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Good Thermal Properties (good + thermal_property)
Selected AbstractsPolyimide nanocomposites: Comparison of their properties with precursor polymer nanocompositesPOLYMER ENGINEERING & SCIENCE, Issue 12 2001Jin-Hae Chang A precursor poly(amic acid) was obtained by solution polymerization of pyromellitic dianhydride and benzidine in N, N-dimethylacetamide. Poly(amic acid)/Organoclay hybrids were prepared by the solution intercalation method with dodecylamine-montmorillonite. A polyimide hybrid was obtained from poly(amic acid) hybrid by heat treatment at various temperatures. The film type polyimide hybrids showed better thermal properties than poly(amic acid) hybrids. Also, the thermal stability of the two polymer hybrids were enhanced linearly with increasing clay content from 0 to 8 wt%. Tensile properties and gas barriers of the hybrids, however, were enhanced remarkably compared to pristine polymers. Intercalations of the polymer chains in clar were examined through wide angle X-ray diffraction (XRD) and electron microscopy (SEM and TEM). Transmission electron microscopy revealed that a partially exfoliated structure had been obtained from polyimide/organo-clay hybrids. [source] Synthesis and characterization of a thiadiazole/benzoimidazole-based copolymer for solar cell applicationsJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 20 2010Guan-yu Chen Abstract In this study, we synthesized a new polymer, PCTDBI, containing alternating carbazole and thiadiazole-benzoimidazole (TDBI) units. This polymer (number-average molecular weight = 25,600 g mol,1), which features a planar imidazole structure into the polymeric main chain, possesses reasonably good thermal properties (Tg = 105 °C; Td = 396 °C) and an optical band gap of 1.75 eV that matches the maximum photon flux of sunlight. Electrochemical measurements revealed an appropriate energy band offset between the polymer's lowest unoccupied molecular orbital and that of PCBM, thereby allowing efficient electron transfer between the two species. A solar cell device incorporating PCTDBI and PCBM at a blend ratio of 1:2 (w/w) exhibited a power conversion efficiency of 1.20%; the corresponding device incorporating PCTDBI and PC71BM (1:2, w/w) exhibited a PCE of 1.84%. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 [source] A simple approach toward low-dielectric polyimide nanocomposites: Blending the polyimide precursor with a fluorinated polyhedral oligomeric silsesquioxaneJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 18 2008Yun-Sheng Ye Abstract This article describes a new and simple method for preparing polyimide nanocomposites that have very low dielectric constants and good thermal properties: simply through blending the polyimide precursor with a fluorinated polyhedral oligomeric silsesquioxane derivative, octakis(dimethylsiloxyhexafluoropropyl) silsesquioxane (OF). The low polarizability of OF is compatible with polyimide matrices, such that it can improve the dispersion and free volume of the resulting composites. Together, the higher free volume and lower polarizability of OF are responsible for the lower dielectric constants of the PI-OF nanocomposites. This simple method for enhancing the properties of polyimides might have potential applicability in the electronics industry. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6296,6304, 2008 [source] Energetic polymer salts from 1-vinyl-1,2,4-triazole derivativesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 7 2008Hong Xue Abstract Energetic polymers salts from 1-vinyl-1,2,4-triazole derivatives have been synthesized via free radical polymerization of 1-vinyl-1,2,4-triazolium monomer salts or by protonation of poly(1-vinyl-1,2,4-triazole) with inorganic or organic acids. Standard enthalpies of formation of the new monomer salts were calculated using the computationally feasible DFT(B3LYP) and MP2 methods in conjunction with an empirical approach based on densities of salts. Compared with the monomer salts, the polymer salts have good thermal properties with high densities > 1.5 g cm,3. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2414,2421, 2008 [source] Synthesis and properties of novel conjugated poly(silylacetylene silazane)sJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 12 2004Ji Dong Hu Abstract A series of novel conjugated polymers, poly(silylacetylene silazane)s having different substituents, were prepared by ammonolysis of the corresponding ,,,-dichlorosilyleneacetylene oligomers. The structures and properties of the poly(silylacetylene silazane)s were characterized by Fourier transform infrared, 1H, 13C, 29Si NMR, and elemental analyses, gel permeation chromatography, thermogravimetric analysis, differential scanning calorimetry, and spectrofluorophotometry. The resulting polymers had good thermal properties and were moderately fluorescent. Their thermal stability was improved, and obvious red shift was observed when a phenyl substituent was attached on a silicon atom of polymers in the emission spectra. These polymers have the potential to be used as light-emitting materials with good thermal stability. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2897,2903, 2004 [source] Effect of temperature distribution and current crowding on the performance of lateral GaN-based light-emitting diodesPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 7-8 2010Dongpyo Han Abstract Current crowding effect is detrimental for the performance of light-emitting diodes (LEDs), causing non-uniform light emission and local heat generation. In particular, heat generated by non-uniform current distribution can badly influence the performance of LED devices. In this paper, we examine the temperature distributions of lateral InGaN/GaN multiple-quantum-well LEDs in relation to current crowding, using both simulation and experimental results. Simulation results are obtained from a 3-dimensional electrical circuit model consisting of resistances and intrinsic diodes. Temperature and luminance distributions are investigated by images taken by an infrared camera and a charge-coupled-device camera, respectively. Finally, the internal quantum efficiency is taken for each device and compared. We show that the thermal property in the lateral LED is affected by the current crowding due to the local Joule heating nearby electrodes. Therefore, uniform current spreading is very important not only for uniform luminance distribution but also for good thermal property in the LED device. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||