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Terms modified by Inner Selected AbstractsTemplate Synthesis of Aligned Carbon Nanotube Arrays using Glucose as a Carbon Source: Pt Decoration of Inner and Outer Nanotube Surfaces for Fuel-Cell Catalysts,ADVANCED FUNCTIONAL MATERIALS, Issue 6 2008Zhenhai Wen A facile method is developed to synthesize aligned arrays of open-ended carbon nanotubes (CNTs) via in situ glucose polymerization in the inner pores of anodic aluminum oxide templates under hydrothermal conditions, followed by carbonization at high temperature. Pt nanoparticles are decorated on the surfaces of the as-prepared CNTs using the incipient wet method based on the use of NaBH4 as a reductant. Characterization of the resulting structures by transmission electron microscopy and field-emission scanning electron microscopy demonstrates that the Pt nanoparticles are anchored on both the inner and outer walls of CNTs, thus giving rise to a shell,core,shell-like nanotube composite. The electrocatalytic properties of the Pt,CNT,Pt electrodes are investigated for methanol oxidation by cyclic voltammetry and chronoamperometric measurements. It is found that the hybrid electrodes show superior catalytic performance compared to commercial carbon-black-supported Pt. The increased catalytic efficiency of Pt might be a result of the unique morphology of these structures. [source] The Relation of Patterns of Coping of Inner,City Youth to Psychopathology SymptomsJOURNAL OF RESEARCH ON ADOLESCENCE, Issue 4 2002Patrick H. Tolan This study provides empirical verification that variations in patterns of coping can explain current and future functioning of youth. The study evaluated the methods and styles of coping of inner,city youth and their relation to age, gender, ethnicity, stress levels, and internalizing and externalizing symptom levels. Three hundred seventy,two 12, to 16,year,old adolescents from inner,city schools (67.0% African American, 24.4% Hispanic; 53.41% males) participated. One hundred forty,nine were also included in a follow,up evaluation of the prospective relation of coping to functioning. A seven,factor model of coping methods was identified and found to be applicable across age groups, genders, and ethnic groups. The model was robust over time. Coping methods were categorized through cluster analysis into five styles. Styles were found to relate somewhat to demographic characteristics and stress levels. Controlling for demographic characteristics and stress levels, coping style related concurrently and prospectively to internalizing and externalizing symptom levels. Except in one instance, age, ethnicity, and gender did not interact with coping in predicting symptoms. Implications for further coping research and risk and intervention design are discussed. [source] Residual stress analysis of an autofrettaged compound cylinder under machining processMATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK, Issue 3 2009E.-Y. Lee Autofrettage; Schrumpfpassung; Verbundzylinder; Bearbeitungsprozess Abstract The autofrettage process is used to manufacture pressure vessels and cylinders that can withstand high internal pressure. A multi-layered cylinder was assembled by a shrink fit. Autofrettaged compound cylinder can resist higher internal pressure than a thick cylinder having the same dimension and extend its life time. Inner and outer surfaces of the autofrettaged compound cylinder have to be manufactured into exact dimensions. The distribution of residual stress can change after the machining process. The machining procedure of inner and outer surfaces also affects the distribution of residual stress as a function of the machining procedure. In this study, the distribution of residual stresses of an autofrettaged compound cylinder as machining procedure was investigated using analytical and numerical analyses. [source] Handwritten Thai Character Recognition Using Fourier Descriptors and Genetic Neural NetworksCOMPUTATIONAL INTELLIGENCE, Issue 3 2002Pisit Phokharatkul This article presents a method to solve the rotated and scaling character recognition problem using Fourier descriptors and genetic neural networks. The contours of character image are extracted and separated between the outer contour and inner or loop contours. The loop contours are a special characteristic of Thai characters, called the head of the character. The special features of Thai characters (loop contours) are used at the rough classification stage, and Fourier descriptors with genetic neural networks are used at the fine classification stage. The Fourier descriptors detect the outer contour of a character and it is fed to network. These features are recognized by a multilayer neural network. Genetic algorithms (GAs) are utilized to help compute the weights of the neural network optimally and reduce uncertain states in the neural networks output. Experimental results have shown that the combination of the Fourier descriptors with genetic neural networks, loop features, and local curvature charateristics of similar characters are powerful tools for successfully classifying Thai characters. The recognition rate by this method is 99.12% for 1200 examples of handwritten Thai words (a total of 13,500 characters) written by 60 persons. [source] Scene Graph and Frame Update Algorithms for Smooth and Scalable 3D Visualization of Simulated Construction OperationsCOMPUTER-AIDED CIVIL AND INFRASTRUCTURE ENGINEERING, Issue 4 2002Vineet R. Kamat One of the prime reasons inhibiting the widespread use of discrete-event simulation in construction planning is the absence of appropriate visual communication tools. Visualizing modeled operations in 3D is arguably the best form of communicating the logic and the inner working of simulation models and can be of immense help in establishing the credibility of analyses. New software