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Geothermal Gradient (geothermal + gradient)
Selected AbstractsUnravelling the multi-stage burial history of the Swiss Molasse Basin: integration of apatite fission track, vitrinite reflectance and biomarker isomerisation analysisBASIN RESEARCH, Issue 1 2006Martin Mazurek ABSTRACT A complex basin evolution was studied using various methods, including thermal constraints based on apatite fission-track (AFT) analysis, vitrinite reflectance (VR) and biomarker isomerisation, in addition to a detailed analysis of the regional stratigraphic record and of the lithological properties. The study indicates that (1) given the substantial amount of data, the distinction and characterisation of successive stages of heating and burial in the same area are feasible, and (2) the three thermal indicators (AFT, VR and biomarkers) yield internally consistent thermal histories, which supports the validity of the underlying kinetic algorithms and their applicability to natural basins. All data pertaining to burial and thermal evolution were integrated in a basin model, which provides constraints on the thickness of eroded sections and on heat flow over geologic time. Three stages of basin evolution occurred in northern Switzerland. The Permo-Carboniferous strike,slip basin was characterised by high geothermal gradients (80,100°C km,1) and maximum temperature up to 160°C. After the erosion of a few hundreds of metres in the Permian, the post-orogenic, epicontinental Mesozoic basin developed in Central Europe, with subsidence triggered by several stages of rifting. Geothermal gradients in northern Switzerland during Cretaceous burial were relatively high (35,40°C km,1), and maximum temperature typically reached 75°C (top middle Jurassic) to 100°C (base Mesozoic). At least in the early Cretaceous, a stage of increased heat flow is needed to explain the observed maturity level. After erosion of 600,700 m of Cretaceous and late Jurassic strata during the Paleocene, the wedge-shaped Molasse Foreland Basin developed. Geothermal gradients were low at this time (,20°C km,1). Maximum temperature of Miocene burial exceeded that of Cretaceous burial in proximal parts (<35 km from the Alpine front), but was lower in more distal parts (>45 km). Thus, maximum temperature as well as maximum burial depth ever reached in Mesozoic strata occurred at different times in different regions. Since the Miocene, 750,1050 m were eroded, a process that still continues in the proximal parts of the basin. Current average geothermal gradients in the uppermost 2500 m are elevated (32,47°C km,1). They are due to a Quaternary increase of heat flow, most probably triggered by limited advective heat transport along Paleozoic faults in the crystalline basement. [source] Algorithm for determining optimum sequestration depth of CO2 trapped by residual gas and solubility trapping mechanisms in a deep saline formationGEOFLUIDS (ELECTRONIC), Issue 4 2008C. K. LIN Abstract An algorithm is proposed here for determining the optimum sequestration depth (in terms of depth corresponding to maximum net income per unit rock volume) in a saline formation for CO2 trapped by residual gas and solubility trapping mechanisms. The Peng,Robinson equation of state was used to determine the density and fugacity of sequestered CO2 and the compression energy required for CO2 injection. Geochemist's Workbench®, a commercial geochemical software package, was used to estimate CO2 solubility in groundwater. Operational costs and CO2 emissions due to compression energy consumption were estimated. A hypothetical reference case was constructed to illustrate the proposed algorithm, assuming constant values of geothermal gradient, hydrostatic pressure gradient, sweep efficiency and initial groundwater chemistry, with a depth-dependent porosity and porosity-dependent saturation of residual gas. In general, the algorithm was illustrated successfully for the hypothetical reference case and produced the following results. The depth corresponding to maximum trapping capacity was approximately 3000 m, but the depth representing maximum net income was approximately 1300 m. CO2 emissions due to compression energy consumption per unit mass of CO2 sequestration cannot be ignored, but may be <0.15, even down to a depth of 7000 m. Both the trapping capacity and net income of CO2 sequestration decreased with geothermal gradient, but the corresponding optimum depths increased with geothermal gradient. [source] Composition and evolution of fluids during skarn development in the Monte Capanne thermal aureole, Elba Island, central ItalyGEOFLUIDS (ELECTRONIC), Issue 3 2008F. ROSSETTI Abstract We describe the chemistry of the fluids circulating during skarn formation by focusing on fluids trapped in calcsilicate minerals of the inner thermal aureole of the Late Miocene Monte Capanne intrusion of western Elba Island (central Italy). Primary, CH4 -dominant, C-O-H-S-salt fluid inclusions formed during prograde growth of the main skarn-forming