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Analytical Errors (analytical + error)
Selected AbstractsSampling and analytical plus subsampling variance components for five soil indicators observed at regional scaleEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 5 2009B. G. Rawlins Summary When comparing soil baseline measurements with resampled values there are four main sources of error. These are: i) location (errors in relocating the sample site), ii) sampling errors (representing the site with a sample of material) iii) subsampling error (selecting material for analysis) and iv) analytical error (error in laboratory measurements). In general we cannot separate the subsampling and analytical sources of error (since we always analyse a different subsample of a specimen), so in this paper we combine these two sources into subsampling plus analytical error. More information is required on the relative magnitudes of location and sampling errors for the design of effective resampling strategies to monitor changes in soil indicators. Recently completed soil surveys of the UK with widely differing soils included a duplicate site and subsampling protocol to quantify ii), and the sum of iii) and iv) above. Sampling variances are estimated from measurements on duplicate samples , two samples collected on a support of side length 20 m separated by a short distance (21 m). Analytical and subsampling variances are estimated from analyses of two subsamples from each duplicate site. After accounting for variation caused by region, parent material class and land use, we undertook a nested analysis of data from 196 duplicate sites across three regions to estimate the relative magnitude of medium-scale (between sites), sampling and subsampling plus analytical variance components, for five topsoil indicators: total metal concentrations of copper (Cu), nickel (Ni) and zinc (Zn), soil pH and soil organic carbon (SOC) content. The variance components for each indicator diminish by about an order of magnitude from medium-scale, to sampling, to analytical plus subsampling. Each of the three fixed effects (parent material, land use and region) were statistically significant for each of the five indicators. The most effective way to minimise the overall uncertainty of our observations at sample sites is to reduce the sampling variance. [source] Contextualizing Research on Social Capital in Regional ClustersINTERNATIONAL JOURNAL OF URBAN AND REGIONAL RESEARCH, Issue 3 2007UDO STABER Abstract Numerous works in economic geography and regional studies have considered social capital a salient factor in the performance of regional business clusters. Theoretical arguments have focused on those structural, relational and cognitive features of social capital that are expected to facilitate cooperation and innovation as a basis for cluster success. However, the available empirical evidence on the performance implications of social capital is weak and largely inconsistent. I argue that one reason for the observed cross-study inconsistencies is the neglect of the situational context in which social capital evolves. I discuss how acontextual studies can lead to analytical error and flawed conclusions concerning the performance outcomes of social capital. I propose several approaches to contextualizing research and discuss how they would advance our understanding of the performance implications of social capital in a cluster setting. Résumé De nombreux travaux de géographie économique et études régionales voient dans le capital social un facteur fondamental de la réussite des pôles d'entreprises régionaux. Les discussions théoriques ont porté sur les caractéristiques structurelles, relationnelles et cognitives du capital social qui sont censées faciliter coopération et innovation, composantes de base de la réussite de ces pôles. Toutefois, les preuves empiriques disponibles des implications du capital social dans cette réussite sont fragiles et peu cohérentes. Cet article affirme que les incohérences des études croisées tiennent, pour une part, à l'ignorance du contexte situationnel dans lequel évolue le capital social. Il expose comment des études hors contexte peuvent conduire à une erreur analytique et à des conclusions incorrectes quant aux résultats générés par le capital social. Il propose plusieurs approches pour placer les recherches en contexte et analyse comment, grâce à elles, nous pourrions mieux comprendre la part de réussite propre au capital social dans le cadre d'un pôle donné. [source] Deceptive hyperbilirubinaemia in a newborn with familial lipoprotein lipase deficiencyJOURNAL OF PAEDIATRICS AND CHILD HEALTH, Issue 3 2001PC Ng Abstract: A rare case of familial lipoprotein lipase (LPL) deficiency in a Chinese newborn who presented with severe hyperbilirubinaemia is described. The falsely high serum bilirubin concentration was subsequently found to be a laboratory