development technologies emerge at incredible rates that allow engineers and scientists to create novel, domain-specific applications. The authors capitalized on a computer graphics technology based on the concept of the scene graph to design and implement a general-purpose 3D visualization system that is simulation and CAD-software independent. This system, the Dynamic Construction Visualizer, enables realistic visualization of modeled construction operations and the resulting products and can be used in conjunction with a wide variety of simulation tools. This paper describes the scene graph architecture and the frame updating algorithms used in designing the Dynamic Construction Visualizer. [source] Simulating the Role of Intrinsic Carbon Impurities in the Divertor Detachment of ASDEX UpgradeCONTRIBUTIONS TO PLASMA PHYSICS, Issue 1-3 2008M. Wischmeier Abstract As part of a general effort in validating SOL fluid Monte Carlo codes, well diagnosed ohmic discharges have been done in ASDEX Upgrade reaching from the lowest accessible density up to densities at which both targets were at least partially detached. The numerical code B2.5-EIRENE has been used to simulate these experiments with a particular focus on detachment. Whilst it is possible to qualitatively reproduce the general experimental observations when transiting from attached to detached plasmas, the simulations do not reproduce the detachment threshold observed in experiment quantitatively. The strong asymmetry of the ion flux density between the inner and the outer target with increasing density and in particular the vanishing ion flux, defined as full detachment, at the inner target cannot be reproduced. The influence of various parameters such as chemical sputtering yields and the effect of the activation of drift terms on the results is analyzed. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Journeys of Expansion and Synopsis: Tensions in Books That Shaped Curriculum Inquiry, 1968,PresentCURRICULUM INQUIRY, Issue 1 2010WILLIAM H. SCHUBERT In honor of the 40th volume of Curriculum Inquiry, I begin by claiming that pursuit of questions about what is worthwhile, why, and for whose benefit is a (perhaps the) central consideration of curriculum inquiry. Drawing autobiographically from my experience as an educator during the past 40 years, I sketch reflections on curriculum books published during that time span. I situate my comments within both the historical backdrop that preceded the beginning of Curriculum Inquiry and the emergence of new curricular languages or paradigms during the late 1960s and early 1970s. I suggest that two orientations of curriculum books have provided a lively tension in curriculum literature,one expansive and the other synoptic,while cautiously wondering if both may have evolved from different dimensions of John Dewey's work. I speculate about the place of expansion and synopsis in several categories of curriculum literature: historical and philosophical; policy, professional, and popular; aesthetic and artistic; practical and narrative; critical; inner and contextual; and indigenous and global. Finally, I reconsider expansive and synoptic tendencies in light of compendia, heuristics, and venues that portray evolving curriculum understandings without losing the purport of myriad expansions of the literature. [source] Expression patterns of focal adhesion associated proteins in the developing retinaDEVELOPMENTAL DYNAMICS, Issue 4 2002Ming Li Abstract Adhesive interactions between integrin receptors and the extracellular matrix (ECM) are intimately involved in regulating development of a variety of tissues within the organism. In the present study, we have investigated the relationships between ,1 integrin receptors and focal adhesion associated proteins during eye development. We used specific antibodies to examine the distribution of ,1 integrin ECM receptors and the cytoplasmic focal adhesion associated proteins, talin, vinculin, and paxillin in the developing Xenopus retina. Immunoblot analysis confirmed antibody specificity and indicated that ,1 integrins, talin, vinculin, and paxillin were expressed in developing retina and in the retinal-derived Xenopus XR1 glial cell line. Triple-labeling immunocytochemistry revealed that talin, vinculin, paxillin, and phosphotyrosine proteins colocalized with ,1 integrins at focal adhesions located at the termini of F-actin filaments in XR1 cells. In the retina, these focal adhesion proteins exhibited developmentally regulated expression patterns during eye morphogenesis. In the embryonic retina, immunoreactivities for focal adhesion proteins were expressed in neuroepithelial cells, and immunoreactivity was especially strong at the interface between the optic vesicle and overlying ectoderm. At later stages, these proteins were expressed throughout all retinal layers with higher levels of expression observed in the plexiform layers, optic fiber layer, and in the region of the inner and outer limiting membrane. Strong immunoreactivities for ,1 integrin, paxillin, and phosphotyrosine were expressed in the radially oriented Müller glial cells at later stages of development. These results suggest that focal adhesion-associated proteins are involved in integrin-mediated adhesion and signaling and are likely to be essential in regulating retinal morphogenesis. © 2002 Wiley-Liss, Inc. [source] Species richness of marine Bryozoa in the continental shelf and slope off Argentina (south-west Atlantic)DIVERSITY AND DISTRIBUTIONS, Issue 1 2000Juan López Gappa Abstract., A total of 246 marine bryozoan species was recorded within an area of the south-west Atlantic between 35° and 56°S, and between the coast of Argentina and 50°W. The distribution pattern of benthic stations surveyed during the most important cruises in the area shows that the sampling effort has been biased towards