mineral phases: grossular/andradite and vesuvianite. The variable phase ratios attest to heterogeneous entrapment of fluid, with co-entrapment of an immiscible hydrocarbon,brine mixture. Chemical elements driving skarn metasomatism such as Na, K, Ca, S and Cl, Fe and Mn were dominantly partitioned into the circulating fluid phase. The high salinity (apparent salinity between 58 and 70 wt% NaCl eq.) and the C-component of the fluids are interpreted as evidence for a composite origin of the skarn-forming fluids that involves both fluids derived from the crystallizing intrusion and contributions from metamorphic devolatilization. Oxidation of a Fe-rich brine in an environment dominated by fluctuation in pressure from lithostatic to hydrostatic conditions (maintained by active crack-sealing) contributed to skarn development. Fluid infiltration conformed to a geothermal gradient of about 100°C km,1, embracing the transition from high-temperature contact metamorphism and fluid-assisted skarn formation (at ca 600°C) to a barren hydrothermal stage (at ca 200°C). [source] Late Cretaceous-Cenozoic exhumation of the Yanji area, northeast China: Constraints from fission-track thermochronologyISLAND ARC, Issue 1 2010Xiaoming Li Abstract The Yanji area, located at the border of China, Russia, and Korea, where the Phanerozoic granitoids have been widely exposed, was considered part of the orogenic collage between the North China Block in the south and the Jiamusi,Khanka Massifs in the northeast. In this study, the cooling and inferred uplift and denudation history since the late Mesozoic are intensively studied by carrying out apatite and zircon fission-track analyses, together with electron microprobe analyses (EMPA) of chemical compositions of apatite from the granitoid samples in the Yanji area. The results show that: (i) zircon and apatite fission-track ages range 91.7,99.6 Ma and 76.5,85.4 Ma, respectively; (ii) all apatite fission-track length distributions are unimodal and yield mean lengths of 12,13.2 µm, and the apatites are attributed to chlorine-bearing fluorapatite as revealed by EMPA results; and (iii) the thermal history modeling results based on apatite fission-track grain ages and length distributions indicate that the time,temperature paths display similar patterns and the cooling has been accelerated for each sample since ca 15 Ma. Thus, we conclude that sequential cooling, involving two rapid (95,80 Ma and ca 15,0 Ma) and one slow (80,15 Ma) cooling, has taken place through the exhumation of the Yanji area since the late Cretaceous. The maximum exhumation is more than 5 km under a steady-state geothermal gradient of 35°C/km. Combined with the tectonic setting, this exhumation is possibly related to the subduction of the Pacific Plate beneath the Eurasian Plate since the late Cretaceous. [source] Petrology of coesite-bearing eclogite from Habutengsu Valley, western Tianshan, NW China and its tectonometamorphic implicationJOURNAL OF METAMORPHIC GEOLOGY, Issue 9 2009Z. LÜ Abstract Coesite inclusions in garnet have been found in eclogite boudins enclosed in coesite-bearing garnet micaschist in the Habutengsu Valley, Chinese western Tianshan, which are distinguished from their retrograde quartz by means of optical characteristics, CL imaging and Raman spectrum. The coesite-bearing eclogite is mainly composed of porphyroblastic garnet, omphacite, paragonite, glaucophane and barroisite, minor amounts of rutile and dotted (or banded) graphite. In addition to coesite and quartz, the zoned porphyroblastic garnet contains inclusions of omphacite, Na-Ca amphibole, calcite, albite, chlorite, rutile, ilmenite and graphite. Multi-phase inclusions (e.g. Czo + Pg ± Qtz, Grt II + Qtz and Chl + Pg) can be interpreted as breakdown products of former lawsonite and possibly chloritoid. Coesite occurs scattered within a compositionally homogenous but narrow domain of garnet (outer core), indicative of equilibrium at the UHP stage. The estimate by garnet-clinopyroxene thermometry yields peak temperatures of 420,520 °C at 2.7 GPa. Phase equilibrium calculations further constrain the P,T conditions for the UHP mineral assemblage Grt + Omp + Lws + Gln + Coe to 2.4,2.7 GPa and 470,510 °C. Modelled modal abundances of major minerals along a 5 °C km,1 geothermal gradient suggests two critical dehydration processes at ,430 and ,510 °C respectively. Computed garnet composition patterns are in good agreement with measured core-rim profiles. The petrological study of coesite-bearing eclogite in this paper provides insight into the metamorphic evolution in a cold subduction zone. Together with other reported localities of UHP rocks from the entire orogen of Chinese western Tianshan, it is concluded that the regional extent of UHP-LT metamorphism in Chinese western Tianshan is extensive and considerably larger than previously thought, although intensive retrogression has erased UHP-LT assemblages at most localities. [source] Variations in the transient prograde geothermal gradient from chloritoid-staurolite equilibria: a case study from the Barrovian and Buchan-type domains in the Bohemian MassifJOURNAL OF METAMORPHIC GEOLOGY, Issue 1 2007M. KO Abstract Thermodynamic modelling of metamorphic rocks increases the possibilities of deciphering prograde paths that provide important insights into early orogenic evolution. It is shown that the chloritoid,staurolite transition is not only an indicator of temperature on prograde P,T paths, but also a useful indicator of pressure. The approach is applied to the Moravo-Silesian eastern external belt of the Bohemian Massif, where metamorphic zones range from biotite to staurolite-sillimanite. In the staurolite zone, inclusions of chloritoid occur in garnet cores, while staurolite is included at garnet rims and is widespread in the matrix. Chloritoid XFe = 0.91 indicates transition to staurolite at 5 kbar and 550 °C and consequently, an early transient prograde geothermal gradient of 29 °C km,1. The overall elevated thermal evolution is then reflected in the prograde transition of staurolite to sillimanite and in the achievement of peak temperature of 660 °C at a relatively low pressure of 6.5 kbar. To the south and to the west of the studied area, high-grade metamorphic zones record a prograde path evolution from staurolite to kyanite and development of sillimanite on decompression. Transition of chloritoid to staurolite was reported in two places, with chloritoid XFe = 0.75,0.80, occurring at 8,10 kbar and 560,580 °C, and indicating a transient prograde geothermal gradient of 16,18 °C km,1. These data show variable barric evolutions along strike and across the Moravo-Silesian domain. Elevated prograde geothermal gradient coincides with areas of Devonian sedimentation and volcanism, and syn- to late Carboniferous intrusions. Therefore, we interpret it as a result of heat inherited from Devonian rifting, further fuelled by syntectonic Carboniferous intrusions. [source] Petrochemical constraints for dual origin of garnet peridotites from the Dabie-Sulu UHP terrane, eastern-central ChinaJOURNAL OF METAMORPHIC GEOLOGY, Issue 2 2000Zhang Garnet peridotites occur as lenses, blocks or layers within granulite,amphibolite facies gneiss in the Dabie-Sulu ultra-high-pressure (UHP) terrane and contain coesite-bearing eclogite. Two distinct types of garnet peridotite were identified based on mode of occurrence and petrochemical characteristics. Type A mantle-derived peridotites originated from either: (1) the mantle wedge above a subduction zone, (2) the footwall mantle of the subducted slab, or (3) were ancient mantle fragments emplaced at crustal depths prior to UHP metamorphism, whereas type B crustal peridotite and pyroxenite are a portion of mafic,ultramafic complexes that were intruded into the continental crust as magmas prior to subduction. Most type A peridotites were derived from a depleted mantle and exhibit petrochemical characteristics of mantle rocks; however, Sr and Nd isotope compositions of some peridotites have been modified by crustal contamination during subduction and/or exhumation. Type B peridotite and pyroxenite show cumulate structure, and some have experienced crustal metasomatism and contamination documented by high 87Sr/86Sr ratios (0.707,0.708), low ,Nd(t) values (,6 to ,9) and low ,18O values of minerals (+2.92 to +4.52). Garnet peridotites of both types experienced multi-stage recrystallization; some of them record prograde histories. High- P,T estimates (760,970 °C and 4.0,6.5±0.2 GPa) of peak metamorphism indicate that both mantle-derived and crustal ultramafic rocks were subducted to profound depths >100 km (the deepest may be ,180,200 km) and experienced UHP metamorphism in a subduction zone with an extremely low geothermal gradient of <5 °C km,1. [source] PETROLEUM POTENTIAL, THERMAL MATURITY AND THE OIL WINDOW OF OIL SHALES AND COALS IN CENOZOIC RIFT BASINS, CENTRAL AND NORTHERN THAILANDJOURNAL OF PETROLEUM GEOLOGY, Issue 4 2006H. I. Petersen Oil shales and coals occur in Cenozoic rift basins in central and northern Thailand. Thermally immature outcrops of these rocks may constitute analogues for source rocks which have generated oil in several of these rift basins. A total of 56 oil shale and coal samples were collected from eight different basins and analysed in detail in this study. The samples were analysed for their content of total organic carbon (TOC) and elemental composition. Source rock quality was determined by Rock-Eval pyrolysis. Reflected light microscopy was used to analyse the organic matter (maceral) composition of the rocks, and the thermal maturity was determined by vitrinite reflectance (VR) measurements. In addition to the 56 samples, VR measurements were carried out in three wells from two oil-producing basins and VR gradients were constructed. Rock-Eval screening data from one of the wells is also presented. The oil shales were deposited in freshwater (to brackish) lakes with a high preservation potential (TOC contents up to 44.18 wt%). They contain abundant lamalginite and principally algal-derived fluorescing