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Internal Reflection (internal + reflection)
Kinds of Internal Reflection Terms modified by Internal Reflection Selected AbstractsSolar Energy Collectors with Tunable TransmissionADVANCED FUNCTIONAL MATERIALS, Issue 9 2010Michael G. Debije Abstract A new type of "smart" window is proposed that makes use of fluorescent dye guests in a liquid-crystal host sandwiched between glass panels. The dye absorbs a variable amount of light depending on its orientation, and re-emits this light, of which a significant fraction is trapped by total internal reflection at the glass,air interface, and becomes concentrated along the edges. Such a device could both generate electricity via an attached photovoltaic as well as allow user control of the amount of transmitted light. By applying a voltage across the cell, absorption could be varied 31%, while the usable light output only varied 11% due to the increased efficiency of light collection at homeotropic dye orientation. [source] Monitoring Delamination Progression in Thermal Barrier Coatings by Mid-Infrared Reflectance ImagingINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 2 2006Jeffrey I. Eldridge Mid-infrared (MIR) reflectance imaging is shown to be a reliable diagnostic tool for monitoring delamination progression in thermal barrier coatings (TBCs). MIR reflectance imaging utilizes the maximum transparency of TBCs in the 3,6 ,m wavelength region to probe below-surface delamination crack propagation that is typically hidden from visible wavelength inspection. The image contrast that identifies delamination progression arises from the increased reflectance produced by a large component of total internal reflection at the TBC/buried-crack interface. Imaging was performed at a wavelength of 4 ,m to take advantage of the relatively high transmittance of plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) TBCs along with a desirable relative insensitivity to potentially interfering absorptions by atmospheric constituents at that wavelength. A key advantage of MIR reflectance imaging over competing techniques is that it is sensitive to delamination progression even at very early stages before delamination cracks start linking together; therefore, TBC health assessment can be achieved throughout the life of the TBC well before TBC failure is imminent. Examples are presented to demonstrate monitoring delamination progression by MIR reflectance imaging in 8YSZ TBC-coated specimens subjected to furnace cycling to 1163°C. The experimental results were in good agreement with reflectance values predicted by a four-flux Kulbelka,Munk approximation applied to the extreme cases of a completely adherent and a completely detached TBC. Practical considerations, including potential interfering effects from surface contamination, sintering, and erosion are discussed. [source] Detection of creatinine enriched on a surface imprinted polystyrene film using FT-ATR-IRJOURNAL OF MOLECULAR RECOGNITION, Issue 5 2006K. Sreenivasan Abstract The surface of polystyrene (PS) was chemically modified by coating a thin layer of polyaniline (PANI) by oxidizing aniline using ammonium persulfate. Affinity sites for creatinine, a clinically relevant molecule, were created in the coated layer by adding creatinine as print molecules during the oxidation. The imprinted layer adsorbed creatinine was compared to non-imprinted surface reflecting the creation of creatinine-specific sites on the surface. The equilibrium was attained rapidly, indicating that a material of this kind is suitable for sensing applications. The adsorbed creatinine on the surface was detected using the technique of Fourier transform attenuated total internal reflection infra red spectroscopy (FT-ATR-IR). The results show that molecularly imprinted surface can enrich molecules of interest and the enriched molecules can be detected using FT-IR. Copyright © 2006 John Wiley & Sons, Ltd. [source] A luminescent solar concentrator with 7.1% power conversion efficiencyPHYSICA STATUS SOLIDI - RAPID RESEARCH LETTERS, Issue 6 2008L. H. Slooff Abstract The Luminescent Solar Concentrator (LSC) consists of a transparent polymer plate, containing luminescent particles. Solar cells are connected to one or more edges of the polymer plate. Incident light is absorbed by the luminescent particles and re-emitted. Part of the light emitted by the luminescent particles is guided towards the solar cells by total internal reflection. Since the edge