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Extrusion Process (extrusion + process)
Kinds of Extrusion Process Selected AbstractsA NEW APPROACH TO MODELING AND CONTROL OF A FOOD EXTRUSION PROCESS USING ARTIFICIAL NEURAL NETWORK AND AN EXPERT SYSTEMJOURNAL OF FOOD PROCESS ENGINEERING, Issue 1 2001OTILIA POPESCU ABSTRACT The paper presents a new approach to the modeling of the start-up part of a food extrusion process. A neural network model is proposed and its parameters are determined. Simulation results with real data are also presented. The inputs and outputs of the model are among those used by the human operator during the start-up process for control. An intelligent controller structure that uses an expert system and "delta-variations" to modify inputs is also proposed. [source] Study of Polyurethane Formulations Containing Diols Obtained via Glycolysis of Poly(ethylene terephthalate) (PET) by Oligoesters Diols through a Reactive Extrusion ProcessMACROMOLECULAR MATERIALS & ENGINEERING, Issue 7 2005Gaël Colomines Abstract Summary: The glycolysis of PET by oligoester diols in the presence of zinc acetate was carried out in two successive twin-screw extruders with total residence times of 4 min and without solvent. These new glycolysates were analyzed and used in polyurethane formulation with a commercial polyol. The reactivity of these formulations was studied. The mechanical properties, thermal and swelling behavior of these polyurethanes were investigated. Mechanical properties are improved with the addition of glycolysate. The thermal behavior is not modified with the addition of glycolysate. The swelling behavior of the material depends on the solvent nature. The addition of glycolysate allows a decrease in material swelling in chloroform but increases this swelling in acetone. [source] Finite-element analysis of a combined fine-blanking and extrusion processINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 3 2006P. F. Zheng Abstract This paper presents the characteristics of the combined fine-blanking and extrusion process and gives a detailed analysis of the process with the finite-element method. To carry out the simulation step by step and avoid the tendency to diverge in the calculations, the remeshing, tracing and golden section methods were developed and introduced into the finite-element program. Different boundary conditions were used in the simulation; the mesh distortion, field of material flow, and the stress and strain distributions were obtained. From the simulated results, the deformation characteristics under different boundary conditions were revealed. An experiment was also carried out to verify the simulated results. A large strain analysis technique was chosen to determine the effective strain distribution based on the experiment. The effective strain distributions from the simulation are in accordance with the effective strain distributions and the hardness distributions from the experiment. Copyright © 2005 John Wiley & Sons, Ltd. [source] Macroscopic Fibers of Oriented Vanadium Oxide Ribbons and Their Application as Highly Sensitive Alcohol Microsensors,ADVANCED MATERIALS, Issue 24 2005L. Biette Vanadium oxide macroscopic fibers (see Figure) are obtained by an extrusion process. The fibers consist of nanoscopic ribbons with a preferential orientation and a longitudinal Young's modulus of around 15,GPa. As well as showing high sensitivity, the fibers reversibly cycle between insulating and semiconducting upon exposure to alcohol vapor sources, with signature responses to different alcohols. [source] Changes in the biochemical and functional properties of the extruded hard-to-cook cowpea (Vigna unguiculata L. Walp)INTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 4 2010Karla A. Batista Summary Changes in the biochemical and functional properties of the hard-to-cook cowpea bean after treatment by the extrusion process are reported. The extrusion was carried out at 150 °C, with a compression ratio screw of 3:1, a 5-mm die, and a screw speed of 150 r.p.m. The extrusion caused the complete inactivation of the ,-amylase and lectin and it also reduced the trypsin inhibitor activity (38.2%) and phytic acid content (33.2%). The functional properties were also modified by the process, an increase of 2.5 times in the water absorption index and 3.1% in the water solubility were observed. The digestibility of the hard-to-cook flour of the cowpea bean was improved after the extrusion, with a 55.9% increase in protein digestibility and a 5.9% increase in starch digestibility. [source] Effect of extrusion parameters on flavour retention, functional and physical properties of mixtures of starch and d -limonene encapsulated in milk proteinINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 2006Sri Yuliani Summary The purpose of this research was to investigate the retention of flavour volatiles encapsulated in water-insoluble systems during high temperature,short time extrusion process. A protein precipitation method was used to produce water-insoluble