amorphous organic matter followed by liptodetrinite and telalginite (Botryococcus-type). Huminite may be present in subordinate amounts. The coals are completely dominated by huminite and were formed in freshwater mires. VR values from 0.38 to 0.47%Ro show that the exposed coals are thermally immature. VR values from the associated oil shales are suppressed by 0.11 to 0.28%Ro. The oil shales have H/C ratios >1.43, and Hydrogen Index (HI) values are generally >400 mg HC/g TOC and may reach 704 mg HC/ gTOC. In general, the coals have H/C ratios between about 0.80 and 0.90, and the HI values vary considerably from approximately 50 to 300 mg HC/gTOC. The HImax of the coals, which represent the true source rock potential, range from ,160 to 310 mg HC/g TOC indicating a potential for oil/gas and oil generation. The steep VR curves from the oil-producing basins reflect high geothermal gradients of ,62°C/km and ,92°C/km. The depth to the top oil window for the oil shales at a VR of ,0.70%Ro is determined to be between ,1100 m and 1800 m depending on the geothermal gradient. The kerogen composition of the oil shales and the high geothermal gradients result in narrow oil windows, possibly spanning only ,300 to 400 m in the warmest basins. The effective oil window of the coals is estimated to start from ,0.82 to 0.98%Ro and burial depths of ,1300 to 1400 m (,92°C/km) and ,2100 to 2300 m (,62°C/km) are necessary for efficient oil expulsion to occur. [source] A fossilized Opal A to Opal C/T transformation on the northeast Atlantic margin: support for a significantly elevated Palaeogeothermal gradient during the Neogene?BASIN RESEARCH, Issue 4 2002R. J. Davies ABSTRACT Rock samples , collected from a recent deep-water exploration well drilled in the Faeroe-Shetland Channel, northwest of the UK , confirm that a distinctive high-amplitude seismic reflector that cross-cuts the Upper Palaeogene and Neogene succession and covers an area of 10 000 km2 is an example of a fossilized Opal A to Opal C/T (Cristobalite/Tridymite) transition. Analysis of these rock fragments tied to an extensive two-dimensional and three-dimensional seismic database constrains the time at which the boundary was fossilized and in addition reveals the unusual geometrical characteristics of a relict bottom-simulating reflector. The diagenetic transformation of biogenic silica (Opal A) to Opal C/T is predominantly temperature-controlled and requires sediments that contain biogenic silica. The reflector (termed as Horizon E) probably initially represented a biosiliceous ooze or a siltstone that contained a component of biogenic silica that underwent transformation as the diagenetic front migrated upsection during burial. The parallelism it shows with a shallower early Pliocene reflector and its apparent upsection migration during a compressional episode in the basin indicate that it was active during the middle and late Miocene and ceased activity during the early Pliocene when there was between 200 and 400 m of overburden. The present-day burial depth of the boundary is ca. 700 m and the temperature at the inactive diagenetic front at the well location is 24 °C. Given these temperature and depth constraints, we hypothesize that even if this is an example of a relatively low-temperature Opal A to Opal C/T transformation, a temporarily elevated geothermal gradient of ca. 60 °C km,1 would have been required to initiate and arrest upsection migration of the boundary during the middle and late Miocene. Factors such as climatic deterioration and the onset of cold deep-water circulation are likely to only have had a contributory role in arresting the upward migration of the boundary. [source] Insulating effect of coals and organic rich shales: implications for topography-driven fluid flow, heat transport, and genesis of ore deposits in the Arkoma Basin and Ozark PlateauBASIN RESEARCH, Issue 2 2002J.A. Nunn ABSTRACT Sedimentary rocks rich in organic matter, such as coal and carbonaceous shales, are characterized by remarkably low thermal conductivities in the range of 0.2,1.0 W m,1 °C,1, lower by a factor of 2 or more than other common rock types. As a result of this natural insulating effect, temperature gradients in organic rich, fine-grained sediments may become elevated even with a typical continental basal heat flow of 60 mW m,2. Underlying rocks will attain higher temperatures and higher thermal maturities than would otherwise occur. A two-dimensional finite element model of fluid flow and heat transport has been used to study the insulating effect of low thermal conductivity carbonaceous sediments in an uplifted foreland basin. Topography-driven recharge is assumed to be the major driving force for regional groundwater flow. Our model section cuts through the Arkoma Basin to Ozark Plateau and terminates near the Missouri River, west of St. Louis. Fluid inclusions, organic maturation, and fission track evidence show that large areas of upper Cambrian rocks in southern Missouri have experienced high temperatures (100,140 °C) at