area is smaller than the receiving one, this allows for concentration of sunlight without the need for solar tracking. External Quantum Efficiency (EQE) and current,voltage (I ,V) measurements were performed on LSC devices with multicrystalline silicon (mc-Si) or GaAs cells attached to the sides. The best result was obtained for an LSC with four GaAs cells. The power conversion efficiency of this device, as measured at European Solar Test Installation laboratories, was 7.1% (geometrical concentration of a factor 2.5). With one GaAs cell attached to one edge only, the power efficiency was still as high as 4.6% (geometrical concentration of a factor 10). To our knowledge these efficiencies are among the highest reported for the LSC. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] The role of phonons in establishing a non-equilibrium quasiparticle state in small gap multiple tunnelling superconducting tunnel junctionsPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 11 2004A. G. Kozorezov Abstract We derive expressions for phonon escape times from a thin superconducting film. The escape time is determined by the rate of scattering conversion for phonons propagating beyond the critical cone for total internal reflection. The conversion is due to different scattering processes for the groups of Cooper pair breaking and sub-gap phonons. For pair breaking phonons the most efficient conversion mechanism is through the interaction with the condensate. For sub-gap phonons the conversion rate is much slower and for plane parallel films is due to elastic scattering at surface or interface roughness resulting in significantly slower escape times. We discuss implications of slow escape time for sub-gap phonons for the properties of the recently observed new non-equilibrium state in small gap multiple tunnelling superconducting tunnel junctions. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] When Does Deliberation Begin?POLITICAL STUDIES, Issue 4 2003Internal Reflection versus Public Discussion in Deliberative Democracy Political deliberation involves both internal reflection and public discussion. The former might be far more important than implied by deliberative democrats' heavy emphasis on the discursive component. Analysis of the deliberations of a citizen's jury on an Australian environmental issue shows jurors' attitudes changing more in response to the ,information' phase of the jury proceedings, involving a large degree of ,deliberation within', than during the formal ,discussion' phase. Various ways can be imagined for evoking internal reflection of that sort, even in mass-political settings. [source] Simulation and implementation of a porous silicon reflector for epitaxial silicon solar cellsPROGRESS IN PHOTOVOLTAICS: RESEARCH & APPLICATIONS, Issue 5 2008Filip Duerinckx Abstract One of the main challenges in the ongoing development of thin film crystalline silicon solar cells on a supporting silicon substrate is the implementation of a long-wavelength reflector at the interface between the epitaxial layer and the substrate. IMEC has developed such a reflector based on electrochemical anodization of silicon to create a multi-layer porous silicon stack with alternating high and low porosity layers. This innovation results in a 1,2% absolute increase in efficiency for screenprinted epitaxial cells with a record of 13·8%. To reach a better understanding of the reflector and to aid in its continued optimization, several extensive optical simulations have been performed using an in-house-developed optical software programme. This software is written as a Microsoft Excel workbook to make use of its user-friendliness and modular structure. It can handle up to 15 individual dielectric layers and is used to determine the influence of the number and the sequence of the layers on the internal reflection. A sensitivity analysis is also presented. A study of the angle at which the light strikes the reflector shows separate regions in the physical working of the reflector which include a region where the Bragg effect is dominant as well as a region where total internal reflection plays the largest role. The existence of these regions is proved using reflection measurements. Based on these findings, an estimate is made for the achievable current gain with an ideal reflector and the potential of epitaxial silicon solar cells is determined. Copyright © 2008 John Wiley & Sons, Ltd. [source] Large-area epitaxial silicon solar cells based on industrial