Home About us Contact
|
Home About us Contact | ||
|
|
||
Ionic Liquid Electrolyte (ionic + liquid_electrolyte)
Selected AbstractsNew Type High Efficient Quasi-Solid-State Ionic Liquid Electrolyte for Dye-Sensitized Solar CellsCHINESE JOURNAL OF CHEMISTRY, Issue 11 2007Xu PAN Abstract For the fist time the preparation of a mostly solid-state high efficient electro-conductive material comprising 1-methyl-3-propylimidazolium iodide (MPII), benzimidazole (BI), iodine and lithium iodide was reported. In this electrolyte, BI acts as not only additives but also gelators. With its significant electrochemical properties, an overall efficiency of 3.07% was achieved under AM 1.5 (100 mW/cm2). [source] Effects of TiO2 Film on the Performance of Dye-sensitized Solar Cells Based on Ionic Liquid ElectrolyteCHINESE JOURNAL OF CHEMISTRY, Issue 12 2005Xu Pan Abstract Photo correlation spectroscopy was used to measure the particle size distribution of TiO2 films. Other parameters, such as porosity, BET surface area, average pore size, crystallite size D101, distribution of pore size etc. were also measured. The effects of these parameters on the ionic liquid based dye-sensitized solar cells (DSC) were studied. It was concluded that the particle size distribution of nanocrystalline TiO2 played an important role on the performance of DSC. The narrow particle size distribution of nanocrystalline TiO2 increased the efficiency of DSC, while the wide distribution decreased the efficiency of DSC. From the result above, it was also concluded that the photo correlation spectroscopy was a good method to identify the performance of TiO2 films. Based on electrochemical impedance spectroscopy, we found that the particle size distribution could affect the electronic contact between the TiO2 layers as well. The narrow particle size distribution made the electronic contact between TiO2 layers better than the wide particle size distribution of the TiO2 films, and then better the electronic contact, higher the efficiency of the DSC. [source] Solvent-Free Ionic Liquid Electrolytes for Mesoscopic Dye-Sensitized Solar CellsADVANCED FUNCTIONAL MATERIALS, Issue 14 2009Shaik M. Zakeeruddin Abstract Ionic liquids have been identified as a new class of solvent that offers opportunities to move away from the traditional solvents. The physical-chemical properties of ionic liquids can be tuned and controlled by tailoring their structures. The typical properties of ionic liquids, such as non-volatility, electrochemical stability and high conductivity, render them attractive as electrolytes for dye-sensitized solar cells. However, the high viscosity of ionic liquids leads to mass transport limitations on the photocurrents in the solar cells at full sunlight intensity, but the contribution of a Grotthous-type exchange mechanism in these viscous electrolytes helps to alleviate these diffusion problems. This article discusses recent developments in the field of high-performance dye-sensitized solar cells with ionic liquid-based electrolytes and their characterization by electrochemical impedance analysis. [source] The Zwitterion Effect in Ionic Liquids: Towards Practical Rechargeable Lithium-Metal Batteries,ADVANCED MATERIALS, Issue 20 2005N. Byrne Practical lithium-metal batteries are the ultimate goal of battery researchers. The addition of a zwitterionic compound (see Figure) to an ionic liquid electrolyte doped with a lithium salt results in a 100% enhancement of the current densities achieved in the cycling of a lithium-metal cell. This phenomenon arises due to increased lithium-ion mobility or a reduced solid electrolyte interphase layer resistance. [source] | ||||||||||