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Homogeneous Material (homogeneous + material)
Selected AbstractsNano-Scale Design of TiAl Alloys Based on ,-Phase Decomposition,ADVANCED ENGINEERING MATERIALS, Issue 5 2006F. Appel Abstract Phase decomposition and ordering reactions in ,/B2-phase containing TiAl alloys were utilized to establish a novel, previously unreported, type of laminate microstructure. The characteristic constituent of this microstructure are laths with a nanometer-scale substructure that are comprised of several stable and metastable phases. Microstructural control can be achieved by conventional thermomechanical processing and leads to a structurally and chemically very homogeneous material with excellent mechanical properties. The physical metallurgy of this novel type of alloy has been assessed by transmission electron microscope investigations and mechanical testing. [source] Studies on glass transition temperature of mono and bilayer protein films plasticized by glycerol and olive oilJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2008Babak Ghanbarzadeh Abstract Thermomechanical and thermal properties of whey protein, maize prolamin protein (zein), and the laminated whey protein,zein films were studied. The dynamic mechanical (thermal) analysis (DMTA) results showed that the single zein film had higher Tg than single whey protein and zein,whey laminated films. The shift in the Tg values of films from 31.2°C in whey protein film and 88.5°C in the zein film to 82.8°C in the laminated whey protein,zein films may be implied some interaction formation between the two polymers. The small tan , peaks were observed at ,50°C in zein,glycerol films and at ,22.37°C in the whey protein films and can be related to ,-relaxation phenomena or presence of glycerol rich region in polymer matrix. Zein-olive oil and zein,whey protein,olive oil films showed tan , peaks corresponded the Tg values at 113.8, and 92.4°C, respectively. Thus, replacing of glycerol with olive oil in film composition increased Tg. A good correspondence was obtained when DSC results were compared with the tan , peaks in DMTA measurements. DSC thermograms suggested that plasticizers and biopolymers remained a homogeneous material throughout the cooling and heating cycle. The results showed that Tg of zein,glycerol films predicted by Couchman and Karasz equation is very close to value obtained by DSC experiments. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Vaccine-associated granulomatous inflammation and melanin accumulation in Atlantic salmon, Salmo salar L., white muscleJOURNAL OF FISH DISEASES, Issue 1 2005E O Koppang Abstract The purpose of this study was to investigate the nature of variably sized pigmented foci encountered in fillets of farmed Atlantic salmon, Salmo salar L. The material was sampled on the fillet production line and on salmon farms from fish with an average size of 3 kg from various producers. The fish had been routinely vaccinated by injection. Gross pathology, histology, immunohistochemistry using antisera against major histocompatibility complex (MHC) class II , chain and transmission electron microscopy (TEM) were used to characterize the changes. Macroscopically, melanized foci were seen penetrating from the peritoneum deep into the abdominal wall, sometimes right through to the skin, and also embedded in the caudal musculature. Histological investigation revealed muscle degeneration and necrosis, fibrosis and granulomatous inflammation containing varying numbers of melano-macrophages. Vacuoles, either empty or containing heterogeneous material, were frequently seen. The presence of abundant MHC class II+ cells indicated an active inflammatory condition. TEM showed large extracellular vacuoles and leucocytes containing homogeneous material of lipid-like appearance. The results showed that the melanized foci in Atlantic salmon fillet resulted from an inflammatory condition probably induced by vaccination. The described condition is not known in wild salmon and in farmed salmon where injection vaccination is not applied. [source] Non-Hodgkin's lymphoma and auricular hypoplasia: associated with juvenile colloid milium or ligneous conjunctivitis?JOURNAL OF THE EUROPEAN ACADEMY OF DERMATOLOGY & VENEREOLOGY, Issue 3 2005A Kavak ABSTRACT The exact nature of amyloid-like hyaline material deposits in the skin is not well understood in some disorders. Three of those , ligneous conjunctivitis, ligneous periodontitis and colloid milium , have been rarely reported in a same patient. We report a case of mucosal and skin deposits of an amyloid-like homogeneous material associated with non-Hodgkin's lymphoma and congenital auricular hypoplasia. We discussed and reviewed the literature on these unique associations to determine whether these are the same pathological process. We also noted whether this case represents a new syndrome or a coincidental association. [source] Bite forces, canine strength and skull allometry in carnivores (Mammalia, Carnivora)JOURNAL OF ZOOLOGY, Issue 2 2005Per Christiansen Abstract Skull variables were analysed for allometry patterns in 56 species of extant carnivores. As previously reported, many skull variables scale near isometrically with either skull length or lower jaw length. The maximal gape angle scales insignificantly (P<0.05) with skull size, but the clearance between the canines shows a significant relationship with skull size and scales near isometrically. Maximal bite forces were estimated from geometrical cross-sectional areas of dried skulls, and the bending strength of the canines was computed by modelling the canines as a cantilevered beam of solid, homogeneous material with an elliptical cross section. Previous hypotheses of large taxon differences in canine bending strengths, so that felids