capsules encapsulating limonene, and the capsules were added to the extruder feed material (cornstarch). A twin-screw extruder was used to evaluate the effect of capsule level of addition (0,5%), barrel temperature (125,145 °C) and screw speed (145,175 r.p.m.) on extruder parameters (torque, die pressure, specific mechanical energy, residence time distribution) and extrudate properties [flavour retention, texture, colour, density, expansion, water absorption index, water solubility index (WSI)]. Capsule level had a significant effect on extrusion conditions, flavour retention and extrudate physical properties. Flavour retention increased with the increase in capsule level from 0% to 2.5%, reached a maximum value at capsule level of 2.5% and decreased when the capsule level increased from 2.5% to 5%. The die pressure, torque, expansion ratio, hardness and WSI exhibited the opposite effect with the presence of capsules. [source] The optimization of the extrusion process when using maize flour with a modified amino acid profile for making tortillasINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 7 2006Jorge Milán-Carrillo Summary Maize with a modified amino acid profile, i.e. greater amounts of lysine and tryptophan than normal, is known as ,quality protein maize' (QPM). The objective of this work was to find the best combination of extrusion process variables to produce QPM flour for making tortillas. QPM grits were mixed with lime and water and had a moisture content of 28%. The single screw extruder operation conditions were selected from factorial combination of three process variables: extrusion temperature (ET, 70,100 °C), lime concentration (LC, 0.1,0.3% of the maize weight) and screw velocity (SV, 80,250 rpm). Response surface methodology was used as an optimization technique. In vitro protein digestibility (PD); total colour difference (,E) of the flours, and tortilla puffing (TP) were chosen as response variables. A graphical method was used to obtain maximum PD, TP and minimum ,E. The optimum combination of process variables was: ET = 85 °C/LC = 0.21%(w/w)/SV = 240 rpm. Tortillas from QPM flour had similar chemical composition, physicochemical and sensory properties to tortillas from commercial nixtamalized maize flour; however, the former had the highest (P , 0.05) available lysine content and were therefore better nutritionally. [source] Flavour retention during high temperature short time extrusion cooking process: a reviewINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 5 2001Bhesh Bhandari Research on the stability of flavours during high temperature extrusion cooking is reviewed. The important factors that affect flavour and aroma retention during the process of extrusion are illustrated. A substantial number of flavour volatiles which are incorporated prior to extrusion are normally lost during expansion, this is because of steam distillation. Therefore, a general practice has been to introduce a flavour mix after the extrusion process. This extra operation requires a binding agent (normally oil), and may also result in a non-uniform distribution of the flavour and low oxidative stability of the flavours exposed on the surface. Therefore, the importance of encapsulated flavours, particularly the ,-cyclodextrin-flavour complex, is highlighted in this paper. [source] On the high-density polyethylene extrusion: Numerical, analytical and experimental modelingADVANCES IN POLYMER TECHNOLOGY, Issue 3 2010A. G. Mamalis Abstract A three-dimensional numerical model was developed to investigate the nonisothermal, non-Newtonian polymer flow through a cone cylindrical die used in the HDPE (high-density polyethylene) extrusion process. The numerical model was based on the computational fluid dynamics code COMSOL 3.4 the finite element method, and it was used to calculate pressure, flow, and temperature distributions in a cone cylindrical die used for industrial-scale extrusion of an HDPE rod. The model also accounted for viscous heating. In addition, pressure and temperature data were derived using an analytical solution. The numerical approach agrees fairly well with the experimental data recorded during the extrusion process of the material. © 2010 Wiley Periodicals, Inc. Adv Polym Techn 29:173,184, 2010; View this article online at wileyonlinelibrary. DOI 10.1002/adv.20185 [source] Paste extrusion control and its influence on pore size properties of PTFE membranesADVANCES IN POLYMER TECHNOLOGY, Issue 3 2007Radium Huang Abstract Polytetrafluoroethylene (PTFE) is a remarkable membrane material. Owing to its high-melting point, PTFE fine powder cannot be processed using conventional melting processing methods. Instead, techniques such as paste extrusion, rolling, and sintering have to be employed. Each processing step has an important influence on the final pore size quality within the membrane. In this paper, a PID controller (proportional-integral-derivative controller) was used to improve the properties of PTFE paste during the extrusion process and the quality of the PTFE