shallow depths (< 1.5 km). Low thermal conductivity sediments, such as coal and organic rich mudstone were deposited over the Arkoma Basin and Ozark Plateau, as well as most of the mid-continent of North America, during the Late Palaeozoic. Much of these Late Palaeozoic sediments were subsequently removed by erosion. Our model results are consistent with high temperatures (100,130 °C) in the groundwater discharge region at shallow depths (< 1.5 km) even with a typical continental basal heat flow of 60 mW m,2. Higher heat energy retention in basin sediments and underlying basement rocks prior to basin-scale fluid flow and higher rates of advective heat transport along basal aquifers owing to lower fluid viscosity (more efficient heat transport) contribute to higher temperatures in the discharge region. Thermal insulation by organic rich sediments which traps heat transported by upward fluid advection is the dominant mechanism for elevated temperatures in the discharge region. This suggests localized formation of ore deposits within a basin-scale fluid flow system may be caused by the juxtaposition of upward fluid discharge with overlying areas of insulating organic rich sediments. The additional temperature increment contributed to underlying rocks by this insulating effect may help to explain anomalous thermal maturity of the Arkoma Basin and Ozark Plateau, reducing the need to call upon excessive burial or high basal heat flow (80,100 mW m,2) in the past. After subsequent uplift and erosion remove the insulating carbonaceous layer, the model slowly returns to a normal geothermal gradient of about 30 °C km,1. [source] Late Cretaceous-Cenozoic Exhumation History of the Lüliang Mountains, North China Craton: Constraint from Fission-track ThermochronologyACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 2 2010Xiaoming LI Abstract: The Lüliang Mountains, located in the North China Craton, is a relatively stable block, but it has experienced uplift and denudation since the late Mesozoic. We hence aim to explore its time and rate of the exhumation by the fission-track method. The results show that, no matter what type rocks are, the pooled ages of zircon and apatite fission-track range from 60.0 to 93.7 Ma and 28.6 to 43.3 Ma, respectively; all of the apatite fission-track length distributions are unimodal and yield a mean length of ,13 ,m; and the thermal history modeling results based on apatite fission-track data indicate that the time-temperature paths exhibit similar patterns and the cooling has been accelerated for each sample since the Pliocene (c.5 Ma). Therefore, we can conclude that a successive cooling, probably involving two slow (during c.75,35 Ma and 35,5 Ma) and one rapid (during c.5 Ma-0 Ma) cooling, has occurred through the exhumation of the Lüliang Mountains since the late Cretaceous. The maximum exhumation is more than 5 km under a steady-state geothermal gradient of 35°C/km. Combined with the tectonic setting, this exhumation may be the resultant effect from the surrounding plate interactions, and it has been accelerated since c.5 Ma predominantly due to the India-Eurasia collision. [source] A Preliminary Study of the Gas Hydrate Stability Zone in the South China SeaACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 4 2002JIN Chunshuang Abstract, Based on the analysis of sea-bottom temperature and geothermal gradient, and by means of the phase boundary curve of gas hydrate and the sea-bottom temperature versus water depth curve in the South China Sea, this paper studies the temperature and pressure conditions for gas hydrate to keep stable. In a marine environment, methane hydrate keeps stable at water depths greater than 550 m in the South China Sea. Further, the thickness of the gas hydrate stability zone in the South China Sea was calculated by using the phase boundary curve and temperature-depth equations. The result shows that gas hydrate have a better perspective in the southeast of the Dongsha Islands, the northeast of the Xisha Islands and the north of the Nansha Islands for thicker stability zones. [source] Prograde eclogites from the Tonaru epidote amphibolite mass in the Sambagawa Metamorphic Belt, central Shikoku, southwest JapanISLAND ARC, Issue 3 2005Yasuo Miyagi Abstract Prograde eclogites occur in the Tonaru epidote amphibolite mass in the Sambagawa Metamorphic Belt of central Shikoku. The Tonaru mass is considered to be a metamorphosed layered gabbro, and occurs as a large tectonic block (approximately 6.5 km × 1 km) in a high-grade portion of the Sambagawa schists. The Tonaru mass experienced high- P/low- T prograde metamorphism from the epidote-blueschist facies to the eclogite facies prior to its emplacement into the Sambagawa schists. The estimated P,T conditions are T = 300,450°C and P = 0.7,1.1 GPa for the epidote-blueschist facies, and the peak P,T conditions for the eclogite facies are T = 700,730°C and P , 1.5 GPa. Following the eclogite facies metamorphism, the Tonaru mass was retrograded to the epidote amphibolite facies. It subsequently