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Allylic Amines (allylic + amine)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

Catalyst-Controlled Wacker-Type Oxidation of Protected Allylic Amines,

ANGEWANDTE CHEMIE, Issue 40 2010
Brian W. Michel
Ganz im Gegenteil: Mit dem Katalysatorsystem [Pd(Quinox)],TBHP konnten geschützte Allylamine mit hohen Selektivitäten zugunsten des Methylketonprodukts oxidiert werden. Die Reaktion ist katalysatorkontrolliert, und die Selektivität ist darum umgekehrt zur substratkontrollierten Tsuji-Wacker-Oxidation (siehe Schema). Verschiedenste N-Schutzgruppen wurden hoch selektiv zu den Ketonen oxidiert. TBHP=tert -Butylhydroperoxid. [source]

Asymmetric Allylboration of ,,,-Enals as a Surrogate for the Enantioselective Synthesis of Allylic Amines and ,-Amino Acids.

CHEMINFORM, Issue 33 2005
P. Veeraraghavan Ramachandran
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Reductive Alkylation of ,-Alkoxy Aziridines: New Route to Substituted Allylic Amines.

CHEMINFORM, Issue 16 2005
Clare M. Rosser
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Asymmetric Catalytic Coupling of Organoboranes, Alkynes, and Imines with a Removable (Trialkylsilyloxy)ethyl Group , Direct Access to Enantiomerically Pure Primary Allylic Amines.

CHEMINFORM, Issue 46 2004
Sejal J. Patel
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Allylic Amination of Unfunctionalyzed Olefins by Nitroarenes and CO, Catalyzed by Ru3(CO)12/Ph-BIAN (Ph-BIAN = Bis(phenylimino)acenaphthenequinone): Extension to the Synthesis of Allylic Amines with Strongly Electron-Withdrawing or Electron-Donating Groups on the Aryl Ring.

CHEMINFORM, Issue 38 2004
Fabio Ragaini
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

A Phosphorimidate Rearrangement for the Facile and Selective Preparation of Allylic Amines.

CHEMINFORM, Issue 36 2004
Bin Chen
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

ChemInform Abstract: Synthesis of N-Protected Allylic Amines from Allyl Ethers.

CHEMINFORM, Issue 19 2002
Ji Duck Kim
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

ChemInform Abstract: Stereoselective Syntheses of Allylic Amines Through Reduction of 1-Azadiene Intermediates.

CHEMINFORM, Issue 7 2001
Enrique Aguilar
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Efficient palladium,ferrocenylphosphine catalytic systems for allylic amination of monoterpene derivatives

APPLIED ORGANOMETALLIC CHEMISTRY, Issue 12 2006
Duc Hanh Nguyen
Abstract Ferrocenylphosphines added to [Pd(µ-Cl)(,3 -C3H5)]2 dimeric precursor produce efficient catalysts to effect the allylic amination of terpenic allylacetates. Particularly convenient are tetrakis(diphenylphosphino)ferrocene and 1,1,-bis(diphenylphosphino)ferrocene, which allow the amination of allylacetates with good to excellent selectivity, and have turnover numbers as high as 80 000, for instance, for the formation of allylaniline. Herein, we report on reactions that selectively transform geranylacetate, nerylacetate, linalylacetate and perillylacetate into the corresponding allylic amines. These preparative methods give facile access to various products of great potential industrial interest. Copyright © 2006 John Wiley & Sons, Ltd. [source]