membrane. A range of lubricant content (18, 20, and 22 wt%) was used to monitor the pressure drop at different extrusion speeds (0.5, 1, and 2 mm/s) and reduction ratios (RR = 26.47, 47.06, 80.06). It was found that a higher lubricant content and a higher reduction ratio resulted in a lower pressure drop. It was also found that a higher stretching temperature tends to result in larger pore size and broader pore size distribution at the same stretching rate. At a monitored and controlled constant low-extrusion speed, the porosity of PTFE membrane was increased from 38% to 55% and the mean pore size was decreased from 0.22 to 0.15 ,m because of less migration and more uniform distribution of lubricant during extrusion. Properties and the associated property uniformity of the PTFE extrudate affect the subsequent membrane-forming process and the final pore size and size distribution significantly. © 2008 Wiley Periodicals, Inc. Adv Polym Techn 26:163,172, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20099 [source] Influence of the length of the plasticating system on selected characteristics of an autothermal extrusion processADVANCES IN POLYMER TECHNOLOGY, Issue 1 2005Janusz W. Sikora Abstract The presented paper aims to determine the influence of the length of the plasticating system on the course of an autothermal extrusion process. Three special screws were used, of the relationship of the length of the operating part to diameter of the screw L/D = 20, 25, and 30, with a tip for intensive shearing and mixing, assigned for polyethylene processing, and five screw rotation frequencies were applied. The conducted research consisted of the measurement, during the extrusion, of the factors studied directly and in the calculation, and on their basis, the values characterizing this process. It is stated that the change of the length of the plasticating system in a significant way influences the dependences determining polymer flow rate, temperature and pressure of the processed polymer, extrusion velocity, specific energy consumption, and energy efficiency of the extruder; that is, the whole characteristic of an autothermal extrusion process. © 2005 Wiley Periodicals, Inc. Adv Polym Techn 24:21,28, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/.adv20021 [source] Influence of melt drawing on the morphology of one- and two-step processed LDPE/thermoplastic starch blendsADVANCES IN POLYMER TECHNOLOGY, Issue 4 2003F. J. Rodriguez-Gonzalez Abstract In this study the morphology of LDPE/TPS blends prepared by a one-step extrusion process is compared to that obtained by reprocessing of the original blends. The influence of composition and melt drawing is examined. A novel methodology based on the form factor of the dispersed particle was used to estimate the equivalent spherical particle size of dispersed thermoplastic starch (TPS). This approach allows for the quantitative comparison of average dispersed phase particles regardless of their shape. Blends prepared in the one-step extrusion process show increased levels of anisotropy as a consequence of a combination of coalescence and particle deformation during melt drawing. Reprocessed materials demonstrate morphologies that are highly stable to a wide range of hot stretch ratio conditions. The TPS particles of reprocessed blends show no coalescence and a low degree of deformation. This phenomenon is explained by plasticizer evaporation resulting from the second processing step. The TPS is transformed from a highly deformable phase to one resembling a partially cross-linked material. These data indicate that the one-step processing of LDPE/TPS blends can be used to generate a wide range of highly elongated morphological structures. A two-step approach, analogous to typical compounding and shaping operations and involving controlled glycerol removal in the second step can be used to prepare a wide range of highly stable, more isotropic, dispersed particle morphologies. © 2003 Wiley Periodicals, Inc. Adv Polym Techn 22: 297,305, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.10057 [source] Amorphous orientation and its relationship to processing stages of blended polypropylene/polyethylene fibersJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2008Amy M. Trottier Abstract Changes in the molecular orientation, melting behavior, and percent crystallinity of the individual components in a fibrous blend of isotactic polypropylene (iPP) and high-density polyethylene (HDPE) that occur during the melt extrusion process were examined using wide-angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC). The crystalline orientation of each component was found using Wilchinsky's treatment of uniaxial orientation and described by the Hermans,Stein orientation parameter. The amorphous orientation was found by resolving the X-ray diffraction pattern in steps of the azimuthal angle into its iPP and HDPE crystalline and amorphous reflections. The utility of DSC and WAXD analyses to capture the effects of small differences in processing, and the use of these results as fingerprints of a particular manufacturing process were demonstrated. Major increases in the melting temperatures, percent crystallinities, and molecular orientations of the iPP and HDPE components occurred during the main stretching stage of the melt extrusion process. The annealing stage was found to have little to no effect on the melting behavior and molecular orientation of these components. