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Impurity Concentration (impurity + concentration)
Selected AbstractsSpin-lattice relaxation of spin-½ nuclei in solids containing diluted paramagnetic impurity centers.CONCEPTS IN MAGNETIC RESONANCE, Issue 1 2003Abstract Dynamic nuclear polarization of nuclear spins via the solid-state and thermal mixing effects is discussed. Continuous-wave S- and X-band microwave radiation have been employed to measure 13C signal enhancements and polarization times for 13C nuclei in a natural type Ib diamond as a function of magnetic field. It was found that thermal mixing plays an important role in the 13C signal enhancement because the central electron spin resonance (ESR) line width HL , H0,C/,e, resulting in flip-flip and flip-flop forbidden transitions taking place simultaneously. On the other hand, the 13C spin-lattice relaxation rate is determined to a large extent by the solid-state effect (forbidden transitions). 13C polarization rates have also been measured for a suite of natural diamonds. It is shown that the polarization rate is proportional to the paramagnetic impurity concentration, in agreement with the theory. © 2003 Wiley Periodicals, Inc. Concepts Magn Reson 19A: 36,43, 2003. [source] Spin-lattice relaxation of spin-½ nuclei in solids containing diluted paramagnetic impurity centers.CONCEPTS IN MAGNETIC RESONANCE, Issue 1 2003Abstract Dynamic nuclear polarization of nuclei by means of paramagnetic electron spin locking (Hartmann-Hahn cross-polarization between paramagnetic electrons and nuclei, or NOVEL) is discussed. The theory is demonstrated by experiments executed at 2.4 and 9.6 GHz on a natural type Ib diamond. It is shown that the 13C polarization rate is independent of the microwave frequency, in agreement with theory. NOVEL polarization takes place only while the spin-locking pulse is on. The rate at which the nuclei are polarized is proportional to the electron polarization in the rotating frame. Therefore, the length of the spin-locking pulse is limited by the value of T1,(e), and because T1,(e) , T1(e) for diamond the effective NOVEL polarization rate of 13C nuclei is usually relatively low. A comparison between the relative effectiveness of 13C polarization rates between NOVEL and the solid-state effect is made for high and low paramagnetic impurity concentrations. The dependence of the 13C polarization rate on the paramagnetic impurity concentration has been determined for a suite of natural diamonds. © 2003 Wiley Periodicals, Inc. Concepts Magn Reson 19A: 44,49, 2003. [source] Silicon crystal growth from the melt: Analysis from atomic and macro scalesCRYSTAL RESEARCH AND TECHNOLOGY, Issue 4-5 2005K. Kakimoto Abstract The effect of impurity concentration on thermal conductivity of natural and isotope silicon by using equilibrium molecular dynamics simulation is investigated. It was found that the concentrations of the impurities such as boron, phosphor and arsene play an important role in the propagation of phonons in silicon crystals. It was also clarified that a mass difference of impurities and host crystals results in degradation of thermal conductivity of silicon. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Electrical Conductivities of (CeO2)1,x(Y2O3)x Thin FilmsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2002Chunyan Tian Electrical properties of CeO2 thin films of different Y2O3 dopant concentration as prepared earlier were studied using impedance spectroscopy. The ionic conductivities of the films were found to be dominated by grain boundaries of high conductivity as compared with that of the bulk ceramic of the same dopant concentration sintered at 1500°C. The film grain-boundary conductivities were investigated with regard to grain size, grain-boundary impurity segregation, space charge at grain boundaries, and grain-boundary microstructures. Because of the large grain boundary and surface area in thin films, the impurity concentration is insufficient to form a continuous highly resistive Si-rich glassy phase at grain boundaries, such that the resistivity associated with space-charge layers becomes important. The grain-boundary resistance may originate from oxygen-vacancy-trapping near grain boundaries from space-charge layers. High-resolution transmission electron microscopy coupled with a trans-boundary profile of electron energy loss spectroscopy gives strong credence to the space-charged layers. Since the conductivities of the films were observed to be independent of crystallographic texture, the interface misorientation contribution to the grain-boundary resistance is considered to be negligible with respect to those of the impurity layer and space-charge layers. [source] Magnetic impurity transition in a (d,+,s)-wave superconductorPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 3 2010L. S. BorkowskiArticle first published online: 8 FEB 2010 Abstract We consider the superconducting state of symmetry with finite concentration of Anderson impurities in the limit . The model consists of a BCS-like term in the