Home About us Contact
|
Home About us Contact | ||
|
|
||
Hybrid Coatings (hybrid + coating)
Selected AbstractsStructure and Mechanical Properties of Polyurethane/Silica Hybrid CoatingsMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10 2005Yongchun Chen Abstract Summary: Polyurethane/silica hybrid coatings were prepared via in situ (IS) or blending (BL) method using different acidic silica sols. The effects of preparation methods, silica types, and content on the structure and mechanical properties of the hybrid coatings were investigated. It was found that there existed two types of silica phases in the hybrid coatings: silica-rich agglomerate and primary silica-rich phase, whose size and compactness depended upon the silica types and the preparation methods. Introducing silica could result in obvious changes in surface free energy, atomic composition, and mechanical properties of the hybrid coatings. Typical SEM image of the fractured surface of hybrids obtained by the in situ method. [source] Green Nanocomposites from Renewable Resources: Biodegradable Plant Oil-Silica Hybrid CoatingsMACROMOLECULAR RAPID COMMUNICATIONS, Issue 12 2003Takashi Tsujimoto Abstract Green nanocomposite coatings based on renewable plant oils have been developed. An acid-catalyzed curing of epoxidized plant oils with 3-glycidoxypropyltrimethoxysilane produced transparent nanocomposites. The hardness and mechanical strength improved by incorporating the silica network into the organic polymer matrix, and good flexibility was observed in the nanocomposite. The nanocomposites showed high biodegradability. [source] Infrared stealth and anticorrosion performances of organically modified silicate-NiZn ferrite/polyaniline hybrid coatingsJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 3 2008K. H. Wu Abstract Hybrid coatings based on organically modified silicate-Ni0.5Zn0.5Fe2O4/polyaniline were synthesized through a sol,gel technique with different NiZn ferrite/polyaniline weight ratio (1/1, 1/2, 1/5). These hybrid films were deposited via spin coating onto an aluminum alloy to improve the corrosion protection and to act as infrared stealth coatings. The effects induced by the NiZn ferrite/polyaniline hybrids on the chain dynamic, ferromagnetic behavior, infrared stealth, and anticorrosion performances of the coated samples were investigated. The rotating-frame spin-lattice relaxation times and scale of the spin-diffusion path length indicated that the configuration of the hybrid films was highly cross-linked and dense. The thermal extinction of the hybrid coatings increased with the increase in the polyaniline content. Potentio-dynamic and salt-spray analysis revealed that the hybrid films provided an exceptional barrier and corrosion protection in comparison with untreated aluminum alloy substrates. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 926,935, 2008 [source] Synthesis and characterization of novel polyimide/SiO2 nanocomposite materials containing phenylphosphine oxide via sol-gel techniqueJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Canan Kizilkaya Abstract In this article, a series of novel polyimide/silica (PI/SiO2) nanocomposite coating materials were prepared from tetraethoxysilane (TEOS), ,-glycidyloxypropyltrimethoxysilane (GOTMS), and polyamic acid (PAA) via sol-gel technique. PAA was prepared by the reaction of 3,3,,4,4,-benzophenone tetracarboxylic dianhydride (BTDA) and bis (3-aminophenyl) phenyphosphine oxide (BAPPO) in N -methyl-2- pyrrolidone (NMP). BAPPO was synthesized hydrogenation of bis (3-nitrophenyl) phenyphosphine oxide (BNPPO) in the presence of Pd/C. The silica content in the hybrid coating materials was varied from 0 to 20 wt %. The molecular structures of the composite materials were analyzed by means of FT-IR and 29Si-NMR spectroscopy techniques. The physical and mechanical properties of the nanocomposites were evaluated by various techniques such as, hardness, contact angle, and optical transmission and tensile tests. These measurements revealed that all the properties of the nanocomposite coatings were improved noticeable, by the addition of sol-gel precursor into the coating formulation. Thermogravimetric analysis showed that the incorporation of sol-gel precursor into the polyimide matrix leads to an enhancement in the thermal stability and also flame resistance properties of the coating material. The surface morphology of the hybrid coating was characterized by scanning electron microscopy (SEM). SEM studies indicated that nanometer-scaled inorganic particles were homogenously dispersed throughout the polyimide matrix © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Stable Inverted Polymer/Fullerene Solar Cells Using a Cationic Polythiophene Modified PEDOT:PSS Cathodic InterfaceADVANCED FUNCTIONAL MATERIALS, Issue 15 2010David A. Rider Abstract A cationic and water-soluble polythiophene [poly[3-(6-pyridiniumylhexyl)thiophene bromide] (P3PHT+Br,)] is synthesized and used in combination with anionic poly(3,4-ethylenedioxythiophene):poly(p -styrenesulfonate) (PEDOT:PSS), to produce hybrid coatings on indium tin oxide (ITO). Two coating strategies are established: i) electrostatic layer-by-layer assembly with colloidal suspensions of (PEDOT:PSS),, and ii) modification of an electrochemically prepared (PEDOT:PSS), film on ITO. The coatings are found to modify the work function of ITO such that it could act as a cathode in inverted 2,5-diyl-poly(3-hexylthiophene) (P3HT)/[6,6]-phenyl-C61 -butyric acid methyl ester (PCBM) polymer photovoltaic cells. The interfacial modifier created from the layer-by-layer assembly route is used to produce efficient inverted organic photovoltaic devices (power conversion efficiency ,2%) with significant long-term stability in excess of 500,h. [source] Epoxy,siloxane hybrid coatings by a dual-curing processADVANCES IN POLYMER TECHNOLOGY, Issue 2 2009Giulio Malucelli Abstract Coatings based on a hybrid organic,inorganic epoxy system were prepared by a dual-curing mechanism, via cationic photopolymerization in the first step at room temperature and a subsequent hydrolysis/condensation reaction of a trialkoxy-silane compound (sol,gel process) at high temperature. To this end, a high Tg epoxy resin (3,4-epoxycyclohexylmethyl-3,-cyclohexenyl-methyl adipate, UVR 6128) was added in increasing amounts to a precursor for the inorganic-like phase (3,4-epoxycyclohexylethyltrimethoxysilane, EETMOS). The mixture contained triphenylsulfoniumhexafluoroantimonate as a cationic photoinitiator. By this method, the strongly acid environment generated by the photolysis of the triarylsolfunium salt in the first step induces the hydrolysis of EETMOS alkoxy-silane groups. The films produced in the first step of the process were thermal treated to promote the condensation reactions of the siloxane moieties. The kinetics of the reactions of photopolymerization and condensation was investigated. It was found that the presence of EETMOS increases both the polymerization rate and the final consumption of epoxy groups. Thermogravimetric analyses performed in air have revealed an increased stability of the hybrid coatings with respect to the films produced from formulations without EETMOS. A significant increase in surface hardness was also observed for the hybrid coatings. The thermo-mechanical properties were found to be strongly affected by the temperature used in the thermally induced reactions in the second step. The hybrid coatings on a low-density polyethylene substrate were found to decrease the diffusivity of oxygen and to increase the oxygen solubility within the coating. © 2009 Wiley Periodicals, Inc. Adv Polym Techn 28:77,85, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20149 [source] Infrared stealth and anticorrosion performances of organically modified silicate-NiZn ferrite/polyaniline hybrid coatingsJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 3 2008K. H. Wu Abstract Hybrid coatings based on organically modified silicate-Ni0.5Zn0.5Fe2O4/polyaniline were synthesized through a sol,gel technique with different NiZn ferrite/polyaniline weight ratio (1/1, 1/2, 1/5). These hybrid films were deposited via spin coating onto an aluminum alloy to improve the corrosion protection and to act as infrared stealth coatings. The effects induced by the NiZn ferrite/polyaniline hybrids on the chain dynamic, ferromagnetic behavior, infrared stealth, and anticorrosion performances of the coated samples were investigated. The rotating-frame spin-lattice relaxation times and scale of the spin-diffusion path length indicated that the configuration of the hybrid films was highly cross-linked and dense. The thermal extinction of the hybrid coatings increased with the increase in the polyaniline content. Potentio-dynamic and salt-spray analysis revealed that the hybrid films provided an exceptional barrier and corrosion protection in comparison with untreated aluminum alloy substrates. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 926,935, 2008 [source] Sol,gel microextraction phases for sample preconcentration in chromatographic analysisJOURNAL OF SEPARATION SCIENCE, JSS, Issue 19 2010Scott S. Segro Abstract Sol,gel technology provides a simple and reliable method for solid-phase microextraction (SPME) fiber preparation through in situ creation of surface-bonded organic,inorganic hybrid coatings characterized by enhanced thermal stability and solvent-resistance properties that are important for the coupling of SPME with GC and HPLC, respectively. The sol,gel coating technology has led to the development of an extensive array of sol,gel sorbent coatings for SPME. In this article, sol,gel microextraction coatings are reviewed, with particular attention on their synthesis, characterization, and applications in conjunction with GC and HPLC analyses. In addition, the development of sol,gel-coated stir bars, their inherent advantages, and applications are discussed. Next, the development and applications of sol,gel capillary microextraction (CME) in hyphenation with GC and HPLC is extensively reviewed. The newly