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Modeling of coat-hanger die under vibrational extrusionJOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2008Jin-Ping Qu Abstract The distributions of the pulsatile pressure field, the pulsatile velocity field, and the pulsatile resident time of the polymeric melt in the coat-hanger die are derived by using the pulsation of volumetric flow rate and pressure. Subsequently, formulae of the manifold radius and the slope of the manifold are deduced via volumetric flow rate pulsation. Polypropylene (PP) was employed for the experiments of the vibrational extrusion. The results indicate that the average extrusion pressure declines with frequency or amplitude decreasing; the distribution of residence time along the width of the coat-hanger die performs uniformly during the vibrational extrusion process; the theoretical extrusion pressure well agrees with the experimental pressure; the experiments of tensile test, impact test implicate that vibration improves the mechanical properties of products; differential scanning calorimetry testing demonstrates that the melting point of PP is moved to a higher temperature value, and the endothermic enthalpy and the crystallinity are improved as well when superimposing the vibrational force field. Accordingly, the model of the coat-hanger die under vibrational extrusion is well consistent with the experiments. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Dispersion of graphite nanosheets in polymer resins via masterbatch techniqueJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2007Guohua Chen Abstract The dispersion of graphite nanosheets (GNs) in polymer matrices via the masterbatch technique was investigated. Modifying resin was added to GNs to prepare blend which is designated as the masterbatch. Such masterbatches, containing 70,80 wt % of GN filler, were blended with target polymers via melt extrusion process to prepare polymer/GN nanocomposites. The extruded nanocomposites showed characteristic conducting percolation behaviors with the percolation thresholds mainly dependent on the miscibility of the modifying resin with polymer matrix. The percolation thresholds of AS (Acrylonitrile-Styrene compolymer)/GN and high-density polyethylene (HDPE)/GN nanocomposites prepared by this technique were about 9 and 14 wt % of GN, respectively. Scanning electron microscopy and other characterizations showed that the GNs were well dispersed in AS and HDPE resins. The extrusion process and compatibility of the modifying resin with target polymer proved to be important factors for the homogeneity of the nanodispersion. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3470,3475, 2007 [source] A NEW APPROACH TO MODELING AND CONTROL OF A FOOD EXTRUSION PROCESS USING ARTIFICIAL NEURAL NETWORK AND AN EXPERT SYSTEMJOURNAL OF FOOD PROCESS ENGINEERING, Issue 1 2001OTILIA POPESCU ABSTRACT The paper presents a new approach to the modeling of the start-up part of a food extrusion process. A neural network model is proposed and its parameters are determined. Simulation results with real data are also presented. The inputs and outputs of the model are among those used by the human operator during the start-up process for control. An intelligent controller structure that uses an expert system and "delta-variations" to modify inputs is also proposed. [source] NEW GENERATION OF HEALTHY SNACK FOOD BY SUPERCRITICAL FLUID EXTRUSIONJOURNAL OF FOOD PROCESSING AND PRESERVATION, Issue 2 2010K.Y. CHO ABSTRACT A supercritical fluid extrusion (SCFX) process has been successfully developed for the production of a novel healthy snack containing 40,60 wt% protein with unique porous structure and texture. Supercritical carbon dioxide (SC-CO2) injection rate and product temperature at the die were found to be critical to control the expansion and texture of the final product. Maximum cross-sectional expansion was obtained at 0.3 wt% added SC-CO2, whereas more uniform internal structure was achieved at 0.7 wt% SC-CO2 level. As whey protein concentrate (80 wt%) concentration was increased from 52.8 to 78.2 wt% in the formulation, the cross-sectional expansion of baked and fried products increased by 65.8 and 44.4%, respectively. It was observed that lower viscosity of whey protein compared with starch decreased expansion but helped enhance further expansion during post-extrusion drying. The finding showed that an extrusion process at the temperature below protein denaturation temperature using SC-CO2 can help to prevent hard texture due to the thermosetting property of whey protein and to create a uniformly expanded