Home About us Contact
|
Home About us Contact | ||
|
|
||
Huggins Constant (Huggin + constant)
Selected AbstractsSemiempirical equations for the viscosity of amphiphilic polymer solutions: A critical examinationPOLYMER ENGINEERING & SCIENCE, Issue 4 2007A. Durand The associative behavior of amphiphilic polysaccharides derived from dextran, a neutral bacterial polysaccharide, is studied in dilute and moderately concentrated aqueous solutions using viscosity measurements. It is shown that the viscosity of the aqueous solutions can be conveniently depicted over a wide concentration range by several semiempirical equations. The Martin equation as well as the Matsuoka-Cowman equation is shown to depict conveniently the experimental results. These two equations involve only viscometric parameters determined in the dilute range (intrinsic viscosity and Huggins constant). The modification of Lyons and Tobolsky is discussed. The Fedors equation is shown to be similar to the Heller equation over a large concentration domain. Their respective empirical parameters are correlated and can be calculated from the Huggins coefficient. POLYM. ENG. SCI., 47:481,488, 2007. © 2007 Society of Plastics Engineers. [source] Rheological characterization of schizophyllan aqueous solutions after denaturation,renaturation treatmentBIOPOLYMERS, Issue 4 2004Yapeng Fang Abstract Schizophyllan (SPG) with a molecular weight of 2.6×106, designated SPG-1, is denatured and then renatured at a concentration of 1.8 wt % by alkalization,neutralization. The prepared denatured,renatured samples (DRSPG-1) are diluted to various concentrations and equilibrated for 10 days before rheological and intrinsic viscosity measurements. When concentration (Cp) is above 0.75 wt %, DRSPG-1 aqueous systems have weak gel-type rheological properties. However, for 0.28 wt % , Cp , 0.65 wt % and Cp , 0.19 wt %, DRSPG-1 aqueous systems behave as power law fluids and Newtonian fluids, respectively, which are attributed to the moderate isotropy degree of DRSPG-1 chains. Furthermore, a critical overlap parameter of c*[,] = 1.2 is determined for DRSPG-1 in aqueous solutions, which is close to that of 1 for intact SPG in water while far smaller than that of 4.3 for SPG in DMSO. This is considered to be due to the strong interactions of DRSPG-1 chains in water, further confirmed by the intrinsic viscosity measurements in which the DRSPG-1 aqueous solution shows an abnormally large value of Huggins constant. Regarding the structure of DRSPG-1 weak gels, multiruns of dynamic strain sweep measurements suggest that the dominant structures are aggregates formed by hydrogen-bonding associations of DRSPG-1 chains rather than the permanent three-dimensional network. In addition, the step-shear rate tests are performed to study the thixotropic properties of DRSPG-1 aqueous systems. © 2004 Wiley Periodicals, Inc. Biopolymers, 2004 [source] Viscometric properties of viscosity index improvers in lubricant base oil over a wide temperature range.LUBRICATION SCIENCE, Issue 2 2000Part I: Group II base oil Capillary viscometry has been employed to measure the viscosities of dilute polymer solutions over the temperature range -10 to 150 °C. A Group II base oil containing 95% saturates was used as solvent for an olefin copolymer (OCP), a hydrogenated diene copolymer (HDP), and a polymethacrylate (PMA). These three polymers represent the three major families of viscosity index (VI) improvers used nowadays in lubricant formulations. Intrinsic viscosities and Huggins' constants were also determined. The thickening effects of the olefin copolymer and the hydrogenated diene copolymer were found to be higher at low temperatures (e.g., 40 °C) than at higher ones (e.g., 100 °C), which phenomenon was attributed to stronger intermolecular hydrodynamic interactions at low temperatures, as indicated by the Huggins constants. For the hydrogenated diene copolymer and the polymethacrylate polymer, the viscosity increased abruptly when the temperature went below 10 °C. This unusual observation was attributed to the crystallisation of a small fraction of the base oil. Based on the intrinsic viscosity data, it was concluded that at temperatures between 10 and 150 °C, the polymer coil dimension remains a constant for the olefin copolymer and the hydrogenated diene copolymer VI improvers, but increases with increasing temperature for the polymethacrylate VI improver. [source] Character of long-chain branching in highly purified natural rubberJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Sureerut Amnuaypornsri Abstract The nature of long-chain branching in natural rubber (NR) from Hevea brasiliensis was analyzed for NR purified by enzymatic deproteinization in the latex state followed by acetone extraction in the solid state to remove the proteins and neutral lipids, respectively. The treatment of purified NR in a toluene solution with a polar solvent, such as methanol or acetic acid, resulted in a clear decrease in the molecular weight, gel content, and Huggins' constant; this was caused by the decomposition of branch points in the purified rubber. This finding clearly showed that long-chain branching in the purified NR was mainly derived from the association of phospholipids linked with both terminal groups in the rubber chain via hydrogen bonds. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Viscometric properties of viscosity index improvers in lubricant base oil over a wide temperature range.LUBRICATION SCIENCE, Issue 2 2000Part I: Group II base oil Capillary viscometry has been employed to measure the viscosities of dilute polymer solutions over the temperature range -10 to 150 °C. A Group II base oil containing 95% saturates was used as solvent for an olefin copolymer (OCP), a hydrogenated diene copolymer (HDP), and a polymethacrylate (PMA). These three polymers represent the three major families of viscosity index (VI) improvers used nowadays in lubricant formulations. Intrinsic viscosities and Huggins' constants were also determined. The thickening effects of the olefin copolymer and the hydrogenated diene copolymer were found to be higher at low temperatures (e.g., 40 °C) than at higher ones (e.g., 100 °C), which phenomenon was attributed to stronger intermolecular hydrodynamic interactions at low temperatures, as indicated by the Huggins constants. For the hydrogenated diene copolymer and the polymethacrylate polymer, the viscosity increased abruptly when the temperature went below 10 °C. This unusual observation was attributed to the crystallisation of a small fraction of the base oil. Based on the intrinsic viscosity data, it was concluded that at temperatures between 10 and 150 °C, the polymer coil dimension remains a constant for the olefin copolymer and the hydrogenated diene copolymer VI improvers, but increases with increasing temperature for the polymethacrylate VI improver. [source] | ||||||||||