southern shelf areas off Santa Cruz and Tierra del Fuego, as well as around the Malvinas (Falkland) islands. The littoral zone, Patagonian gulfs and the continental shelf off Chubut, Río Negro and Buenos Aires state received less attention, and should be surveyed more intensively in the future. Only 2% of the species can be regarded as non-indigenous, all of them inhabiting biofouling communities in harbour environments. With the exception of some thoroughly surveyed localities, the number of species recorded for different areas of the coast, shelf and slope is estimated to be just a small fraction of the actual number of species present. A distinct diversity gradient was found, with species-rich stations located only in the southern shelf. Highest diversity occurred in shelf areas dominated by coarse sediments, and along a high-productivity shelf-break front. A remarkable decrease in species richness was found in inner and middle shelf areas off Chubut, Río Negro and Buenos Aires state. This pattern may be related to the Pacific origin of the Magellanic fauna, since the diversity of bryozoans is higher in the Pacific than in the Atlantic Ocean. The trend of species richness is, however, overemphasized by the fact that the least diverse faunistic assemblage occurs in areas where surveys have been relatively less frequent. An up-to-date checklist of species recorded for the study area is included. [source] The biology and functional morphology of Arca noae (Bivalvia: Arcidae) from the Adriatic Sea, Croatia, with a discussion on the evolution of the bivalve mantle marginACTA ZOOLOGICA, Issue 1 2008Brian Morton Abstract In the Croatian Adriatic, Arca noae occurs from the low intertidal to a depth of 60 m; it can live for > 15 years and is either solitary or forms byssally attached clumps with Modiolus barbatus. The shell is anteriorly foreshortened and posteriorly elongate. The major inhalant flow is from the posterior although a remnant anterior stream is retained. There are no anterior but huge posterior byssal retractor muscles and both anterior and posterior pedal retractors. The ctenidia are of Type B(1a) and the ctenidial,labial palp junction is Category 3. The ctenidia collect, filter and undertake the primary sorting of potential food in the inhalant water. The labial palps are small with simple re-sorting tracks on the ridges of their inner surfaces. The ciliary currents of the mantle cavity appear largely concerned with the rejection of particulate material. The mantle margin comprises an outer and an (either) inner or middle fold. The outer fold is divided into outer and inner components that secrete the shell and are photo-sensory, respectively. The latter bears a large number of pallial eyes, especially posteriorly. The inner/middle mantle fold of A. noae, possibly representative of simpler, more primitive conditions, may have differentiated into distinct folds in other recent representatives of the Bivalvia. [source] Dynamics of multiple intertidal bars over semi-diurnal and lunar tidal cycles, North Lincolnshire, EnglandEARTH SURFACE PROCESSES AND LANDFORMS, Issue 10 2008Selma van Houwelingen Abstract Multiple intertidal bars are common features of wave-dominated sandy beaches, yet their short-term (<1 month) and small-scale (<1 km) morphology and dynamics remain poorly understood. This study describes the morphodynamics of multiple intertidal bars in North Lincolnshire, England, during single and lunar tidal cycles under two contrasting conditions , first when significant wave height was <0·5 m and second when significant wave height frequently exceeded 1 m. The relative importance of swash, surf and shoaling processes in determining morphological change was examined using detailed field observations and a numerical model. The beach featured four intertidal bars and both cross-shore and longshore bar morphology evolved during the field investigation, particularly under medium to high wave-energy conditions. Numerical modelling suggests shoaling processes are most common on the seaward two bars under calm wave conditions (Hs < 0·5 m) and that surf zone processes become more common during neap tides and under more energetic (Hs < 0·5 m) conditions. Surf processes dominate the inner two bars, though swash influence increases in a landward direction. The numerical modelling results combined with low tide survey data and high-resolution morphological measurements strongly suggest changes in the intertidal bar morphology are accomplished by surf zone processes rather than by shoaling wave or swash processes. This is because shoaling waves do not induce significant sediment transport to have any morphological effect, whereas swash action generally does not have enough scope to act as the swash zone is much narrower than the surf zone. It was found, however, that the absolute rate of morphological change under swash action and surfzone processes are of similar magnitudes and that swash action may induce a significant amount of local morphological change when the high tide mark is located on the upper bar, making this process important for bar morphodynamics. Copyright © 2007 John Wiley & Sons, Ltd. [source] Universal method for synthesis of artificial gel antibodies by the imprinting approach combined with a unique electrophoresis technique for detection of minute structural differences of proteins, viruses, and cells (bacteria).ELECTROPHORESIS, Issue 23 2006III: Gel antibodies against cells (bacteria) Abstract Artificial antibodies in the form of gel granules were synthesized from the monomers acrylamide and N,N'-methylenebisacrylamide by the imprinting method in the presence of Echerichia coli bacteria as template. The electrophoretic migration velocities of the gel antibodies (i),saturated with the antigen (Escherichia,coli MRE-600), (ii),freed of the antigen, and (iii),resaturated with