structure. The textural properties of SCFX chips were comparable to commercial extruded or fried chip products. PRACTICAL APPLICATIONS The American snack market is one of fast-growing markets in the world as snacking becomes more popular. Because of the increasing concerns about health, there is also an increasing demand for new healthy snacks as an alternative for fried starch-based snacks with low nutrient density. This study shows the potential of supercritical fluid extrusion (SCFX) technology for healthy snack food production containing whey protein. SCFX chips had uniform cellular microstructure that cannot be obtained using conventional steam-based extrusion. As supercritical carbon dioxide can deliver certain flavors, an expanded snack not only with high nutrient density and unique texture but also with encapsulated flavors can be produced using the SCFX process and can be marketed as a novel healthy snack. [source] Modeling Thermal and Mechanical Effects on Retention of Thiamin in Extruded FoodsJOURNAL OF FOOD SCIENCE, Issue 8 2003J.Y. Cha ABSTRACT: A model was proposed to predict separate thermal and mechanical effects of extrusion cooking on thiamin retention. Thermal effects were determined by heating small samples of wheat flour mixed with 0.30% (wt/ wt) thiamin hydrochloride isothermally at 140 °C, 151 °C, and 161 °C for different times. The calculated activation energy and rate constants at each temperature were 67.28 kJ/g mol and 0.00869/min, 0.0145/min, and 0.0224/min, respectively. The "extruder constant" was estimated as 27.7/rev, based on a matching-viscosity method. Wheat flour with 0.30% (wt/wt) thiamin was extruded at different screw speeds. Mechanical effects caused 89.7% to 94.4% of total thiamin loss. This research provides a generalized method to "fingerprint" the extrusion process. [source] Dephytinisation of rice bran and manufacturing a new food ingredientJOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 15 2001Wea-Shang Fuh Abstract Rice bran was extruded at 130,°C and a screw speed of 140,rpm for 20,s to inactivate lipase and prevent lipid oxidation. Although the extrusion process induced further complex formation between phytic acid and protein as well as between phytic acid and starch, nearly 94% of phytic acid in the extruded rice bran could still be removed by solid/liquid extraction conducted at 25,°C for 30,min using hydrochloric acid at pH 2 as solvent and a solvent/rice bran ratio of 15. After the extract had been neutralised and phytic acid removed, it was added back to the rice bran solid to replenish the nutritional and functional components of the solid. The mixture was then dried in a drum dryer to yield a powdered product. The dephytinised rice bran product contained most of the protein, fat, dietary fibre and B vitamins and more than 50% of the oryzanol originally present in the raw rice bran. © 2001 Society of Chemical Industry [source] Physico-Mechanical Properties, Odor and VOC Emission of Bio-Flour-Filled Poly(propylene) Bio-Composites with Different Volcanic Pozzolan ContentsMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10 2006Hee-Soo Kim Abstract Summary: This study investigated the physico-mechanical properties, odor and VOC emission of bio-flour filled PP bio-composites with different pozzolan contents. On increasing the pozzolan content, the tensile and flexural strengths of the bio-composites were not significantly changed, whereas the impact strength and water absorption increased slightly and the odor intensity decreased due to the absorption of thermal degradation gases of PP and bio-flour at the pore surface of the pozzolan. The VOC emission of the bio-composites, analyzed by GC-MSD, was mainly due to PP oxidation and the thermal degradation of bio-flour during the extrusion process at high manufacturing temperatures. With increased pozzolan content, other organic compounds of the bio-composites were not significantly changed, but the toluene emission of the bio-composites was decreased. SEM and SEM/EDX mapping techniques were employed to investigate the porous form and the pozzolan distribution in the bio-composites. From these results, we concluded that the addition of pozzolan in the bio-composites was an effective method for reducing their odor and VOC emission without any reduction in mechanical properties. SEM micrograph of pozzolan (10,000×). [source] Morphology and Crystalline Structure of Poly(, -Caprolactone) Nanofiber via Porous Aluminium Oxide TemplateMACROMOLECULAR MATERIALS & ENGINEERING, Issue 9 2006Yang Chen Abstract Summary: Poly(, -caprolactone) (PCL) nanofibers with a dimension of about 150 nm were successfully fabricated by using a process of extruding PCL solution via a porous aluminium oxide template and then solidifying in methanol. The morphology, melting behavior and crystalline structure of the nanofibers were investigated by using scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The results revealed that the weight-average molecular weight () of PCL hardly influenced the morphology of the