Hydrogen Flow (hydrogen + flow)

Distribution by Scientific Domains


Selected Abstracts


Turbulent Dynamics of Beryllium Seeded Plasmas at the Edge of Tokamaks

CONTRIBUTIONS TO PLASMA PHYSICS, Issue 3-5 2010
R.V. Shurygin
Abstract Numerical simulation of turbulent MHD dynamics of beryllium seeded plasmas at the edge of tokamaks is performed. The model is based on the 4-fluid {,, n, pe, pi } reduced nonlinear Braginsky's MHD equations. Neutral hydrogen flow from the wall is described with a diffusion model. Beryllium line radiation is taken into consideration. The Be ion distribution over ionization states is calculated using the reduced model. Electron impact ionization, three body, photo- and dielectronic recombination and charge-exchange with neutral hydrogen are taken into account. Coronal equilibrium is not supposed. Simulations are performed for T-10 parameters. Radial distributions of averaged temperatures and their fluctuation levels, species flows, impurity radiation power, and impurity ions concentrations are obtained as functions of the Be concentration at the wall. The impurity radiation is shown to act on the turbulent oscillation level significantly if the total Be concentration at the wall exceeds 3 · 1011cm,3. The impurity turbulent transversal flow is directed inward and exceeds neoclassical flow significantly. The parallel conductivity and, as a consequence, turbulent transport are increased significantly by impurity radiation. The radiation loss dependence on the neutral Hydrogen concentration at the wall is also examined. The hydrogen concentration increasing the plasma density also rises. The relative beryllium concentration decreases. In total, these two effects are compensated, and the level of radiation losses is changed insignificantly (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Hydrogen Production via Autothermal Reforming of Diesel Fuel

FUEL CELLS, Issue 3 2004
J. Pasel
Abstract Hydrogen, for the operation of a polymer electrolyte fuel cell, can be produced by means of autothermal reforming of liquid hydrocarbons. Experiments, especially with ATR 4, which produces a molar hydrogen stream equivalent to an electrical power in the fuel cell of 3,kW, showed that the process should be preferably run in the temperature range between 700,° and 850,°. This ensures complete hydrocarbon conversion and avoids the formation of considerable amounts of methane and organic compounds in the product water. Experiments with commercial diesel showed promising results but insufficient long-term stability. Experiments concerning the ignition of the catalytic reaction inside the reformer proved that within 60,s after the addition of water and hydrocarbons the reformer reached 95% of its maximum molar hydrogen flow. Measurements, with respect to reformer start-up, showed that it takes approximately 7,min. to heat up the monolith to a temperature of 340,° using an external heating device. Modelling is performed, aimed at the modification of the mixing chamber of ATR Type 5, which will help to amend the homogeneous blending of diesel fuel with air and water in the mixing chamber. [source]


Post-annealing effect upon phosphorus-doped ZnTe homoepitaxial layers grown by MOVPE

PHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 5 2007
Katsuhiko Saito
Abstract The effect of post-annealing treatment upon the photoluminescence (PL) spectra of phosphorus-doped ZnTe homoepitaxial layers grown by metalorganic vapour phase epitaxy using tris-dimethylaminophosphorus (TDMAP) has been investigated. PL properties at 4 K of the layers are dramatically improved by the post-annealing in nitrogen flow, i.e. donor,acceptor pair emission vanishes and instead free-to-bound transition emission (FB) and broadened acceptor-related excitonic emission (Ia) appear. PL intensity at room temperature is enhanced remarkably by the treatment. While the post-annealing treatment in hydrogen flow also gives an increase in PL intensity at room temperature of the layer, PL spectrum at 4 K is almost unchanged. The intensity ratio of FB to broadened Ia for the layer after post-annealing treatment in nitrogen flow increases and the broadened Ia shifts towards longer wavelength side with increasing TDMAP transport rate. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Dynamic simulation of kinetics, heat and mass transfer during hydrogen sorption by LaNi5

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2010
Dr Tarek Moustafa
Abstract A two-dimensional transient heat and mass transfer models have been developed to investigate the dynamic phenomena of hydrogen absorption and desorption in metal hydride bed. LaNi5 has been chosen as the alloy used for hydrogen storage. The numerical simulation has been conducted to simulate the time,space evolution of temperature, fractional conversion, hydrogen pressure and velocity, in addition to metal density. A correlation for the volumetric reaction rate has been deduced. Also, comparisons have been done between various bed geometries and their influence on the average hydrogen desorbed mass. The simulation results showed that heat transfer controls the overall rate of absorption and desorption processes, and because the driving force for the hydrogen flow is the axial pressure difference; the challenge to get optimum bed geometry is in compromising between heat transfer and pressure drop limitations. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source]