bacteria, were determinated by electrophoresis in a rotating narrow-bore tube of 245,mm length and the 2.5 and 9.6,mm inner and outer diameters, respectively. Removal of bacteria from the gel antibodies was made by treatment with enzymes, followed by washing with SDS and buffer. Gel granules becoming charged by adsorption of bacteria move in an electrical field. We obtained a significant selectivity of gel antibodies for E.,coli MRE-600, since the granules did not interact with Lactococcus lactis; and when E.,coli BL21 bacteria were added to the gels selective for E.,coli MRE-600, a significant difference in the migration rate of the complexes formed with the two strains was observed indicating the ability of differentiation between the two strains. The gel antibodies can be used repeatedly. The new imprinting method for the synthesis of artificial gel antibodies against bioparticles described herein, and the classical electrophoretic analysis technique employed, thus represent , when combined , a new approach to distinguish between different types and strains of bacteria. The application area can certainly be extended to cover other classes of cells. [source] Application of Exchangeable Biochemical Reactors with Oxidase-Catalase-Co-immobilizates and Immobilized Microorganisms in a Microfluidic Chip-CalorimeterENGINEERING IN LIFE SCIENCES (ELECTRONIC), Issue 5 2008M. Leifheit Abstract Several methods for the quantitative detection of different compounds, e.g., L -amino acids, sugars or alcohols in liquid media were developed by application of an automatic measuring unit including a fluid chip-calorimeter FCC-21. For this purpose, enzymes were immobilized covalently on the inner and outer surface of CPG (controlled porous glass)-spherules with an outer diameter of 100,,m and filled into a micro flow-through reaction chamber (VR = 20,,L). The design of the measuring cell allows for easy insertion into the calorimeter device of a stored series of comfortably pre-fabricated measuring cells. These cells can be filled with different enzyme immobilizates. Different oxidases were used and co-immobilized with catalase for the improvement of the detection sensitivity. A signal amplification could be achieved up to a factor of 3.5 with this configuration. ,- D -glucose, ethanol and L -lysine could be detected in a range of 0.25,1.75,mM using glucose oxidase, alcohol oxidase and lysine oxidase. The group of oxidases in combination with the enzymatic catalysis of the intermediate H2O2 allows the quantitative detection of a large number of analytes. A good measurement and storage stability could be achieved for several weeks by this immobilization method. In addition to enzyme-based detection reactions, it was shown that living microorganisms can be immobilized in the reaction chamber. Thus, the system can be used as a whole-cell biosensor. The quantitative detection of phenol in the range of 10,100,,M could be performed using the actinomycete Rhodococcus sp. immobilized on glass beads by means of embedding into polymers. [source] Development of an in vitro blood,brain barrier model to study the effects of endosulfan on the permeability of tight junctions and a comparative study of the cytotoxic effects of endosulfan on rat and human glial and neuronal cell culturesENVIRONMENTAL TOXICOLOGY, Issue 3 2006Melissa P. L. Chan Abstract Endosulfan, an organochlorine (OC) insecticide that belongs to the cyclodiene group, is one of the most commonly used pesticides to control pests in vegetables, cotton, and fruits. Porcine brain microvascular endothelial cells were used to develop a model to study the effects of endosulfan on the permeability of tight junctions in the blood,brain barrier (BBB). BBB permeability, measured as transendothelial electrical resistance, decreased in a dose- and time-dependent manner when treated with ,-endosulfan, ,-endosulfan, or endosulfan sulfate. Cytotoxicity testing revealed that the three endosulfans did not cause cell death at concentrations of 10 ,M and below. The ratio of the average permeability of the filter-grown endothelial cell monolayer to 14C-endosulfan (Pe) going from the outer to the inner compartments with that going from the inner to the outer compartments was approximately 1:1.2,2.1 after exposure to concentrations of 0.01,10 ,M. ,-Endosulfan, ,-endosulfan, and endosulfan sulfate had cytotoxic effects on rat glial (C6) and neuronal (PC12) cell cultures as well as on human glial (CCF-STTG1) and neuronal (NT2) cell cultures. The effects of ,-endosulfan were highly selective, with a wide range of LC50 values found in the different cultures, ranging from 11.2 ,M for CCF-STTG1 cells to 48.0 ,M for PC12 cells. In contrast, selective neurotoxicity was not so manifest in glial and neuronal cell cultures after exposure to endosulfan sulfate, as LC50 values were in the range of 10.4,21.6 ,M. CCF-STTG1 cells were more sensitive to ,-endosulfan and endosulfan sulfate, whereas NT2 cells were more sensitive to ,-endosulfan. © 2006 Wiley Periodicals, Inc. Environ Toxicol 21: 223,235, 2006. [source] Characterizing organic matter of soil aggregate coatings and biopores by Fourier transform infrared spectroscopyEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2004R. H. Ellerbrock Summary In some soils, aggregate coatings and walls of biopores differ in the content of clay and organic carbon from that of the aggregate interiors or the soil matrix. The composition of the organic matter on aggregates and on the surfaces of biopores is largely unknown. We have compared the composition of organic matter between inner and outer parts of aggregates and between biopore walls and the soil matrix in a loamy arable soil and a sandy forest one. Hot-water- and sodium-pyrophosphate-extractable organic matter was analysed by Fourier transform infrared (FT-IR) spectroscopy. For the sandy forest soil, the