have stronger canines than canids, are corroborated when actual bite forces at the upper canine are ignored. Incorporation of bite force values, however, nullifies the differences in canine bending strength among felids and canids, and ursids seem to have stronger canines than felids. This is probably because of the significantly longer canines of felids compared to canids and ursids, and the generally high bite forces of felids. [source] Processing of ultra-high molecular weight polyethylene by hot isostatic pressing, and the effect of processing parameters on its microstructurePOLYMER ENGINEERING & SCIENCE, Issue 10 2004Rizwan M. Gul The processing techniques available for ultra-high molecular weight polyethylene (UHMWPE) do not lead to a homogeneous material. The processed material exhibits particle boundaries (fusion defects) reflecting the powder flakes of the virgin resin. Hot isostatic pressing has been used in this study as a possible technique to produce a homogeneous, defect-free material, and to study the effect of processing parameters on consolidation and other properties. The extent of consolidation was determined by optical microscopy using thin sections, and by scanning electron microscopy using cryofractured and solvent-etched specimens. Processing temperature is the most important variable affecting consolidation; fusion defects can be eliminated by increasing the processing temperature. This is sometimes accompanied by the appearance of spherulties; however, the degree of crystallinity, melting point, and density remain constant. DMA results show that the molecular weight between entanglements increases and the entanglement structure changes with an increase in processing temperature. Polym. Eng. Sci. 44:1848,1857, 2004. © 2004 Society of Plastics Engineers. [source] Dynamic stability of a porous rectangular platePROCEEDINGS IN APPLIED MATHEMATICS & MECHANICS, Issue 1 2006Daniel Debowski The study is devoted to a axial compressed porous-cellular rectangular plate. Mechanical properties of the plate vary across is its thickness which is defined by the non-linear function with dimensionless variable and coefficient of porosity. The material model used in the current paper is as described by Magnucki, Stasiewicz papers. The middle plane of the plate is the symmetry plane. First of all, a displacement field of any cross section of the plane was defined. The geometric and physical (according to Hook's law) relationships are linear. Afterwards, the components of strain and stress states in the plate were found. The Hamilton's principle to the problem of dynamic stability is used. This principle was allowed to formulate a system of five differential equations of dynamic stability of the plate satisfying boundary conditions. This basic system of differential equations was approximately solved with the use of Galerkin's method. The forms of unknown functions were assumed and the system of equations was reduced to a single ordinary differential equation of motion. The critical load determined used numerically processed was solved. Results of solution shown in the Figures for a family of isotropic porous-cellular plates. The effect of porosity on the critical loads is presented. In the particular case of a rectangular plate made of an isotropic homogeneous material, the elasticity coefficients do not depend on the coordinate (thickness direction), giving a classical plate. The results obtained for porous plates are compared to a homogeneous isotropic rectangular plate. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Finite cover method for linear and non-linear analyses of heterogeneous solidsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 9 2003Kenjiro Terada Abstract We introduce the finite cover method (FCM) as a generalization of the finite element method (FEM) and extend it to analyse the linear and non-linear mechanical behaviour of heterogeneous solids and structures. The name ,FCM' is actually an alias for the manifold method (MM) and the basic idea of the method has already been established for linear analyses of structures with homogeneous materials. After reviewing the concept of physical and mathematical covers for approximating functions in the FCM, we present the formulation for the static equilibrium state of a structure with arbitrary physical boundaries including material interfaces. The problem essentially involves the discontinuities in strains, and possibly has the discontinuities in displacement caused by interfacial debonding or rupture of material interfaces. We simulate such non-linear mechanical behaviour after presenting simple numerical examples that demonstrate the equivalence between the approximation capabilities of the FCM and those of the FEM. Copyright © 2003 John Wiley & Sons, Ltd. [source] A new variable-order singular boundary element for two-dimensional stress analysisINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 3 2002K. M. Lim Abstract A new variable-order singular boundary element for two-dimensional stress analysis is developed. This element is an extension of the basic three-node quadratic boundary element with the shape functions enriched with variable-order singular displacement and traction fields which are obtained from an asymptotic singularity analysis. Both the variable order of the singularity and the polar profile of the singular fields are incorporated into the singular element to enhance its accuracy. The enriched shape functions are also formulated such that the stress intensity factors appear as nodal unknowns at the singular node thereby enabling direct calculation instead of through indirect extrapolation or contour-integral methods. Numerical examples involving crack, notch and corner problems in homogeneous materials and bimaterial systems show the singular