underwent additional prograde Sambagawa metamorphism, together with the surrounding Sambagawa schists, until the conditions of the oligoclase,biotite zone were reached. The high- P/low- T prograde metamorphism of the eclogite facies in the Tonaru mass and other tectonic blocks show similar steep dP/dT geothermal gradients despite their diverse peak P,T conditions, suggesting that these tectonic blocks reached different depths in the subduction zone. The individual rocks in each metamorphic zone of the Sambagawa schists also recorded steep dP/dT geothermal gradients during the early stages of the Sambagawa prograde metamorphism, and these gradients are similar to those of the eclogite-bearing tectonic blocks. Therefore, the eclogite-bearing tectonic blocks reached greater depths in the subduction zone than the Sambagawa schists. All the tectonic blocks were ultimately emplaced into the hanging wall side of the later-subducted Sambagawa high-grade schists during their exhumation. [source] Separate or shared metamorphic histories of eclogites and surrounding rocks?JOURNAL OF METAMORPHIC GEOLOGY, Issue 3 2006An example from the Bohemian Massif Abstract Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite-dominated volcano-sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite-bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet,staurolite,kyanite,biotite,plagioclase,muscovite,quartz,ilmenite ± rutile ± silli-manite and prograde-zoned garnet includes chloritoid,chlorite,paragonite,margarite, staurolite,chlorite,paragonite,margarite and kyanite,chlorite,rutile. In pseudosection modelling in the system Na2O,CaO,K2O,FeO,MgO,Al2O3,SiO2,H2O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite,+,paragonite (with muscovite + quartz + H2O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet,staurolite,biotite,muscovite,quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet,amphibole,plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610,660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase,clinopyroxene symplectites, epidote and late amphibole,plagioclase domains. Garnet commonly includes rutile,quartz,epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H2O-undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote,amphibole,plagioclase indicating that decompression occurred under decreasing temperature into garnet-free epidote,amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km,1, respectively, to metamorphic pressure peaks that are 6,7 kbar apart. The eclogite,orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared. [source] PETROLEUM POTENTIAL, THERMAL MATURITY AND THE OIL WINDOW OF OIL SHALES AND COALS IN CENOZOIC RIFT BASINS, CENTRAL AND NORTHERN THAILANDJOURNAL OF PETROLEUM GEOLOGY, Issue 4 2006H. I. Petersen Oil shales and coals occur in Cenozoic rift basins in central and northern Thailand. Thermally immature outcrops of these rocks may constitute analogues for source rocks which have generated oil in several of these rift basins. A total of 56 oil shale and coal samples were collected from eight different basins and analysed in detail in this study. The samples were analysed for their content of total organic carbon (TOC) and elemental composition. Source rock quality was determined by Rock-Eval pyrolysis. Reflected light microscopy was used to analyse the organic matter (maceral) composition of the rocks, and the thermal maturity was determined by vitrinite reflectance (VR) measurements. In addition to the 56 samples, VR measurements were carried out in three wells from two oil-producing basins and VR gradients were constructed. Rock-Eval screening data from one of the wells is also presented. The oil shales were deposited in freshwater (to brackish) lakes with a high preservation potential (TOC contents up to 44.18 wt%). They contain abundant lamalginite and principally algal-derived fluorescing amorphous organic matter followed by liptodetrinite and telalginite (Botryococcus-type). Huminite may be present in subordinate amounts. The coals are completely dominated by huminite and were formed in freshwater mires. VR values from 0.38 to 0.47%Ro show that the exposed coals are thermally immature. VR values from the associated oil shales are suppressed by 0.11 to 0.28%Ro. The oil shales have H/C ratios >1.43, and Hydrogen Index (HI) values are generally >400 mg HC/g TOC and may reach 704 mg HC/ gTOC. In general, the coals have H/C ratios between about 0.80 and 0.90, and the HI values vary considerably from approximately 50 to 300 mg HC/gTOC. The HImax of the coals, which represent the true source rock potential, range from ,160 to 310 mg HC/g TOC indicating a potential for oil/gas and oil generation. The steep VR curves from the oil-producing basins reflect high geothermal gradients of ,62°C/km and ,92°C/km. The depth to the top oil window for the oil shales at a VR of ,0.70%Ro is determined to be between ,1100 m and 1800 m depending on the geothermal gradient. The kerogen composition of the oil shales and the high geothermal gradients result in