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Geological Materials (geological + material)
Selected AbstractsTHE HISTORY OF THE LAWRENCE BERKELEY NATIONAL LABORATORY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS PROGRAMME FOR ARCHAEOLOGICAL AND GEOLOGICAL MATERIALSARCHAEOMETRY, Issue 2 2007F. ASARO The Lawrence Berkeley National Laboratory pottery provenance group developed standards and instrumental neutron activation analysis (INAA) methods that are used at many archaeometry laboratories around the world. The background and development of ,Standard Pottery' and of methods for INAA are described. Early pottery provenance studies are described, and other research programmes, involving obsidian and magmatic mixing, the origin of the stone used for the Colossi of Memnon, and the ,Plate of Brass', are mentioned. Research work by the Laboratory included the discovery of the world-wide iridium anomaly and extensive subsequent research on what has come to be known as the ,Asteroid Impact Theory'. Characteristics of the analytical programme for pottery provenance work, including overall aims, precision and accuracy, intercalibration, and irradiation and measurement protocols, are discussed. New research areas developed in the past 15 years, to broaden the usefulness of chemical compositional data for archaeological investigation, and examples of recent work, are described. This research, which makes use of high-precision X-ray fluorescence analysis in addition to INAA measurements on sample splits, includes distinguishing the products of different workshops located at the same production site, studies on the significance of the distribution of silver in archaeological pottery and the use of high-precision chemical compositional data as an aid for making chronological distinctions. [source] Accounting for velocity anisotropy in seismic traveltime tomography: a case study from the investigation of the foundations of a Byzantine monumental buildingGEOPHYSICAL PROSPECTING, Issue 1 2006L. Polymenakos ABSTRACT We estimate velocity anisotropy factors from seismic traveltime tomographic data and apply a correction for anisotropy in the inversion procedure to test possible improvements on the traveltime fit and the quality of the resulting tomographic images. We applied the anisotropy correction on a traveltime data set obtained from the investigation of the foundation structure of a monumental building: a Byzantine church from the 11th century AD, in Athens, Greece. Vertical transverse isotropy is represented by one axis of symmetry and one anisotropy magnitude for the entire tomographic inversion grid. We choose the vertical direction for the symmetry axis by analysing the available data set and taking into account information on the character of the foundations of the church from the literature and past excavations. The anisotropy magnitude is determined by testing a series of values of anisotropy and examining their effect on the tomographic inversion results. The best traveltime fit and image quality are obtained with an anisotropy value (Vmax/Vmin) of 1.6, restricted to the high velocity structures in the subsurface. We believe that this anisotropy value, which is significantly higher than the usual values reported for near-surface geological material, is related to the fabric of the church foundations, due to the shape of the individual stone blocks and the layout of the stonework. Inversion results obtained with the correction for anisotropy indicate that both the traveltime fit and the image quality are improved, providing an enhanced reconstruction of the velocity field, especially for the high-velocity features. Based on this enhanced and more reliable reconstruction of velocity distribution, an improved image of the subsurface material character was made possible. In particular, the pattern and state of the church foundations and possible weak ground material areas were revealed more clearly. This improved subsurface knowledge may assist in a better design of restoration measures for monumental buildings such as Byzantine churches. [source] Numerical modelling of complex resistivity effects on a homogenous half-space at low frequenciesGEOPHYSICAL PROSPECTING, Issue 3 2006T. Ingeman-Nielsen ABSTRACT The many different existing models describing the spectral behaviour of the resistivity of geological materials at low frequency, combined with the lack of available field data, render the interpretation of complex resistivity (CR) data very difficult. With a recent interest in CR-measurements for environmental applications and thanks to technological progress, the use of wide-band frequency equipment seems promising, and it is expected to shed light on the different results