FT-IR spectra showed that organic matter from the walls of root channels contains fewer functional groups with absorption bands at 1740,1710 cm,1 and 1640,1600 cm,1 than that from burrow fillings. For the arable soil, the content of these functional groups in hot-water-soluble organic matter from the coatings is less than in that from the interiors in the topsoil, and the reverse is so in the subsoil, probably because water-soluble organic matter containing these functional groups has moved from topsoil to subsoil. The results indicate that root channels in the forest soil have more reactive zones in an otherwise relatively inert sandy matrix, whereas aggregate coatings in the arable subsoil have a greater cation exchange capacity and a greater sorption potential for hydrophobic substances than the aggregate interiors. [source] Spaces of Utopia and Dystopia: Landscaping the Contemporary CityGEOGRAFISKA ANNALER SERIES B: HUMAN GEOGRAPHY, Issue 3-4 2002Gordon MacLeod Some of the most recent literature within urban studies gives the distinct impression that the contemporary city now constitutes an intensely uneven patchwork of utopian and dystopian spaces that are, to all intents and purposes, physically proximate but institutionally estranged. For instance, so,called edge cities (Garreau, 1991) have been heralded as a new Eden for the information age. Meanwhile tenderly manicured urban villages, gated estates and fashionably gentrified inner,city enclaves are all being furiously marketed as idyllic landscapes to ensure a variety of lifestyle fantasies. Such lifestyles are offered additional expression beyond the home, as renaissance sites in many downtowns afford city stakeholders the pleasurable freedoms one might ordinarily associate with urban civic life. None,the,less, strict assurances are given about how these privatized domiciliary and commercialized ,public' spaces are suitably excluded from the real and imagined threats of another fiercely hostile, dystopian environment ,out there'. This is captured in a number of (largely US) perspectives which warn of a ,fortified' or ,revanchist' urban landscape, characterized by mounting social and political unrest and pockmarked with marginal interstices: derelict industrial sites, concentrated hyperghettos, and peripheral shanty towns where the poor and the homeless are increasingly shunted. Our paper offers a review of some key debates in urban geography, planning and urban politics in order to examine this patchwork,quilt urbanism, In doing so, it seeks to uncover some of the key processes through which contemporary urban landscapes of utopia and dystopia come to exist in the way they do. [source] HAZARDS IN THE BOG,REAL AND IMAGINEDxsGEOGRAPHICAL REVIEW, Issue 3 2002DIANNE MEREDITH ABSTRACT. A rich body of geographical lore, much of it related to real or imaginary hazards, characterizes perceptions of bog landscapes. Bog bursts, will-o,-the-wisps, carnivorous plants, weird creatures, and perceptions of the "bottomless" bog all play a part in the folklore of the landscapes. Ambiguity about the features of bog landscapes is further heightened by the descriptive terminology employed by tale tellers, who present to us a world inhabited by meanings that go beyond the physical environment and touch on the primordial inner landscape. [source] ,-diversity fluctuations in Early,Mid Ordovician brachiopod communities of South ChinaGEOLOGICAL JOURNAL, Issue 3-4 2006R.-B. Zhan Abstract Lower to Middle Ordovician transitional strata (Acrograptus filiformis Biozone to Exigraptus clavus Biozone) of the Upper Yangtze Platform contain rich and diverse brachiopods, particularly in the Daguanshan Formation of Sichuan Province, the Meitan Formation of Guizhou Province, and the Yingpan Formation of Houping, Chongqing City. On the basis of multivariate analyses of 207 samples (about 15,000 brachiopod specimens) and 61 species from these strata, 23 brachiopod-dominated communities and associations are delineated through six graptolitic biozones (Acrograptus filiformis to Exigraptus clavus biozones). The disparity of brachiopod associations or ,-diversity, as measured by the number of contemporaneous associations across variable ecological settings, was low in the A. filiformis Biozone and increased through the overlying graptolitic biozones to reach an acme in the Azygograptus suecisus and Expansograptus hirundo biozones, where as many as nine different brachiopod associations thrived in mid-shelf and also established in inner- and outer-shelf environments. Despite a sharp increase in ,-diversity within the Didymograptellus eobifidus Biozone, ,-diversity remained relatively low, with only three distinct brachiopod communities. The diversity of brachiopod associations suffered an abrupt drop in the E. clavus Biozone, as a result of a major faunal turnover event, with only a single Metorthis Community present in an upper mid-shelf setting. Temporally, brachiopod associations appear to be most stable in mid-shelf settings, with the Paralenorthis, Sinorthis, Desmorthis, and Euorthisina communities having a relatively high ,-diversity and lasting through two to five graptolitic biozones. In both species composition and temporal duration, the brachiopod associations at the shallow- (BA1 to upper BA2) and deep-shelf (BA4) settings are unstable, characterized by low ,-diversity and rapid vertical changes. This study implies that, during the Early and Mid Ordovician, brachiopod communities already attained a high level of organization in mid-shelf settings, but remained poorly established in high-stress environments of very shallow or very deep shelf settings. Copyright © 2006 John Wiley & Sons, Ltd. [source] Reactive Template Method to Synthesize Gold Nanoparticles with Controllable Size and Morphology Supported on Shells of Polymer Hollow Microspheres and Their Application for