narrow oil windows, possibly spanning only ,300 to 400 m in the warmest basins. The effective oil window of the coals is estimated to start from ,0.82 to 0.98%Ro and burial depths of ,1300 to 1400 m (,92°C/km) and ,2100 to 2300 m (,62°C/km) are necessary for efficient oil expulsion to occur. [source] Prediction of formation temperatures in permafrost regions from temperature logs in deep wells,field casesPERMAFROST AND PERIGLACIAL PROCESSES, Issue 3 2003I. M. Kutasov Abstract Important data on the thermal regime of the Earth's interior come from temperature measurements in deep boreholes. Drilling greatly alters the temperature field of earth materials surrounding the wellbore. In permafrost regions, due to thawing of adjacent strata during drilling, representative data can be obtained only by repeated observations over a long period of time. In this paper we predict undisturbed formation temperatures (and geothermal gradients) from shut-in temperature logs in deep wells. The main features of the method are: (1) in the permafrost section of the well, the starting point in the well thermal recovery is moved from the end of well completion to the moment of time when the refreezing of enclosing strata was completed; it takes into account the refreezing of thawed material in a temperature interval; and (2) below the permafrost base, the starting point in the well thermal recovery is moved from the end of well completion to the moment of time when the first shut-in temperature log was taken. A generalized formula to process field data (for the well sections below and above the permafrost base) is presented. Temperature logs conducted in five wells verify the method. Copyright © 2003 John Wiley & Sons, Ltd. [source] Three deep Alpine-permafrost boreholes in Svalbard and ScandinaviaPERMAFROST AND PERIGLACIAL PROCESSES, Issue 1 2001Ketil Isaksen Abstract The presence and thermal character of permafrost reflect past and present surface energy balances plus the heat flux from the Earth's interior. Analysis of permafrost ground temperatures constitutes a key research tool for detecting thermal anomalies caused by twentieth-century warming. Three deep boreholes in alpine permafrost were drilled in Svalbard and Scandinavia and form part of the latitudinal transect of mountain permafrost boreholes through the mountains of Europe established under the EU PACE (Permafrost and Climate in Europe) project. The northernmost borehole in the transect, at Janssonhaugen (depth 102 m), western Svalbard (78°10,46,,N, 16°28,01,,E, 270 m ASL) was drilled in May 1998. In Scandinavia, boreholes were drilled at Tarfalaryggen (depth 100 m), northern Sweden (67°55,09,,N, 18°38,29,,E, 1550 m ASL) in March 2000 and at Juvvasshøe (depth 129 m), southern Norway (61°40,32,,N, 08°22,04,,E, 1894 m ASL) in August 1999. Permafrost thickness at Janssonhaugen is estimated as approximately 220 m. The temperature profiles on Tarfalaryggen and Juvvasshøe show anomalously low geothermal gradients, indicating low heat flow through thick permafrost (,350 m and ,380 m respectively). Palaeoclimatic analysis based on inversion modelling of the ground temperature measurements at Janssonhaugen shows near surface warming of 1.5 ± 0.5 °C during the twentieth century. Both the Tarfalaryggen and Juvvasshøe boreholes also reveal thermal anomalies, which reflect a surface warming over the past decades, with a magnitude of approximately 0.5,1.0 °C. Copyright © 2001 John Wiley & Sons, Ltd. RÉSUMÉ L'existence d'un pergélisol ainsi que ses caractères thermiques reflètent la balance entre l'énergie de surface (passée et actuelle) et le flux de chaleur interne de la terre. L'étude des températures du pergélisol constitue ainsi une recherche fondamentale pour détecter les anomalies thermiques dues au réchauffement du vingtième siècle. Trois sondages profonds dans le pergélisol alpin ont été réalisés au Svalbard et en Scandinavie. Ils constituent une partie du transect en latitude de sondages du pergélisol de montagne réalisé dans le cadre du projet de l'Union Européenne Pace (Pergélisol et Climat en Europe). Le sondage le plus septentrional du transect a été foré en mai 1998 à Janssonhaugen (profondeur 102 m), à l'ouest de Svalbard (78°10,46,,N, 16°28,01,,E, à 270 m d'altitude). En Scandinavie, des sondages ont été réalisés en mars 2000 à Tarfallaryggen (profondeur 100 m) au nord de la Suède (67°55,09,,N, 18°38,29,,E, à 1550 m d'altitude) et en août 1999 à Juvvasshoe (profondeur 129 m), au sud de la Norvège (61°40,32,,N, 08°22,04,,E, à 1894 m d'altitude). L'épaisseur du pergélisol à Janssonhaugen est approximativement de 220 m. Les profils de température à Tarfalaryggen et à Juvvasshoe montrent des gradients géothermiques anormalement faibles, indiquant un faible écoulement de chaleur au travers d'un pergélisol épais (respectivement d'environ 350 m et 380 m). Des analyses paléoclimatiques basées sur un modèle d'inversion des mesures de la température du sol à Janssonhaugen indiquent un réchauffement près de la surface de 1.5 0.5 °C pendant le 20e