nanofibers. However, the melting temperature (Tm) of the PCL crystalline increased slightly from 55.4 to 57.5,°C with an increase in . The accessional pressure and the presence of the porous template played an important role in the improvement of the orientation and crystallization structures of the polymer chains when they were passing through the nano-scale porous channel, leading to the conglomeration of the fiber and the much larger diameter than those from the pressure-induced extrusion process. Furthermore, comparing the processes with and without accessional pressure, the crystallinity of the nanofibers obtained under 0.2 MPa pressure increased, and the diffraction for the (001) lattice plane occurred. SEM image of PCL nanofibers extruded via a porous aluminium oxide template with the aid of pressure. [source] A Solvent Free Graft Copolymerization of Maleic Anhydride onto Cellulose Acetate Butyrate Bioplastic by Reactive ExtrusionMACROMOLECULAR MATERIALS & ENGINEERING, Issue 1 2006Arief C. Wibowo Abstract Summary: Interfacial adhesion between fibers and matrix is a crucial factor for effective stress transfer from matrix to fiber; especially in short fiber reinforced composite systems. The use of a chemical compatibilizer is an efficient means to achieve such adhesion. Maleic anhydride-grafted-cellulose acetate butyrate (CAB-g-MA) is one such compatibilizer which can be used in biocomposite fabrication, and this has been synthesized in our laboratory by utilizing a twin-screw reactive extrusion process in the presence of a free radical initiator (2,5-dimethyl-2,5-di(tert -butylperoxy)hexane). The unique feature of this process is its solvent-free approach for grafting of maleic anhydride onto CAB, without hydroxyl group protection. CAB-g-MA was characterized using FTIR as well as by a non-aqueous titration method. The effects of initiator and monomer concentrations and various processing conditions on the graft content were also investigated. The preliminary results show that by adding approximately 10 wt.-% of CAB-g-MA into a plasticized cellulose acetate butyrate (TEB)-industrial hemp fiber biocomposites system, an improvement in tensile strength (20%) and in tensile modulus (45%) were obtained. These results are promising in that they pave the way for future studies involving the use of CAB-g-MA as a suitable compatibilizer for cellulose ester-natural fiber biocomposites. [source] On Toughness and Stiffness of Poly(butylene terephthalate) with Epoxide-Containing Elastomer by Reactive ExtrusionMACROMOLECULAR MATERIALS & ENGINEERING, Issue 8 2004Zhong-Zhen Yu Abstract Summary: To obtain a balance between toughness (as measured by notched impact strength) and elastic stiffness of poly(butylene terephthalate) (PBT), a small amount of tetra-functional epoxy monomer was incorporated into PBT/[ethylene/methyl acrylate/glycidyl methacrylate terpolymer (E-MA-GMA)] blends during the reactive extrusion process. The effectiveness of toughening by E-MA-GMA and the effect of the epoxy monomer were investigated. It was found that E-MA-GMA was finely dispersed in PBT matrix, whose toughness was significantly enhanced, but the stiffness decreased linearly, with increasing E-MA-GMA content. Addition of 0.2 phr epoxy monomer was noted to further improve the dispersion of E-MA-GMA particles by increasing the viscosity of the PBT matrix. While use of epoxy monomer had little influence on the notched impact strength of the blends, there was a distinct increase in the elastic stiffness. SEM micrographs of impact-fracture surfaces indicated that extensive matrix shear yielding was the main impact energy dissipation mechanism in both types of blends, with or without epoxy monomer, and containing 20 wt.-% or more elastomer. SEM micrographs of freeze-fractured surfaces of PBT/E-MA-GMA blend illustrating the finer dispersion of E-MA-GMA in the presence of epoxy monomer. [source] Influence of Domain Size on Toughness of Poly(styrene- block -butadiene) Star Block Copolymer/Polystyrene BlendsMACROMOLECULAR RAPID COMMUNICATIONS, Issue 24 2004Ralf Lach Abstract Summary: The toughness of poly(styrene- block -butadiene) star block copolymer/polystyrene (PS) blends have been investigated using the essential-work-of-fracture approach. The blends show a co-continuous or layer-like structure of polystyrene-rich and polybutadiene-rich domains arising from the used extrusion process. A tough-to-brittle transition at a critical domain size of polystyrene-rich domains of about 50 nm and a maximum in the non-essential work of fracture at 20,30% PS (co-continuous morphology) have been found. Non-essential work of fracture as a function of the mean thickness of polystyrene-rich domains, demonstrating a tough-to-brittle transition at a critical domain thickness about 50 nm. AFM micrograph of a star block copolymer/PS-blend containing 40% PS. [source] Herstellung verbundverstärkter Aluminiumprofile für ultraleichte Tragwerke durch StrangpressenMATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK, Issue 7 2004M. Kleiner