analytical error caused by interference of optical measurement of the lipaemic serum. Hypertriglyceridaemia and chylomicronaemia could be safely and effectively controlled by a fat-restricted diet using either modified elementary milk formula fortified with protein, calories and minerals, or the commercially available special milk formula such as Monogen or Portagen. DNA sequence analysis of the patient showed a Leu252Arg mutation in exon 6 of both alleles of the LPL gene. Although the parents were unrelated, both were heterozygous carriers of the same genetic defect. Codon 252 in exon 6 appears to be a common and critical site of mutation in the LPL gene of Chinese, but this important association has not been recognized previously. [source] Effects of terrain smoothing on topographic shielding correction factors for cosmogenic nuclide-derived estimates of basin-averaged denudation ratesEARTH SURFACE PROCESSES AND LANDFORMS, Issue 1 2009Kevin P. Norton Abstract Estimation of spatially averaged denudation rates from cosmogenic nuclide concentrations in sediments depends on the surface production rates, the scaling methods of cosmic ray intensities, and the correction algorithms for skyline, snow and vegetation shielding used to calculate terrestrial cosmogenic nuclide production. While the calculation of surface nuclide production and application of latitude, altitude and palaeointensity scaling algorithms are subjects of active research, the importance of additional correction for shielding by topographic obstructions, snow and vegetation is the subject of ongoing debate. The derivation of an additional correction factor for skyline shielding for large areas is still problematic. One important issue that has yet to be addressed is the effect of the accuracy and resolution of terrain representation by a digital elevation model (DEM) on topographic shielding correction factors. Topographic metrics scale with the resolution of the elevation data, and terrain smoothing has a potentially large effect on the correction of terrestrial cosmogenic nuclide production rates for skyline shielding. For rough, high-relief landscapes, the effect of terrain smoothing can easily exceed analytical errors, and should be taken into account. Here we demonstrate the effect of terrain smoothing on topographic shielding correction factors for various topographic settings, and introduce an empirical model for the estimation of topographic shielding factors based on landscape metrics. Copyright © 2008 John Wiley and Sons, Ltd. [source] Reforming pensions: Principles, analytical errors and policy directionsINTERNATIONAL SOCIAL SECURITY REVIEW, Issue 2 2009Nicholas Barr Abstract This article, sets out a series of principles for pension design rooted in economic theory: pension systems have multiple objectives, analysis should consider the pension system as a whole, analysis should be framed in a second-best context, different systems share risks differently, and systems have different effects by generation and by gender. That discussion is reinforced by identification of a series of widespread analytical errors , errors that appear in World Bank work, but by no means only in World Bank work: tunnel vision, improper use of first-best analysis, improper use of steady-state analysis, incomplete analysis of implicit pension debt, incomplete analysis of the impact of funding (including excessive focus on financial flows, failure to consider how funding is generated, and improper focus on the type of asset in trust funds), and ignoring distributional effects. The second part of the article considers implications for policy: there is no single best pension design, earlier retirement does little or nothing to reduce unemployment, unsustainable pension promises need to be addressed directly, a move from pay-as-you-go towards funding in a mandatory system may or may not be welfare improving, and implementation matters , policy design that exceeds a country's capacity to implement it is bad policy design. We illustrate the ranges of designs of pension systems that fit the fiscal and institutional capacity constraints typical at different levels of economic development. The potential gains from simplicity imply that a country capable of implementing an administratively demanding plan does not necessarily gain from doing so. New Zealand has a simple pension system through choice, not constraint. [source] Vertical extrusion and middle crustal spreading of omphacite granulite: a model of syn-convergent exhumation (Bohemian Massif, Czech Republic)JOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2004típská Abstract The exhumation of eclogite facies granulites (Omp,Plg,Grt,Qtz,Rt) in the Rychleby Mts, eastern Czech Republic, was a localised process initiated by buckling of crustal layers in a thickened orogenic root. Folding and post-buckle flattening was followed by the main stage of exhumation that is