element's great versatility and accuracy in solving a wide range of problems with various orders of singularities. The stress intensity factors which are obtained agree very well with those reported in the literature. Copyright © 2002 John Wiley & Sons, Ltd. [source] Crystal structures and phonon modes of Ba(Ca1/2W1/2)O3, Ba(Ca1/2Mo1/2)O3 and Ba(Sr1/2W1/2)O3 complex perovskites investigated by Raman scatteringJOURNAL OF RAMAN SPECTROSCOPY, Issue 1 2010Anderson Dias Abstract This work investigates the crystal structures and phonon modes of Ba(Ca1/2W1/2)O3, Ba(Ca1/2Mo1/2)O3 and Ba(Sr1/2W1/2)O3 perovskites by Raman spectroscopy. The samples were produced by conventional solid-state processing at 1200 °C. X-ray diffraction showed that single-phase homogeneous materials were produced, which are cubic or pseudo-cubic in symmetry. The existing controversies in the literature for these complex perovskites were investigated by comparing experimental Raman data with group-theory analysis. Ceramics with Ca and W or Mo were found to be cubic, space group Fm3m. For these materials, four Raman-active bands were observed and the fitting parameters showed that the Ba(Ca1/2Mo1/2)O3 ceramic presents bands at lower wavenumbers if compared with the Ba(Ca1/2W1/2)O3 sample. For the Ba(Sr1/2W1/2)O3 material, two hypotheses were investigated for monoclinic or triclinic structures. The experimental results showed 12 Raman-active modes for this ceramic, which is in perfect agreement with the theoretical predictions for a monoclinic (I2/m) structure. Copyright © 2009 John Wiley & Sons, Ltd. [source] Preparation and properties of thermoplastic pea starch using N,N -bis(2-hydroxyethyl)formamide as the plasticizerPOLYMER ENGINEERING & SCIENCE, Issue 5 2010Hongguang Dai N,N -bis(2-hydroxyethyl)formamide (BHF) was synthesized efficiently and used as a new plasticizer for pea starch to prepare thermoplastic starch (TPS). The hydrogen bond interaction between BHF and pea starch was proven by Fourier-transform infrared (FT-IR) spectroscopy. As detected by scanning electron microscope (SEM), pea starch granules were completely disrupted, and the homogeneous materials were obtained. The crystallinity of pea starch and BHF-plasticized thermoplastic pea starch (BTPS) was characterized by X-ray diffraction (XRD). Rheological properties of TPS were analyzed. The water resistance of BTPS was better than that of glycerol-plasticized thermoplastic pea starch (GTPS). At RH 33%, the tensile strength of BTPS was higher than that of GTPS for TPS containing 30% plasticizer. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers [source] Acid-Base Interactions in Energetic Materials: I. The Hard and Soft Acids and Bases (HSAB) Principle,Insights to Reactivity and Sensitivity of Energetic MaterialsPROPELLANTS, EXPLOSIVES, PYROTECHNICS, Issue 1 2005Ernst-Christian Koch Abstract The chemistry of energetic materials can be described applying acid-base reaction formalism. Addressing the HSAB concept, the number of electrons transferred, ,N, in an acid-base reaction, allows for description and prediction of properties of composite and homogeneous materials. At first ,N helps in estimating the rate of reaction of binary systems with either given fuel or oxidizer. Nevertheless ,N is only a relative number thus the range of comparability remains narrow. At second ,N can be used as a measure for the sensitivity of homogeneous explosives. The increased reactivity of hypothetical fragments to recombine in a reaction such as R3C.+.NO2=R3C,NO2 given by ,N correlates very well with experimentally determined reduced impact sensitivity of 1,3,5-trinitrobenzene compounds. On the contrary the rising impact sensitivity of metal azides correlates with rising values of ,N of Mn+/N3, reaction because increased reactivity, that is increased electron transfer from the azide anion to the metal cation triggers formation of the azide radical (.N3). The latter then decomposes rapidly to give dinitrogen. This increased reactivity/sensitivity of metral azides coincides with covalent bonding whereas ionic azides are relatively insensitive. [source] Mathematical model for mixing index in gas,solid fluidized bed: an analysisASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 4 2010Abanti Sahoo Abstract An available theoretical model for mixing index in gas-solid fluidized bed has been analyzed for further modification and improvement. Assumption of 50% bed material moving in the upward direction and rest 50% in the downward direction considered for the above model (the counter-flow circulation model) has been analyzed for optimum result. A computer program was run for different bed conditions by varying operating parameters, namely, the mixture composition, fractions of bed materials, minimum fluidization velocity of the jetsam particles and that of the bed materials (i.e. mixture of the jetsam and the flotsam particles). The developed model was solved by finite difference (central differencing). Fraction of the bed material moving in the upward direction was varied from 0 to 100% and the minimum fluidization velocity was varied within the Umf of the flotsam to that of the jetsam particles (i.e. 0.465,1.0335 m/s). Optimum fraction of bed materials with respect to its distribution (as per the earlier proposed model) in the upward and downward streams during the fluidization process was found to be 20 and 80%, respectively. The modified model was validated by conducting experiments on fluidization and studying the mixing characteristics of regular homogeneous materials (sago) in a 15 × 100 cm cylindrical column. Fairly good agreement was observed between the values of mixing index obtained from the proposed modified model and the experimental observations. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] | ||||||||||||||||