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Gap Width (gap + width)
Selected AbstractsDFT calculations on the electronic structures of BiOX (X = F, Cl, Br, I) photocatalysts with and without semicore Bi 5d statesJOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 2 2009Wen Lai Huang Abstract The electronic structures of BiOX (X = F, Cl, Br, I) photocatalysts have been calculated with and without Bi 5d states using the experimental lattice parameters, via the plane-wave pseudopotential method based on density functional theory (DFT). BiOF exhibits a direct band gap of 3.22 or 3.12 eV corresponding to the adoption of Bi 5d states or not. The indirect band gaps of BiOCl, BiOBr, and BiOI are 2.80, 2.36, and 1.75 eV, respectively, if calculated with Bi 5d states, whereas the absence of Bi 5d states reduces them to 2.59, 2.13, and 1.53 eV successively. The calculated gap characteristics and the falling trend of gap width with the increasing X atomic number agree with the experimental results, despite the common DFT underestimation of gap values. The shapes of valence-band tops and conduction-band bottoms are almost independent of the involvement of Bi 5d states. The indirect characteristic becomes more remarkable, and the conduction-band bottom flattens in the sequence of BiOCl, BiOBr, and BiOI. Both O 2p and X np (n = 2, 3, 4, and 5 for X = F, Cl, Br, and I, respectively) states dominate the valence bands, whereas Bi 6p states contribute the most to the conduction bands. With the growing X atomic number, the localized X np states shift closer toward the valence-band tops, and the valence and conduction bandwidths evolve in opposite trends. Atomic and bond populations have also been explored to elucidate the atomic interactions, along with the spatial distribution of orbital density. © 2008 Wiley Periodicals, Inc. J Comput Chem, 2009 [source] Marginal gap formation of composites in dentine: effect of water storageJOURNAL OF ORAL REHABILITATION, Issue 3 2003A. U. J. Yap summary, This study investigated the effects of water storage on the marginal adaptation of two composite resins (Spectrum TPH and Ariston AT), two polyacid-modified composite resins (Dyract AP and F2000) and a new PRG composite (Reactmer) to dentine over time. Two cylindrical dentine cavities (1·5 mm diameter and 1·5 mm deep) were prepared on the horizontally sectioned surfaces of freshly extracted teeth. In each tooth, one cavity was restored using composites with their respective bonding system and the other without the bonding system. The sample size for each material with/without bonding system was 6. The composites were placed in one increment, bulk-polymerized, immediately finished/polished with the Sof-lex discs system and fine polished on 30 ,m silicon carbide/9 ,m aluminium oxide lapping film discs in a microgrinding system. The specimens were then stored in distilled water at 37 °C and the maximum marginal gap width between the material and the dentine wall was determined at 24 h, 1 week, 2 weeks, 3 weeks and 4 weeks using a measurescope at ×500 magnification. Results were subjected to statistical analysis using monva, anova/Scheffe's post hoc test and independent samples of t -test at significance level 0·05. At all time intervals, no significant difference in marginal gap formation was observed between materials. Where bonding systems were not used, a decrease in gap widths over time was observed with most materials but only Dyract AP exhibited a significant decrease. The latter was observed after 2 weeks storage in water. The use of bonding systems reduced dentine marginal gaps significantly and is therefore mandatory for all composites evaluated. Marginal gaps arising from polymerization contraction of conventional, polyacid-modified and PRG composites cannot be fully compensated by hydroscopic expansion. Clinical relevance Bonding systems are mandatory for all composites when bonding to dentin. In the event of a bond failure at placement, hygroscopic expansion of composites can reduce marginal gaps but not completely. [source] Fabrication and measurement of triangular-slot antenna for triple-band (2.4/5.2/5.8 GHz) antenna with rectangular tuning stubMICROWAVE AND OPTICAL TECHNOLOGY LETTERS, Issue 8 2007JoongHan Yoon Abstract In this paper, a novel design of a triangular-slot antenna with rectangular tuning stub for 2.4/5.2/5.8 GHz triple-band applications is presented. The prototype consists of a triangular slot and rectangular tuning stub. Results show that the impedance matching of the proposed antenna is greatly affected by the feed gap width. Experimental results indicate that the impedance bandwidth (VSWR 1:2) of the proposed antenna is about 423 MHz for the 2.4-GHz band and 1.92 GHz for the 5-GHz band. The simulated and experimental results for the return loss, radiation patterns, and gains are presented and discussed. © 2007 Wiley Periodicals, Inc. Microwave Opt Technol Lett 49: 1793,1797, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.22621 [source] A two-dimensional electrodynamical outer gap model for ,-ray pulsars: ,-ray spectrumMONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 4 2006J. Takata ABSTRACT A two-dimensional electrodynamical model is used to study particle acceleration in the outer magnetosphere of a pulsar. The charge depletion from the Goldreich,Julian charge density causes a large electric field along the magnetic field lines. The charge particles are accelerated by the electric field and emit ,-rays via the curvature process. Some of the emitted ,-rays may collide with X-ray photons to make new pairs, which are accelerated again on the different field lines and emit ,-rays. We simulate the pair creation cascade in the meridional plane using the pair creation mean-free path, in which the X-ray photon number density is proportional to the inverse square of the radial distance. With the space charge density determined by the pair creation simulation, we solve the electric structure of the outer gap in the meridional plane and calculate the curvature spectrum. We investigate in detail the relation between the spectrum and total current, which is carried by the particles produced in the gap and/or injected at the boundaries of the gap. We demonstrate that the hardness of the spectrum is strongly controlled by the current carriers. Especially, the spectrum sharply softens if we assume a larger particle injection at the outer boundary of the outer gap. This is because the mean-free path of the pair creation of the inwardly propagating ,-ray photons is much shorter than the light radius, so many pairs are produced in the gap to quench the outer gap. Because the two-dimensional model can link both gap width along the magnetic field line and trans-field thickness with the spectral cut-off energy and flux, we can diagnose both the current through the gap and the inclination angle between the rotational and magnetic axes. We apply the theory to the Vela pulsar. By comparing the results with the Energetic Gamma Ray Experiment Telescope (EGRET) data, we rule out any cases that have a large particle injection at the outer boundary. We also suggest the inclination angle of ,inc, 65°. The present model predicts the outer gap starting from near the conventional null charge surface for the Vela pulsar. [source] Electrospray ionization from a gap with adjustable widthRAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 21 2006Patrik Ek In this paper, we present a new concept for electrospray ionization mass spectrometry, where the sample is applied in a gap which is formed between the edges of two triangular-shaped tips. The size of the spray orifice can be changed by varying the gap width. The tips were fabricated from polyethylene terephthalate film with a thickness of 36,µm. To improve the wetting of the gap and sample confinement, the edges of the tips forming the gap were hydrophilized by means of silicon dioxide deposition. Electrospray was performed with gap widths between 1 and 36,µm and flow rates down to 75,nL/min. The gap width could be adjusted in situ during the mass spectrometry experiments and nozzle clogging could be managed by simply widening the gap. Using angiotensin I as analyte, the signal-to-noise ratio increased as the gap width was decreased, and a shift towards higher charge states was observed. The detection limit for angiotensin I was in the low nM range. Copyright © 2006 John Wiley & Sons, Ltd. [source] Regimes of Multiple Emulsions of W1/O/W2 and O1/W/O2 Type in the Continuous Couette-Taylor Flow ContactorCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 1 2010E. Dluska Abstract The flow regimes of multiple emulsions in the continuous Couette-Taylor flow (CTF) contactor and characterization of the dispersion state are reported. The proposed method of multiple emulsion preparation is a one-step procedure on the contrary to the classical two-step procedure. The effect of operating parameters in the CTF contactor on multiple emulsion appearance, structure (drop size and packing), and rheological behavior is discussed. The key factors affecting multiple emulsion preparation in the CTF apparatus were the phases ratio, the rotational flow, and an annular gap width. The influence of an axial flow was more significant in the range of small rotational rates. The operating conditions were optimized to find the best characteristic multiple emulsions (largest interfacial area). The paper presents the same exemplary data of using W1/O/W2 emulsions as emulsion liquid membranes (ELMs) in the extraction process and O1/W/O2 for control active agent (drug) release. [source] Marginal gap formation of composites in dentine: effect of water storageJOURNAL OF ORAL REHABILITATION, Issue 3 2003A. U. J. Yap summary, This study investigated the effects of water storage on the marginal adaptation of two composite resins (Spectrum TPH and Ariston AT), two polyacid-modified composite resins (Dyract AP and F2000) and a new PRG composite (Reactmer) to dentine over time. Two cylindrical dentine cavities (1·5 mm diameter and 1·5 mm deep) were prepared on the horizontally sectioned surfaces of freshly extracted teeth. In each