Aerobic Alcohol Oxidation in WaterADVANCED FUNCTIONAL MATERIALS, Issue 7 2009Jie Han Abstract A novel method has been developed to synthesize gold nanoparticles with tunable size and morphology supported on both inner and outer surfaces of poly(o -phenylenediamine) (PoPD) hollow microspheres, which act as both reductant and template/stabilizer. The size of gold nanoparticles supported on shells of PoPD hollow microspheres can be tuned from 3 to 15,nm by changing the concentration of the gold source, HAuCl4. Gold nanorods supported on shells of PoPD hollow microspheres can also be fabricated by introducing a well-known seed-growth strategy. In addition, silver nanoparticles supported on shells of PoPD hollow microspheres can also be successfully fabricated using the same strategy, which indicates the diversity of this proposed method for polymer hollow microspheres supporting noble metal nanoparticles. The products are characterized by X-ray diffraction and contact angle analysis. Furthermore, the catalytic activity of the obtained PoPD-microsphere-supported gold nanoparticles for aerobic alcohol oxidation is investigated. The results demonstrate that such polymer-supported gold nanoparticles can be used as reusable catalysts with high catalytic activity for aerobic alcohol oxidation in water. [source] Expression of glial fibrillary acidic protein and glutamine synthetase by Müller cells after optic nerve damage and intravitreal application of brain-derived neurotrophic factorGLIA, Issue 2 2002Hao Chen Abstract Müller glia play an important role in maintaining retinal homeostasis, and brain-derived neurotrophic factor (BDNF) has proven to be an effective retinal ganglion cell (RGC) neuroprotectant following optic nerve injury. The goal of these studies was to investigate the relation between optic nerve injury and Müller cell activation, and to determine the extent to which BDNF affects the injury response of Müller cells. Using immunocytochemistry and Western blot analysis, temporal changes in the expression of glial fibrillary acidic protein (GFAP) and glutamine synthetase (GS) were examined in rats after optic nerve crush alone, or in conjunction with an intravitreal injection of BDNF (5 ,g). GFAP protein levels were normal at 1 day post-crush, but increased ,9-fold by day 3 and remained elevated over the 2-week period studied. Müller cell GS expression remained stable after optic nerve crush, but the protein showed a transient shift in its cellular distribution; during the initial 24-h period post-crush the GS protein appeared to translocate from the cell body to the inner and outer glial processes, and particularly to the basal endfeet located in the ganglion cell layer. BDNF alone, or in combination with optic nerve crush, did not have a significant effect on the expression of either GFAP or GS compared with the normal retina, or after optic nerve crush alone, respectively. The data indicate that although BDNF is a potent neuroprotectant in the vertebrate retina, it does not appear to have a significant influence on Müller cell expression of either GS or GFAP in response to optic nerve injury. GLIA 38:115,125, 2002. © 2002 Wiley-Liss, Inc. [source] Template Synthesis of Aligned Carbon Nanotube Arrays using Glucose as a Carbon Source: Pt Decoration of Inner and Outer Nanotube Surfaces for Fuel-Cell Catalysts,ADVANCED FUNCTIONAL MATERIALS, Issue 6 2008Zhenhai Wen A facile method is developed to synthesize aligned arrays of open-ended carbon nanotubes (CNTs) via in situ glucose polymerization in the inner pores of anodic aluminum oxide templates under hydrothermal conditions, followed by carbonization at high temperature. Pt nanoparticles are decorated on the surfaces of the as-prepared CNTs using the incipient wet method based on the use of NaBH4 as a reductant. Characterization of the resulting structures by transmission electron microscopy and field-emission scanning electron microscopy demonstrates that the Pt nanoparticles are anchored on both the inner and outer walls of CNTs, thus giving rise to a shell,core,shell-like nanotube composite. The electrocatalytic properties of the Pt,CNT,Pt electrodes are investigated for methanol oxidation by cyclic voltammetry and chronoamperometric measurements. It is found that the hybrid electrodes show superior catalytic performance compared to commercial carbon-black-supported Pt. The increased catalytic efficiency of Pt might be a result of the unique morphology of these structures. [source] The heat transfer heterogeneities of bends in flow boiling of hairpin tubesHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 8 2009Meng Meng Abstract A series of visual experiments were conducted for liquid, vapor two-phase flow in hairpin tubes, and it was observed that most of the nucleation sites were located at the outer tube wall of the bend. From the simulation, it was concluded that the uneven velocity distribution in the bend induced the heat transfer heterogeneity. Furthermore, the nucleation of both the inner and outer tube wall of the bend and the wall temperature distribution were discussed to understand the physical phenomena. © 2009 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20269 [source] Heat transfer characteristics between inner and outer rings of an angular ball bearingHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 1 2003Keiji Mizuta Abstract Heat transfer between the inner and the outer rings of an angular ball bearing is investigated experimentally and heat transport by balls is analyzed theoretically. The bearing used is lubricated by oil and rotated in the range from 600 to 4000 rpm. Considering heat generation by friction, the net heat flow between the rings is evaluated. The results show that balls are the dominant heat carrier and their conductance depends on rotational speed and thrust force. The other heat transfer route is supposed mainly to be between the rings based on the fact that its heat flow rate depends on the rotational speed. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 32(1): 42,57, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.10070 [source] Shaping ability of ProFile and K3 rotary Ni-Ti instruments when used in a variable tip sequence in simulated curved root canalsINTERNATIONAL ENDODONTIC JOURNAL, Issue 9 2004L. R. Ayar Abstract Aim, To compare the shaping ability of ProFile and K3 rotary Ni-Ti instruments when used in a variable tip sequence in simulated curved root canals with different curvature and radius. Methodology, ProFile or K3 .06 taper instruments were used to prepare simulated canals of 20° curvature and 5 mm radius (n = 10) and 30° curvature and 3 mm radius canals (n = 10) in resin blocks. All canals were prepared to an apical size 40 at 0.5 mm from the canal terminus using a variable tip crown-down sequence. Pre- and postinstrumentation digital images were recorded, and an assessment of the canal shape was determined using a computer image analysis program. The material removal from the inner and outer wall of the canal was measured at 28 measuring points, beginning 0.5 mm from the end-point of the canal and the data compared using the Mann,Whitney U -test. Results, In 20° and 30° canals both instruments significantly removed more (P < 0.05) material on the outer wall than the inner wall in the apical half of the canal. For ProFile files there was no significant difference in the amount of material removed on the outer canal wall between the 20° and 30° canals. However, in the K3 groups significantly more (P < 0.05) outer canal wall was removed in the apical area in 20° canals. When comparing both instruments the results showed that in 20° canals K3 instruments removed more outer and inner canal wall than ProFile instruments (P < 0.05) but that there was no significant difference (P > 0.05) between the instruments in 30° canals. Conclusion, Within the limitation of this study, both rotary nickel-titanium instruments prepared a well-shaped root canal with minimal canal transportation. [source] An in vitro comparison of canal preparation using two automated rotary nickel,titanium instrumentation techniquesINTERNATIONAL ENDODONTIC JOURNAL, Issue 4 2000S. J. Jardine Abstract Aim The aim of this study was to compare the efficacy of root canal preparation using two automated rotary nickel,titanium instrumentation techniques with a double flared balanced forces hand preparation technique, using stainless steel files in extracted human teeth. Methodology Sixty root canals in extracted human teeth were matched for curvature, length and diameter and divided evenly between three groups (group 1 = double flare using Flexofiles®, group 2 = rotary nickel,titanium using McXIM® instruments and group 3 = rotary nickel,titanium using Profile® .04 TaperTM Series 29 instruments). The instruments were used according to the manufacturer's instructions in a torque controlled motor and handpiece (groups 2 and 3) and according to a predetermined procedure in group 1. A standardized radiographic technique using mercury as a contrast medium was used to evaluate the canal shape before and after preparation in the plane of maximum curvature. The pre- and postoperative radiographic images were compared against each other and with a predicted ,ideal preparation' calculated from a projection of the final instrument dimensions. The outcome measures were changes in canal dimensions as quantified by measuring the changes in the position of the inner and outer wall at 1 mm intervals. Alteration in canal curvature could be inferred by comparison with the ideal preparation. Results The degree of canal curvature did not influence the effectiveness of any of the techniques. The results showed no statistically significant differences in the outcome measures between the groups (two-way anova). There were no significant differences in canal wall position changes at any level except the apical three, where significantly less change occurred in all groups (P = 1%). Instruments fractured in three canals, with acute curves in groups 2 and 3. Conclusions Canal curvatures were equally and well maintained following preparation in all the groups, as long as the instrument did not fracture. [source] Shaping ability of Hero 642 rotary nickel,titanium instruments in simulated root canals: Part 2INTERNATIONAL ENDODONTIC JOURNAL, Issue 3 2000S. A. Thompson Abstract Aim To determine the shaping ability of Hero 642 nickel,titanium rotary instruments during the preparation of simulated canals. Methodology A total of 40 simulated root canals made up of four different shapes, in terms of angle and position of curvature, were prepared by Hero 642 instruments using a crown-down preparation sequence. Pre- and postoperative images of the canals were taken using a video camera attached to a computer with image analysis software. The pre- and postoperative views were superimposed to highlight the amount and position of material removed during preparation. This report describes the efficacy of the instruments in terms of prevalence of canal aberrations, the amount and direction of canal transportation and overall postoperative shape. Results Four zips and four elbows were created during preparation, all in canals with 40°, 12 mm curves. No perforations or danger zones were created. Highly significant differences (P < 0.001) were apparent between the canal shapes in total canal width at the apex and beginning of the curve, and in the amount of resin removed from the inner and outer aspects of the curve at the orifice. Canal transportation was most frequently directed toward the outer aspect of the curve at specific points along the canal, except at the orifice, where it was apparent that canals with 20° curves transported toward the