siècle. A la fois à Tarfalarygen et à Juvvasshoe, les anomalies thermiques existantes révèlent un réchauffement de la surface d'une ampleur de approximative de 0.5 à 1.0 °C au cours des dernières décades [source] Unravelling the multi-stage burial history of the Swiss Molasse Basin: integration of apatite fission track, vitrinite reflectance and biomarker isomerisation analysisBASIN RESEARCH, Issue 1 2006Martin Mazurek ABSTRACT A complex basin evolution was studied using various methods, including thermal constraints based on apatite fission-track (AFT) analysis, vitrinite reflectance (VR) and biomarker isomerisation, in addition to a detailed analysis of the regional stratigraphic record and of the lithological properties. The study indicates that (1) given the substantial amount of data, the distinction and characterisation of successive stages of heating and burial in the same area are feasible, and (2) the three thermal indicators (AFT, VR and biomarkers) yield internally consistent thermal histories, which supports the validity of the underlying kinetic algorithms and their applicability to natural basins. All data pertaining to burial and thermal evolution were integrated in a basin model, which provides constraints on the thickness of eroded sections and on heat flow over geologic time. Three stages of basin evolution occurred in northern Switzerland. The Permo-Carboniferous strike,slip basin was characterised by high geothermal gradients (80,100°C km,1) and maximum temperature up to 160°C. After the erosion of a few hundreds of metres in the Permian, the post-orogenic, epicontinental Mesozoic basin developed in Central Europe, with subsidence triggered by several stages of rifting. Geothermal gradients in northern Switzerland during Cretaceous burial were relatively high (35,40°C km,1), and maximum temperature typically reached 75°C (top middle Jurassic) to 100°C (base Mesozoic). At least in the early Cretaceous, a stage of increased heat flow is needed to explain the observed maturity level. After erosion of 600,700 m of Cretaceous and late Jurassic strata during the Paleocene, the wedge-shaped Molasse Foreland Basin developed. Geothermal gradients were low at this time (,20°C km,1). Maximum temperature of Miocene burial exceeded that of Cretaceous burial in proximal parts (<35 km from the Alpine front), but was lower in more distal parts (>45 km). Thus, maximum temperature as well as maximum burial depth ever reached in Mesozoic strata occurred at different times in different regions. Since the Miocene, 750,1050 m were eroded, a process that still continues in the proximal parts of the basin. Current average geothermal gradients in the uppermost 2500 m are elevated (32,47°C km,1). They are due to a Quaternary increase of heat flow, most probably triggered by limited advective heat transport along Paleozoic faults in the crystalline basement. [source] Apatite fission track thermochronology: an overview of its potential and limitations in geomorphologyBASIN RESEARCH, Issue 2 2000Gunnell The specific time window of apatite fission track thermochronology (AFTT) places it in a unique position to offer continuous time,temperature baseline histories for relatively stable shield, rift and passive margin environments, spanning several geological eras. Fission tracks anneal partially at temperatures between ,110 °C and ,60 °C and thereby provide information on residence times within specific levels of the crust. Most samples collected from these terrains, however, are usually found to have cooled out of the apatite partial annealing zone (APAZ) by the mid-Cenozoic at the latest. Owing to the stability, at geological timescales, of tracks at temperatures <60 °C (i.e. within depths of 0,2.5 km at normal geothermal gradients), a significant loss of resolution must therefore be reckoned with at shallow, although geomorphologically crucial, crustal depths. Indeed, the Neogene and Quaternary are understood to have been most influential in generating the scenery of today, and a use of radiometric and stratigraphic techniques in a nested, multisystem approach can assist in bridging the resolution gap. This paper examines and illustrates, mostly with original examples, the uses and limitations of AFTT in addressing the response of Earth surface systems to event patterns in global tectonics, the controls of lithology and structure on denudation rates, the origin and evolution of passive margin escarpments, the mass-balanced reconstruction of palaeoelief, the use of apatites as tracers for understanding provenance in sediment routing systems, and the tempo (or episodicity) of denudation as postulated by W. M. Davis' canons of the ,geographical cycle'. Alongside efforts towards standardizing the supply of analytically robust AFT results in the laboratory, a more standardized geoscientific interpretation of AFT data is also desirable in order to build a consistent world base of geomorphic rates which can be made available to , and used with confidence by , non-AFTT specialists. [source] | ||||||||||