tooth, one cavity was restored using composites with their respective bonding system and the other without the bonding system. The sample size for each material with/without bonding system was 6. The composites were placed in one increment, bulk-polymerized, immediately finished/polished with the Sof-lex discs system and fine polished on 30 ,m silicon carbide/9 ,m aluminium oxide lapping film discs in a microgrinding system. The specimens were then stored in distilled water at 37 °C and the maximum marginal gap width between the material and the dentine wall was determined at 24 h, 1 week, 2 weeks, 3 weeks and 4 weeks using a measurescope at ×500 magnification. Results were subjected to statistical analysis using monva, anova/Scheffe's post hoc test and independent samples of t -test at significance level 0·05. At all time intervals, no significant difference in marginal gap formation was observed between materials. Where bonding systems were not used, a decrease in gap widths over time was observed with most materials but only Dyract AP exhibited a significant decrease. The latter was observed after 2 weeks storage in water. The use of bonding systems reduced dentine marginal gaps significantly and is therefore mandatory for all composites evaluated. Marginal gaps arising from polymerization contraction of conventional, polyacid-modified and PRG composites cannot be fully compensated by hydroscopic expansion. Clinical relevance Bonding systems are mandatory for all composites when bonding to dentin. In the event of a bond failure at placement, hygroscopic expansion of composites can reduce marginal gaps but not completely. [source] Electrospray ionization from a gap with adjustable widthRAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 21 2006Patrik Ek In this paper, we present a new concept for electrospray ionization mass spectrometry, where the sample is applied in a gap which is formed between the edges of two triangular-shaped tips. The size of the spray orifice can be changed by varying the gap width. The tips were fabricated from polyethylene terephthalate film with a thickness of 36,µm. To improve the wetting of the gap and sample confinement, the edges of the tips forming the gap were hydrophilized by means of silicon dioxide deposition. Electrospray was performed with gap widths between 1 and 36,µm and flow rates down to 75,nL/min. The gap width could be adjusted in situ during the mass spectrometry experiments and nozzle clogging could be managed by simply widening the gap. Using angiotensin I as analyte, the signal-to-noise ratio increased as the gap width was decreased, and a shift towards higher charge states was observed. The detection limit for angiotensin I was in the low nM range. Copyright © 2006 John Wiley & Sons, Ltd. [source] A Passive Magnetically and Hydrodynamically Suspended Rotary Blood PumpARTIFICIAL ORGANS, Issue 3 2009Martin Stoiber Abstract A combined hydrodynamic,magnetic bearing allows the design of rotary blood pumps that are not encumbered with mechanical bearings and magnets requiring sensors or electrical power. However, such pumps have so far needed very small and accurately manufactured gaps between rotor and housing to assure effective hydromagnetic bearing behavior. In order to use this concept in disposable pump heads, a design that allows larger rotor-housing gaps, and thus larger manufacturing tolerances, is needed. A pump with passive magnetic bearings and a gap between rotor and housing in the range of 0.5 mm was designed. Numerical simulations were performed to optimize the rotor geometry at low levels of shear stress. An experimental test stand was used to find a range of speeds and gap settings that resulted in low levels of vibration and useful pressure,flow relationships. Three different rotor geometries were tested using a viscosity-adjusted test fluid. Blood damage tests were conducted within the desirable range of speeds and gap settings. In this study stable pump performance was demonstrated at total gap widths between 0.3 and 0.7 mm at flows of 0,10 L/min, with afterloads up to 230 mm Hg. Best performance was achieved with rotors sliding on a fluid pillow between the rotor and the outer housing at a gap distance of 50 to 250 µm. The inner gap distance, between the rotor and the inner housing, could be as great as 500 µm. Hemolysis tests on the prototype within the chosen operating range showed lower values (NIH = 0.0029 ± 0.0012 g/100 L) than the Biomedicus BP-80 pump (NIH = 0.0033 ± 0.0011 g/100 L). In conclusion, it is possible to build rotary blood pumps with passive hydromagnetic bearings that have large gaps between their rotors and housings. Rotor behavior is sensitive to the position of the permanent magnetic drive unit. To minimize vibration and blood damage, the fluid gaps and the rotational speed have to be adjusted according to the desired operating point of the pump. Further study is needed to optimize the magnetic drive unit and to ascertain its ability to withstand inertial loads imposed by sudden movements and external shock. [source] | |||||||||||||