among the published solutions to the electromagnetic (EM) coupling problem. We review the theory of EM-coupling over a homogeneous half-space with CR-effects and study some aspects of the complex coupling function. We advocate the use of the CR-based coupling function in the interpretation process, in order to obtain a better understanding of the physical processes involved in CR-effects. Application of the model to real field data shows systematic good agreement in two simple cases, even over wide ranges of frequencies. Interpretation with a double Cole,Cole model is applied for comparison, and in spite of good fits to the data, large differences are observed in the interpreted low-frequency dispersion. We conclude that the use of a second Cole,Cole model to describe EM-coupling may corrupt the interpretation of the low-frequency dispersion, even when only the normal range of frequencies (<100 Hz) is considered, and that the use of the actual EM-coupling expression is essential when the goal is a better understanding of interaction between CR-effects and EM-coupling. [source] Preparation of a Synthetic Titanite Glass Calibration Material for In Situ Microanalysis by Direct Fusion in Graphite Electrodes: A Preliminary Characterisation by EPMA and LA-ICP-MSGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 2 2005Magne Ødegård matériaux de calibration; microanalyse; fusion directe; électrodes de graphite; verre de titanite This paper describes a technique for the preparation of a titanite (CaTiSiO5) glass calibration material for use in in situ microanalysis of major, minor, and trace elements in geological materials. The starting composition was a titanite matrix doped with minor and trace elements at , 200 ,g g -1. The elements Sc, Y, REEs, Th and U were added in the form of nitrates in solution, and the elements V, Cr, Mn, Fe, Co, Ni, Zr, Nb, Hf and W were added as solid oxides. The synthetic titanite glass was produced by direct fusion by resistance heating in graphite electrodes at 1600-1700 °C, and quenched in air. Backscattered electron images indicate good homogeneity, with no signs of separate phases or vesicles, and analysis of the major elements Ca, Ti and Si by electron microprobe showed relative standard deviations between 0.5 and 0.7%, based on six independent measurements. Deviations from nominal concentrations for Ca, Si and Ti were measured to -1.2, -3.3 and -0.8%, respectively. The homogeneity of the trace elements in the glass was assessed by LA-ICP-MS analyses, using NIST SRM 610, 612 and 616 as external calibrators, and Ca as the internal standard element. Determinations were made both with a quadrupole mass spectrometer and a sector field instrument, and both raster and spot modes of analysis were used. For the majority of doped elements, precision was better than 10%, and relative deviations from nominal values were, with few exceptions, between 5 and 10%. Cet article décrit une technique de préparation d'un verre de composition CaTiSiO5 (titanite) pour l'utiliser comme matériau de calibration lors de microanalyses in situ des éléments majeurs, mineurs et en trace dans des matériaux géologiques. La composition de départ a une matrice de titanite, dopée avec des éléments mineurs et en trace à une concentration de , 200 ,g g-1. Les éléments Sc, Y, REE, Th et U ont été ajoutés sous forme de nitrates en solution et les éléments V, Cr, Mn, Fe, Co, Ni, Zr, Nb, Hf et W sous forme d'oxydes solides. Le verre synthétique de titanite a été produit par fusion directe avec un chauffage par des résistances dans des électrodes de graphite à 1600-1700 °C suivi d'un refroidissement rapide à l'air. Les images obtenues par électrons rétrodiffusés montrent que le verre présente une bonne homogénéité, sans aucun signe de phases individualisées ou de vésicules, et l'analyse des éléments majeurs Ca, Ti et Si par microsonde électronique a des déviations standard relatives (RSD) entre 0.5 et 0.7% provenant de six mesures indépendantes. Les déviations par rapport aux concentrations calculées, pour Ca, Si et Ti, sont de -1.2, -3.3 et -0.8% respectivement. L'homogénéité de répartition des éléments en trace dans le verre a été vérifiée par des analyses LA-ICP-MS, en utilisant les matériaux de référence NIST SRM 610, 612 et 616 pour la calibration externe et Ca comme élément standard interne. Les déterminations ont été faites avec un spectromètre de masse de type quadrupôle et un autre de type secteur magnétique, par des analyses à la fois en mode balayage et en mode ponctuel. Pour la majorité des éléments dopés, la précision est meilleure que 10% et les déviations standard relatives par rapport aux valeurs calculées sont, à quelques exceptions près, entre 5 et 10%. [source] | ||||||||||