screen-printing processesPROGRESS IN PHOTOVOLTAICS: RESEARCH & APPLICATIONS, Issue 8 2005Filip Duerinckx Abstract Thin-film epitaxial silicon solar cells are an attractive future alternative for bulk silicon solar cells incorporating many of the process advantages of the latter, but on a potentially cheap substrate. Several challenges have to be tackled before this potential can be successfully exploited on a large scale. This paper describes the points of interest and how IMEC aims to solve them. It presents a new step forward towards our final objective: the development of an industrial cell process based on screen-printing for >,15% efficient epitaxial silicon solar cells on a low-cost substrate. Included in the discussion are the substrates onto which the epitaxial deposition is done and how work is progressing in several research institutes and universities on the topic of a high-throughput epitaxial reactor. The industrial screen-printing process sequence developed at IMEC for these epitaxial silicon solar cells is presented, with emphasis on plasma texturing and improvement of the quality of the epitaxial layer. Efficiencies between 12 and 13% are presented for large-area (98,cm2) epitaxial layers on highly doped UMG-Si, off-spec and reclaim material. Finally, the need for an internal reflection scheme is explained. A realistically achievable internal reflection at the epi/substrate interface of 70% will result in a calculated increase of 3,mA/cm2 in short-circuit current. An interfacial stack of porous silicon layers (Bragg reflectors) is chosen as a promising candidate and the challenges facing its incorporation between the epitaxial layer and the substrate are presented. Experimental work on this topic is reported and concentrates on the extraction of the internal reflection at the epi/substrate interface from reflectance measurements. Initial results show an internal reflectance between 30 and 60% with a four-layer porous silicon stack. Resistance measurements for majority carrier flow through these porous silicon stacks are also included and show that no resistance increase is measurable for stacks up to four layers. Copyright © 2005 John Wiley & Sons, Ltd. [source] An international and multidisciplinary drilling project into a young complex impact structure: The 2004 ICDP Bosumtwi Crater Drilling Project,An overviewMETEORITICS & PLANETARY SCIENCE, Issue 4-5 2007Christian KOEBERL It is the source crater of the Ivory Coast tektites. The structure was excavated in 2.1,2.2 Gyr old metasediments and metavolcanics of the Birimian Supergroup. A drilling project was conceived that would combine two major scientific interests in this crater: 1) to obtain a complete paleoenvironmental record from the time of crater formation about one million years ago, at a near-equatorial location in Africa for which very few data are available so far, and 2) to obtain a complete record of impactites at the central uplift and in the crater moat, for ground truthing and comparison with other structures. Within the framework of an international and multidisciplinary drilling project led by the International Continental Scientific Drilling Program (ICDP), 16 drill cores were obtained from June to October 2004 at six locations within Lake Bosumtwi, which is 8.5 km in diameter. The 14 sediment cores are currently being investigated for paleoenvironmental indicators. The two impactite cores LB-07A and LB-08A were drilled into the deepest section of the annular moat (540 m) and the flank of the central uplift (450 m), respectively. They are the main subject of this special issue of Meteoritics & Planetary Science, which represents the first detailed presentations of results from the deep drilling into the Bosumtwi impactite sequence. Drilling progressed in both cases through the impact breccia layer into fractured bedrock. LB-07A comprises lithic (in the uppermost part) and suevitic impact breccias with appreciable amounts of impact melt fragments. The lithic clast content is dominated by graywacke, besides various metapelites, quartzite, and a carbonate target component. Shock deformation in the form of quartz grains with planar microdeformations is abundant. First chemical results indicate a number of suevite samples that are strongly enriched in siderophile elements and Mg, but the presence of a definite meteoritic component in these samples cannot be confirmed due to high indigenous values. Core LB-08A comprises suevitic breccia in the uppermost part, followed with depth by