Extrusion; Aluminum; Continuously Reinforcement; Special Tool Abstract Auf Grund ähnlicher spezifischer Steifigkeits- und Festigkeitseigenschaften von Aluminium und Stahl lassen sich in der Anwendung bei leichten Rahmenstrukturen durch gegenseitige Werkstoffsubstitution nur geringe Leichtbaugewinne erzielen. Lediglich die Verwendung von z.,B. Kohlefaserwerkstoffen oder Höchstleistungsstählen lässt eine Gewichtsreduktion für den Einsatz von Rohren oder Profilen in ultraleichten Strukturen erwarten. Am Lehrstuhl für Umformtechnik (LFU) der Universität Dortmund ist ein Verfahren entwickelt worden, das durch ein modifiziertes Strangpressen zur Herstellung von Verbundprofilen geeignet ist. Ausgehend von konventionellen Aluminium-Pressblöcken werden hierbei verschiedenartige endlose Verstärkungselemente innerhalb der Wandstärke der Profilmatrix eingebettet. Für das Verfahren, das im Rahmen des Sonderforschungsbereiches SFB/TR10 erforscht wird, ist die Entwicklung neuartiger Strangpresswerkzeuge erforderlich. Durch experimentelle Untersuchungen auf einer 2,5 MN Laborstrangpresse wurden erfolgreich erste Verbundprofile hergestellt. Zur Vertiefung des Prozessverständnisses und der Prognose der Wirksamkeit neuer Werkzeugkonzepte wurden parallel FEM-Simulationen durchgeführt. Die mit Hilfe des Verfahrens hergestellten geraden Verbundprofile lassen sich auf Grund möglicher Gefügeschädigungen nicht biegen. In Kombination mit dem ebenfalls am LFU entwickelten Verfahren Runden beim Strangpressen werden diese Verbundprofile jedoch auch mit gekrümmter Kontur herstellbar sein. Manufacture of Extruded and Continuously Reinforced Aluminum Profiles for Ultra-Lightweight Constructions Due to similar specific properties of aluminum and steel regarding stiffness and mechanical strength only minor achievements as to their application in lightweight space-frame structures can be attained by substituting one material for the other. Only the usage of carbon fibre materials or high performance steels promises a weight reduction as to the application of pipes and profiles in ultra-lightweight structures. At the Chair of Forming Technology of the University of Dortmund a process has been developed which is suitable for the manufacturing of continuously reinforced profiles by means of a modified direct extrusion process. Starting from conventional aluminum billets, various continuously reinforcing elements are being embedded in the wall thickness of the profile matrix. For this process, which is being investigated in the context of the Collaborative Research Centre SFB/TR10, new extrusion dies have to be developed. During experimental studies on a 2.5 MN laboratory direct extrusion press first reinforced profiles were manufactured successfully. In order to improve the understanding of the process and to predict the efficiency of new tool concepts, FEM simulations were carried out simultaneously. Reinforced straight profiles produced with the help of this method cannot be bend due to possible damages to the microstructure. However, in combination with the process of Rounding During Extrusion, which also has been developed at the Chair of Forming Technology, these reinforced profiles will be producible with a curved contour as well. [source] Asymptotic analysis of flow in wavy tubes and simulation of the extrusion processMATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 8 2007A. Ainser Abstract The paper is devoted to the mathematical modelling of an extrusion process. Usually, an extruder has a very complicated geometry. This generates a lot of difficulties for computations of three-dimensional flows. In the present paper, we develop and justify the asymptotic domain decomposition strategy in order to parallelize the computational process and reduce the memory. The error estimates are proved for the Stokes steady-state equation in the two-dimensional and three-dimensional cases. Then, the asymptotic domain decomposition procedure is applied for numerical testing and computations of the non-Newtonian fluid simulating a real process of the polymer extrusion. Copyright © 2007 John Wiley & Sons, Ltd. [source] Structural and mechanical properties of polystyrene nanocomposites with 1D titanate nanostructures prepared by an extrusion processPOLYMER COMPOSITES, Issue 9 2009Polona Umek Polystyrene (PS) nanocomposites with titanate nanotubes and titanate nanoribbons were prepared by an extrusion process at 180°C. Nanocomposites with 1 wt% of nanofillers and pure PS that had also been exposed to the extrusion process were comparatively examined with scanning electron microscopy (SEM), electron dispersive X-ray spectrometry (EDS) mapping, solid state proton nuclear magnetic resonance measurements (1H NMR), tensile tests, and shear creep measurements. SEM images and EDS mapping analysis show that titanate nanoribbons homogeneously distribute at a micrometer length-scale in the PS matrix during the extrusion process. This is not the case for titanate nanotubes, which show a stronger tendency to form clusters. Solid state 1H NMR