Hamiltonian and the Anderson impurity treated in the self-consistent large- N mean field approximation. Increasing impurity concentration or lowering the ratio drives the system through a transition from a state with two sharp peaks at low energies and exponentially small density of states at the Fermi level to one with . This transition is discontinuous if the energy of the impurity resonance is the smallest energy scale in the problem. [source] Spin-lattice relaxation of spin-½ nuclei in solids containing diluted paramagnetic impurity centers.CONCEPTS IN MAGNETIC RESONANCE, Issue 1 2003Abstract Dynamic nuclear polarization of nuclei by means of paramagnetic electron spin locking (Hartmann-Hahn cross-polarization between paramagnetic electrons and nuclei, or NOVEL) is discussed. The theory is demonstrated by experiments executed at 2.4 and 9.6 GHz on a natural type Ib diamond. It is shown that the 13C polarization rate is independent of the microwave frequency, in agreement with theory. NOVEL polarization takes place only while the spin-locking pulse is on. The rate at which the nuclei are polarized is proportional to the electron polarization in the rotating frame. Therefore, the length of the spin-locking pulse is limited by the value of T1,(e), and because T1,(e) , T1(e) for diamond the effective NOVEL polarization rate of 13C nuclei is usually relatively low. A comparison between the relative effectiveness of 13C polarization rates between NOVEL and the solid-state effect is made for high and low paramagnetic impurity concentrations. The dependence of the 13C polarization rate on the paramagnetic impurity concentration has been determined for a suite of natural diamonds. © 2003 Wiley Periodicals, Inc. Concepts Magn Reson 19A: 44,49, 2003. [source] In situ measurement of growth kinetics of {100} KDP crystal faces in the presence of polyphosphate impuritiesCRYSTAL RESEARCH AND TECHNOLOGY, Issue 7 2008Bing Liu Abstract The face growth rate and critical supersaturation of {100} face were in situ measured using the laser-polarization-interference technique in the presence of potassium pyrophosphate, trimetric sodium phosphate and sodium hexametaphosphate impurities. The polyphosphate impurities inhibit the growth rate of prismatic faces. The face growth rate as a function of supersaturation at different impurity concentrations, as well as critical supersaturation as a function of impurity concentrations, was found in good agreement with a two-dimensional nucleation model in the pure system and Kubota and Mullin's model in the presence of impurities. The average distance L between active sites available for impurity adsorption as well as the edge free energy was calculated. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Oxygen Grain-Boundary Diffusion in Polycrystalline Mullite CeramicsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 12 2004Peter Fielitz Oxygen tracer diffusivities of low- and high-alumina mullite ceramics (72 wt% Al2O3, 28 wt% SiO2 and 78 wt% Al2O3, 22 wt% SiO2, respectively) were determined. Gas/solid exchange experiments were conducted in an atmosphere enriched in the rare stable isotope 18O, and the resulting 18O isotope depth distributions were analyzed using SIMS depth profiling. The investigation showed that grain-boundary diffusivities for both mullite ceramics were several orders of magnitude higher than mullite volume diffusivity. Activation enthalpies of oxygen diffusion were 363 ± 25 kJ/mol for the low-alumina and 548 ± 46 kJ/mol for the high-alumina materials. Because the glassy grain-boundary films were not identified, the differences between the low- and high-alumina materials might be explained by different impurity concentrations in the grain boundaries of the two materials. [source] 3D Monte Carlo simulation including full Coulomb interaction under high electron concentration regimesPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 1 2008Tadayoshi Uechi Abstract We construct 3D Monte Carlo (MC) simulations including the full Coulomb interaction as accurately as possible. In order to achieve this goal, the usual strategy for the MC approach is employed; the Coulomb potential is split into the long-range and the short-range parts. The long-range part of the Coulomb potential is taken into account by solving the Poisson equation, in which the simulation parameters such as mesh size, charged-particle size, time step etc are carefully optimized by performing the particle simulations with turning off artificially all short-ranged scatterings. The short-range part of the Coulomb potential is incorporated into the MC simulations as scattering processes by developing a new scattering model, in which the impurities are localized in real space. It is shown that the present 3D MC simulations successfully explain the entire regime of the electron mobility as a function of impurity concentrations. In addition, it is found for the first time that the plasma frequency is modulated due to localization of the background impurities. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] |