sedigraphs. Surprisingly few tests have been done on the comparison of simulated and modelled erosion patterns, although this may arguably be just as important in the sense of designing anti-erosion measures and determining source and sink areas. Two studies are shown in which the spatial performance of the erosion model LISEM (Limburg soil erosion model) is analysed. It seems that: (i) the model is very sensitive to the resolution (grid cell size); (ii) the spatial pattern prediction is not very good; (iii) the performance becomes better when the results are resampled to a lower resolution and (iv) the results are improved when certain processes in the model (in this case gully incision) are restricted to so called ,critical areas', selected from the digital elevation model with simple rules. The difficulties associated with calibrating and validating spatially distributed soil erosion models are, to a large extent, due to the large spatial and temporal variability of soil erosion phenomena and the uncertainty associated with the input parameter values used in models to predict these processes. They will, therefore, not be solved by constructing even more complete, and therefore more complex, models. However, the situation may be improved by using more spatial information for model calibration and validation rather than output data only and by using ,optimal' models, describing only the dominant processes operating in a given landscape. Copyright © 2003 John Wiley & Sons, Ltd. [source] | |||||||||||||||||||||||||||||||||||||