a thick sequence of graywacke-dominated metasediment with suevite and a few granitoid dike intercalations. It is assumed that the metasediment package represents bedrock intersected in the flank of the central uplift. Both 7A and 8A suevite intersections differ from suevites outside of the northern crater rim. Deep drilling results confirmed the gross structure of the crater as imaged by the pre-drilling seismic surveys. Borehole geophysical studies conducted in the two boreholes confirmed the low seismic velocities for the post-impact sediments (less than 1800 m/s) and the impactites (2600,3300 m/s). The impactites exhibit very high porosities (up to 30 vol%), which has important implications for mechanical rock stability. The statistical analysis of the velocities and densities reveals a seismically transparent impactite sequence (free of prominent internal reflections). Petrophysical core analyses provide no support for the presence of a homogeneous magnetic unit (= melt breccia) within the center of the structure. Borehole vector magnetic data point to a patchy distribution of highly magnetic rocks within the impactite sequence. The lack of a coherent melt sheet, or indeed of any significant amounts of melt rock in the crater fill, is in contrast to expectations from modeling and pre-drilling geophysics, and presents an interesting problem for comparative studies and requires re-evaluation of existing data from other terrestrial impact craters, as well as modeling parameters. [source] The nearly aligned rotating-monoplate compensatorPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 4 2008M. Asar Abstract A rotating-compensator polarimeter with a misaligned monoplate compensator generates first, third, and fifth harmonics as well as the zeroth (dc), second, and fourth harmonics that provide information about the sample. We outline a general procedure for calculating the detected intensity with mis- aligned components, then provide some results where multiple internal reflections in the component are ignored. The analysis involves several orders of tensors, and a quartic secular equation instead of the usual quadratic of a quadratic. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Lisiguangite, CuPtBiS3, a New Platinum-Group Mineral from the Yanshan Mountains, Hebei, ChinaACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 2 2009Zuxiang YU Abstract: Lisiguangite, CuPtBiS3, is a new mineral species discovered in a PEG-bearing, Co-Cu sulfide vein in garnet pyroxenite of the Yanshan Mountains, Chengde Prefecture, Hebei Province, China. It is associated with chalcopyrite and bornite, galena, minor pyrite, carrolite, molybdenite and the platinum-group minerals daomanite (CuPtAsS2), Co-bearing malanite (Cu(Pt, Co)2S4) sperrylite, moncheite, cooperite and malyshevite (CuPdBiS3), rare damiaoite (Pt2In3) and yixunite (Pt3In). Lisiguangite occurs as idiomorphic crystals, tabular or lamellae (010) and elongated [100] or as aggregates, up to 2 mm long and 0.5 mm wide. The mineral is opaque, has lead-gray color, black streak and metallic luster. The mineral is non-fluorescent The observed morphology displays the following forms: pinacoids {100}, {010}, {001}, and prism {110}. No twining is observed. The a:b:c ratio, calculated from unit-cell parameters, is 0.6010:1:0.3836. Cleavage: {010} perfect, {001} distinct, {100} may be visible. H Mohs: 2½ VHN25= 46.7,49.8 (mean 48.3) kg/mm2. Tenacity: brittle. Lisiguangite is bright white with a yellowish tint In reflected light it shows neither internal reflections nor bireflectance or pleochroism. It has weak to moderate anisotropy (blue-greenish to brownish) and parallel-axial extinction. The reflectance values in air (and in oil) for R3, R4 and (imR3, imR4), at the standard Commission on Ore Mineralogy wavelengths are: 37.5, 35.7 (23.4, 22.3) at 470 nm; 38.6, 36.5 (23.6, 22.6) at 546 nm; 39.4, 37.5 (23.6, 22.7) at 589 nm and 40.3, 38.2 (23.7, 22.9) at 650 nm. The average of eight electron-microprobe analyses: Cu 12.98, Pt 30.04, Pd 2.69, Bi 37.65 and S 17.55, totaling 100.91%, corresponding to Cu1.10(Pt0.83, Pd0.14),0.97Bi0.97S2.96 based on six atoms apfu. The ideal formula is CuPtBiS3. The mineral is orthorhombic. Space group: P212121, a= 7.7152(15)Å, b= 12.838(3) Å, c= 4.9248(10)Å, V= 487.80(17)Å3, Z= 4. The six strongest lines in the X-ray powder-diffraction pattern [d in Å (I) (h k l) are 6.40(30)(020), 3.24(80)(031), 3.03(100)(201), 2.27(40)(051), 2.14(50)(250), 1.865(60)(232). [source] | |||||||||||||