inner. Overall, mean absolute transportation was always less than 0.15 mm; however, significant differences occurred between canal shapes at the end-point (P < 0.01), apex of the curve (P < 0.01) and at the orifice (P < 0.01). Conclusions Under the conditions of this study, Hero 642 rotary nickel,titanium instruments created canals with few aberrations and no perforations. The relatively high proportion of aberrations in canals with short, acute curves may indicate that instruments with increased taper should be used with caution at or near the full working distance. Further research in real teeth is necessary to elucidate the full potential of these new rotary instruments for use in root canal preparation. [source] Performance analysis of IDEAL algorithm for three-dimensional incompressible fluid flow and heat transfer problemsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 10 2009Dong-Liang Sun Abstract Recently, an efficient segregated algorithm for incompressible fluid flow and heat transfer problems, called inner doubly iterative efficient algorithm for linked equations (IDEAL), has been proposed by the present authors. In the algorithm there exist inner doubly iterative processes for pressure equation at each iteration level, which almost completely overcome two approximations in SIMPLE algorithm. Thus, the coupling between velocity and pressure is fully guaranteed, greatly enhancing the convergence rate and stability of solution process. However, validations have only been conducted for two-dimensional cases. In the present paper the performance of the IDEAL algorithm for three-dimensional incompressible fluid flow and heat transfer problems is analyzed and a systemic comparison is made between the algorithm and three other most widely used algorithms (SIMPLER, SIMPLEC and PISO). By the comparison of five application examples, it is found that the IDEAL algorithm is the most robust and the most efficient one among the four algorithms compared. For the five three-dimensional cases studied, when each algorithm works at its own optimal under-relaxation factor, the IDEAL algorithm can reduce the computation time by 12.9,52.7% over SIMPLER algorithm, by 45.3,73.4% over SIMPLEC algorithm and by 10.7,53.1% over PISO algorithm. Copyright © 2009 John Wiley & Sons, Ltd. [source] Large eddy simulation of turbulent concentric annular channel flowsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 12 2004Nan-Sheng Liu Abstract Fully developed turbulent concentric annular channel flow has been investigated numerically by use of large eddy simulation (LES) technique coupled with a localized one-equation dynamic subgrid-scale (SGS) model. The objective of this study is to deal with the behaviour of turbulent flow near the inner and outer walls of the concentric annular channel and to examine the effectiveness of LES technique for predicting the turbulent flow influenced by the transverse curvature effect. The computations are performed for the Reynolds number Re,=180, 395 and 640, based on an averaged friction velocity and the annular channel width with the inner and outer cylinder radius being Ri=1 and Ro=2. To validate the present approach, calculated results for turbulent pipe flow and concentric annular channel flow are compared with available experimental data and direct numerical simulation results, which confirms that the present approach can be used to study turbulent concentric annular channel flow satisfactorily. To elucidate turbulence characteristics in the concentric annular channel, some typical quantities, including the resolved velocity, turbulence intensity, turbulent eddy viscosity, SGS kinetic energy, SGS dissipation rate, Reynolds stress budgets, and turbulence structures based on the velocity fluctuations, are analysed. Copyright © 2004 John Wiley & Sons, Ltd. [source] Computations of two passing-by high-speed trains by a relaxation overset-grid algorithmINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 12 2004Jenn-Long Liu Abstract This paper presents a relaxation algorithm, which is based on the overset grid technology, an unsteady three-dimensional Navier,Stokes flow solver, and an inner- and outer-relaxation method, for simulation of the unsteady flows of moving high-speed trains. The flow solutions on the overlapped grids can be accurately updated by introducing a grid tracking technique and the inner- and outer-relaxation method. To evaluate the capability and solution accuracy of the present algorithm, the computational static pressure distribution of a single stationary TGV high-speed train inside a long tunnel is investigated numerically, and is compared with the experimental data from low-speed wind tunnel test. Further, the unsteady flows of two TGV high-speed trains passing by each other inside a long tunnel and at the tunnel entrance are simulated. A series of time histories of pressure distributions and aerodynamic loads acting on the train and tunnel surfaces are depicted for detailed discussions. Copyright © 2004 John Wiley & Sons, Ltd. [source] Annular liquid jets at high Reynolds numbersINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 2 2003G. Georgiou Abstract The flow of annular liquid jets at high Reynolds numbers is analysed by means of the finite element method and the full-Newton iteration scheme. Results have been obtained for various values of the inner to the outer diameter ratio and for non-zero surface tension, using extremely long meshes. The annular film moves far from the symmetry axis at low values of the Reynolds number. At higher Reynolds numbers, the film moves towards the axis of symmetry and appears close to very far downstream, forming a round jet. Asymptotic results for the radius of the resulting round jet are provided. Copyright © 2003 John Wiley & Sons, Ltd. [source] | |||||||||||||||||||||||||||||||||||||||||||||||||||||||