emerging germania- and titania-based sol,gel microextraction phases look promising, especially in terms of pH and hot solvent stability. Finally, sol,gel monolithic beds for CME are reviewed. Such monolithic beds are in a position to greatly improve the extracting capabilities and enhanced sensitivity in CME. [source] Synthesis of Polar and Non-Polar Nano-Corundum and Uses for Aluminium Carboxylate Hybrid Nanocomposites with Enhanced Surface Mechanical and Viscoelastic PropertiesMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10-11 2007Hans-Jürgen Gläsel Abstract Amorphous aluminium carboxylate nanoparticles were checked for their potential as precursors for nano-corundum powders prepared by a high-temperature conversion process. Exemplifying x-ray photoelectron spectroscopy studies of the aluminium carboxylate nanoparticles with polar and non-polar ligands showed that, during the course of the high-temperature treatment, specific features of the ultrafine organo-aluminium powders such as polarity/non-polarity and concomitant hydrophilic/hydrophobic properties were preserved. The resulting nano-corundum powders were in turn identified as positive synergists for the enforcement of radiation-cured aluminium carboxylate/acrylate coatings. The simultaneous (optional) use of micro-corundum particles yielded polymer hybrid coatings. In comparison to acrylate-based organo-aluminium nanocomposites, polymeric hybrid coatings revealed significantly improved surface mechanical and viscoelastic properties. In addition to acrylate coatings, other polar and even non-polar bulk polymers were subject to nano/micro modification using polar and non-polar nano-corundum powders, respectively. [source] Preparation and Characterization of Hyperbranched Polymer/Silica Hybrid Nanocoatings by Dual-Curing ProcessMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10 2006Ezio Amerio Abstract Summary: Organic-inorganic nanocomposite hybrid coatings were prepared through a dual-cure process involving cationic photopolymerization of a hyperbranched epoxy functionalized resin and subsequent condensation of an alkoxysilane inorganic precursor. All the formulations investigated gave rise to photocured films characterized by high gel content values. An increase in glass transition temperature and an increase in storage modulus above Tg in the rubbery plateau is observed with increasing TEOS content in the photocurable formulation. The important role of GPTS on reducing the inorganic domain size and avoiding macroscopic phase separation was demonstrated by TEM analyses. TEM obtained for one of the cured films in the presence of GPTS. [source] Structure and Mechanical Properties of Polyurethane/Silica Hybrid CoatingsMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10 2005Yongchun Chen Abstract Summary: Polyurethane/silica hybrid coatings were prepared via in situ (IS) or blending (BL) method using different acidic silica sols. The effects of preparation methods, silica types, and content on the structure and mechanical properties of the hybrid coatings were investigated. It was found that there existed two types of silica phases in the hybrid coatings: silica-rich agglomerate and primary silica-rich phase, whose size and compactness depended upon the silica types and the preparation methods. Introducing silica could result in obvious changes in surface free energy, atomic composition, and mechanical properties of the hybrid coatings. Typical SEM image of the fractured surface of hybrids obtained by the in situ method. [source] Protective organic-inorganic hybrid coatings on mild steel derived from Ti(OC4H9)4 -modified precursorsMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 9 2004V. Nguyen Abstract Titania-poly(methyl methacrylate-co-butyl methacrylate-co-methacrylic acid) hybrids prepared by a sol-gel method were deposited by dip coating on mild steel. Transparent and defect free coatings with titania content ranging between 0 and 12.7 wt.% have been prepared. Barrier properties and dry adherence have been tested by electrochemical impedance spectroscopy (EIS) and the vertical pull-off test, respectively. The pull-off test results suggest that the titanium alkoxide precursor must intercede on the substrate/coating interphase during film formation to create specific adhesive bondings with the substrate. In this paper, two capacitance models are used to estimate the water uptake, one based on a uniform and one on a heterogeneous distribution of sorbed water. Water uptake determined from these two models is compared to the gravimetry results. It is suggested that a reliable determination of the actual water uptake in coatings from capacitance measurements require an extensive experimental work. The variations in the state of sorbed water with the specimen type or immersion time, the leaching of organics during immersion or the slow diffusion of ions are fundamental factors that must be considered when comparing the water uptake determined from gravimetry and capacitance models. [source] | |||||||||||||