characterized by vertical ductile extrusion. This process is documented by structural data, and the vertical ascent of rocks from a depth of c. 70 to c. 35 km is documented by metamorphic petrology. SHRIMP 206Pb/238U and 207Pb/206Pb evaporation zircon ages of 342 ± 5 and 341.4 ± 0.7 Ma date peak metamorphic conditions. The next stage of exhumation was associated with sideways flat thrusting associated with lateral viscous spreading of granulites and surrounding rocks over indenting adjacent continental crust at a depth of c. 35,30 km. This stage was associated with syntectonic intrusion of a granodiorite sill at 345,339 Ma, emplaced at a crustal depth of c. 25 km. The time required for cooling of the sill as well as for heating of the country rocks brackets this event to a maximum of 250 000 years. Therefore, similar ages of crystallization for the granodiorite magma and the peak of eclogite facies metamorphism of the granulite suggest a very short period of exhumation, limited by the analytical errors of the dating methods. Our calculations suggest that the initial exhumation rate during vertical extrusion was 3,15 mm yr,1, followed by an exhumation rate of 24,40 mm yr,1 during further uplift along a magma-lubricated shear zone. The extrusion stage of exhumation was associated with a high cooling rate, which decreased during the stage of lateral spreading. [source] Critical assessment of the applicability of gas chromatography-combustion-isotope ratio mass spectrometry to determine amino sugar dynamics in soilRAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 8 2009Charlotte Decock Amino sugars in soils have been used as markers of microbial necromass and to determine the relative contribution of bacterial and fungal residues to soil organic matter. However, little is known about the dynamics of amino sugars in soil. This is partly because of a lack of adequate techniques to determine ,turnover rates' of amino sugars in soil. We conducted an incubation experiment where 13C-labeled organic substrates of different quality were added to a sandy soil. The objectives were to evaluate the applicability of compound-specific stable isotope analysis via gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS) for the determination of 13C amino sugars and to demonstrate amino sugar dynamics in soil. We found total analytical errors between 0.8 and 2.6, for the ,13C-values of the soil amino sugars as a result of the required ,13C-corrections for isotopic alterations due to derivatization, isotopic fractionation and analytical conditions. Furthermore, the ,13C-values of internal standards in samples determined via GC-C-IRMS deviated considerably from the ,13C-values of the pure compounds determined via elemental analyzer IRMS (with a variation of 9 to 10, between the first and third quartile among all samples). This questions the applicability of GC-C-IRMS for soil amino sugar analysis. Liquid chromatography-combustion-IRMS (LC-C-IRMS) might be a promising alternative since derivatization, one of the main sources of error when using GC-C-IRMS, is eliminated from the procedure. The high 13C-enrichment of the substrate allowed for the detection of very high 13C-labels in soil amino sugars after 1 week of incubation, while no significant differences in amino sugar concentrations over time and across treatments were observed. This suggests steady-state conditions upon substrate addition, i.e. amino sugar formation equalled amino sugar decomposition. Furthermore, higher quality substrates seemed to favor the production of fungal-derived amino sugars. Copyright © 2009 John Wiley & Sons, Ltd. [source] Determination of atrazine, deethylatrazine and simazine in water at parts-per-trillion levels using solid-phase extraction and gas chromatography/ion trap mass spectrometryRAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 24 2003W. T. Ma Methods for trace analysis of atrazine and simazine in water have been developed by using stable-isotope dilution with detection by gas chromatography/mass spectrometry. D5 -Atrazine was used as the internal standard for the determination of atrazine and deethylatrazine, while 13C3 -simazine was used for simazine analysis. Water samples were fortified with known amounts of the internal standards and submitted to solid-phase extraction with a C18 bonded-silica cartridge. A gas chromatograph coupled with an ion-trap mass spectrometer was used to analyze the water sample extracts. Method detection limits were 38 parts-per-trillion (ppt) for atrazine and deethylatrazine and 75 ppt for simazine. The accuracy of the method, represented by relative analytical errors, was less than 15%, and the method precision was less than 5% (relative standard deviation, n,=,9). The method was successfully applied to analyze surface water samples collected from a reservoir and a river at ppt levels. Copyright © 2003 John Wiley & Sons, Ltd. [source] | |||||||||||||