studies, however, proved that the nanocomposites are inhomogeneous at a nanometric scale where structural components with highly mobile PS molecules coexist with domains of rigid PS molecules. Differences in the 1H spin-lattice relaxation at and above the glass transition temperature Tg = 373 K suggest that nanofillers affect the thermodynamic properties of nanocomposite domains. Only a slight increase in mechanical tensile properties was observed in the case of the nanocomposite containing 1 wt% of titanate nanoribbons (TiNRs) probably reflecting a weak interaction between the polymer matrix and the nanofiller. Nevertheless, our results prove that the use of functionalized TiNRs may, in combination with the extrusion process, represent a very promising starting point for the preparation of TiNR nanocomposites at the industrial level. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers [source] Mechanical properties of injection molded long fiber polypropylene composites, Part 1: Tensile and flexural propertiesPOLYMER COMPOSITES, Issue 2 2007K. Senthil Kumar Innovative polymers and composites are broadening the range of applications and commercial production of thermoplastics. Long fiber-reinforced thermoplastics have received much attention due to their processability by conventional technologies. This study describes the development of long fiber reinforced polypropylene (LFPP) composites and the effect of fiber length and compatibilizer content on their mechanical properties. LFPP pellets of different sizes were prepared by extrusion process using a specially designed radial impregnation die and these pellets were injection molded to develop LFPP composites. Maleic-anhydride grafted polypropylene (MA- g -PP) was chosen as a compatibilizer and its content was optimized by determining the interfacial properties through fiber pullout test. Critical fiber length was calculated using interfacial shear strength. Fiber length distributions were analyzed using profile projector and image analyzer software system. Fiber aspect ratio of more than 100 was achieved after injection molding. The results of the tensile and flexural properties of injection molded long glass fiber reinforced polypropylene with a glass fiber volume fraction of 0.18 are presented. It was found that the differences in pellet sizes improve the mechanical properties by 3,8%. Efforts are made to theoretically predict the tensile strength and modulus using the Kelly-Tyson and Halpin-Tsai model, respectively. POLYM. COMPOS., 28:259,266, 2007. © 2007 Society of Plastic Engineers [source] Characterization of contamination effects for two polypropylene-based materialsPOLYMER ENGINEERING & SCIENCE, Issue 1 2010Daniel Pessey In this work, contamination effects are studied on two polypropylene-based materials. These effects were identified on the molecular weight and on rheological and mechanical properties. Model contaminants chosen in this study were ethylene glycol and engine oil. They were added during the extrusion process to simulate the degradation due to contaminants. To quantify contamination effects and to correlate them with the microstructure evolution, scanning electron microscope (SEM) analyses were also conducted. The analysis of the different obtained results led to a better understanding of the mechanisms involved in the contamination process. Contaminants slightly affect the rheological properties, whereas mechanical properties are more influenced. These observations are confirmed by the modification of the fractured surfaces of the materials due to the presence of contaminants observed on SEM micrographs. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers [source] Morphology and properties of SAN-clay nanocomposites prepared principally by water-assisted extrusionPOLYMER ENGINEERING & SCIENCE, Issue 1 2010Michaël Mainil An efficient extrusion process involving the injection of water while processing was used to prepare poly (styrene- co -acrylonitrile) (SAN)/clay nanocomposites with a high degree of nanoclay delamination. The usefulness of water-assisted extrusion is highlighted here, in comparison with classical extrusion and roll mill processes. Cloisite® 30B (C30B), a montmorillonite clay organomodified with alkylammonium cations bearing 2-hydroxyethyl chains, and pristine montmorillonite were melt blended with SAN (25 wt% AN) in a semi-industrial scale extruder specially designed to allow water injection. XRD analysis, visual and TEM observations were used to evaluate the quality of clay dispersion. The relationship between the nanocomposite morphology and its mechanical and thermal properties was then investigated. The superiority of the SAN/C30B nanocomposite extruded with water has been evidenced by cone calorimetry tests and thermogravimetric measurements (TGA). These analyses showed a substantial improvement of the fire behavior and the thermal properties, while a 20% increase of the Young modulus was recorded. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers [source] | |||||||||||||||||||||||||||||||