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End Members (end + member)
Selected AbstractsFormation Kinetics of a Bi3Nb1,xTaxO7 Fluorite-Type Solid Solution and Thermodynamic Stability of the Bi3TaO7 End MemberJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2010Ursa Pirnat Analysis of kinetic characteristics of the incommensurate,commensurate transformation in the Bi3Nb1,xTaxO7 system with a fluorite-like crystal structure enabled us to define the compositional and thermal stability ranges of the commensurate tetragonal polymorph. We showed that the tetragonal polymorph across the entire homogeneity range is isostructural to the Bi3NbO7 end member. The kinetics of the transformation from the cubic incommensurate to the tetragonal commensurate phase decreases with an increase in Ta concentration within the Bi3Nb1,xTaxO7 system. The formation studies indicate that the tetragonal Bi3TaO7 is thermodynamically stable; however, its formation via the metastable incommensurate-cubic phase is suppressed. [source] Synthesis and Characterization of Mixed-Metal Oxide Nanopowders Along the CoOx,Al2O3 Tie Line Using Liquid-Feed Flame Spray PyrolysisJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2006Jose Azurdia We report here the use of liquid-feed flame spray pyrolysis (LF-FSP) to produce a series of nanopowders along the CoOx,Al2O3 tie line. The process is a general aerosol combustion synthesis route to a wide range of lightly agglomerated oxide nanopowders. The materials reported here were produced by aerosolizing ethanol solutions of alumatrane [Al(OCH2CH2)3N] and a cobalt precursor, made by reacting Co(NO3)2·6H2O crystals with propionic acid. The compositions of the as-produced nanopowders were controlled by selecting the appropriate ratios of the precursors. Nine samples with compositions (CoO)y(Al2O3)1,y, y=0,1 along the CoOx,Al2O3 tie line were prepared and studied. The resulting nanopowders were characterized by X-ray fluorescence, BET, scanning electron microscopy, high-resolution transmission electron micrographs, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and FTIR. The powders typically consist of single-crystal particles <40 nm diameter and specific surface areas (SSAs) of 20,60 m2/g. XRD studies show a gradual change in powder patterns from ,-Al2O3 to Co3O4. The cobalt aluminate spinel phase is observed at stoichiometries (21 and 37 mol%) not seen in published phase diagrams, likely because LF-FSP processing involves a quench of >1000°C in microseconds frequently leading to kinetic rather than thermodynamic products. Likewise, the appearance of Co3O4 rather than CoO as the end member in the tie line is thought to be a consequence of the process conditions. TGA studies combined with diffuse reflectance FTIR spectroscopic studies indicate that both physi- and chemi-sorbed H2O are the principal surface species present in the as-processed nanopowders. The only sample that differs is Co3O4, which has some carbonate species present that are detected and confirmed by a sharp mass loss event at ,250°C. The thermal behavior of the high cobalt content samples differs greatly from the low cobalt content samples. The latter behave like most LF-FSP-derived nanopowders exhibiting typical 1%,4% mass losses over the 1400°C range due mostly to loss of water and some CO2. The high cobalt content samples exhibit a sharp mass loss event that can be attributed to the decomposition of Co3O4 to CoO. [source] Structural elucidation of the Bi2(n,+,2)MonO6(n,+,1) (n = 3, 4, 5 and 6) family of fluorite superstructures by transmission electron microscopyACTA CRYSTALLOGRAPHICA SECTION B, Issue 4 2009Ángel R. Landa-Cánovas The cationic framework structure of a whole new family of compounds with the general formula Bi2(n,+,2)MonO6(n,+,1) (n = 3, 4, 5 and 6) has been elucidated by transmission electron microscopy (TEM) methods. High-resolution transmission electron microscopy (HRTEM) has been used to postulate heavy-atom models based on the known structure of the n = 3 phase, Bi10Mo3O24. These models were tested by HRTEM image simulation, electron diffraction and powder X-ray diffraction simulation methods which agreed with the experimental results. The four known phases of this family correspond to n = 3, 4, 5 and 6 members and all show fluorite superstructures. They consist of a common ,-Bi2O3 fluorite-type framework, inside of which are distributed ribbons of {MoO4} tetrahedra which are infinite along b, one tetrahedron thick along c, and of variable widths of 3, 4, 5 or 6 {MoO4} tetrahedra along a depending on the family member (n value). These {MoO4} tetrahedra are isolated, i.e. without sharing any corner as in the [Bi12O14] columnar structural-type phase Bi[Bi12O14][MoO4]4[VO4]. The structure of all these family members can be described as crystallographic shear derivatives from Aurivillius-type phases such as Bi2MoO6, the n = , end member. All these compounds are good oxygen-ion conductors. [source] Erosional vs. accretionary shelf margins: the influence of margin type on deepwater sedimentation: an example from the Porcupine Basin, offshore western IrelandBASIN RESEARCH, Issue 5 2009M. C. Ryan ABSTRACT A 1000 km2 three-dimensional (3D) seismic data survey that extends out from the western margin of the Porcupine Basin, offshore western Ireland reveals the internal geometry and depositional history of a large Palaeogene (Palaeocene,Early Eocene) shelf-margin. Two wells intersect the margin thereby constraining the depositional environments. The 34/19-1 well (landward end) intersects slope, shelf, marginal marine to coastal plain facies. The 35/21-1 well (basinward end) intersects seismically imaged shelf-margin clinoforms where base of slope back up to coastal plain deposits (source-to-sink) are represented. The basin-fill stratal architecture of the Palaeogene succession reveals sediment deposition under two end member, basin physiographic styles: (1) an erosional margin style and (2) an accretionary or progradational margin style. Uplift of the western margin of the basin is suggested as the major cause of the initially oversteepened shelf-slope erosional profile. Key characteristics of an erosional margin include sediment bypass of the shelf, canyon formation, and the development of significant onlapping submarine fan deposits on the lower slope. Failure on the slope is also revealed by several mass,transport complexes (MTCs) that carve out major erosive features across the slope. Three-dimensional seismic analysis illustrates variations in size, geometry and depositional trend and transport mechanisms of the MTCs. Confined, thick chaotic seismic facies, erosional basal scours and syn-depositional thrusting (pressure ridges) at terminus as opposed to thin, high-amplitude discontinuous facies with an unconfined lobate terminus are interpreted to indicate slump- and slide-dominated vs. debris flow-dominated MTCs, respectively. The erosional margin was transformed into an accretionary margin when the gradient of the shelf-slope to basin-floor profile was sufficiently lowered through the infilling and healing of the topographic lows by the onlapping submarine-fan deposits. This shallowing of the basin allowed nearshore systems to prograde across the deepwater systems. The accretionary margin was characterised by a thick sediment prism composed of clinoforms both at the shoreface/delta (tens of metres) and shelf-margin (hundreds of metres) scales. Shelf-margin clinoforms, the focus of this study, are the fundamental regressive to transgressive building blocks (duration 10,100 kyr) of the stratigraphic succession and can be observed on a larger scale (,1 Myr) through the migration and trajectory patterns of the shelf-edge. Trajectory pathways in the accretionary margin are accretionary in a descending or ascending manner. The descending style was characterised by a shelf-slope break that migrated seawards and obliquely downwards as a result of a relative sea-level fall. The descending trajectory geometry is lobate along strike suggestive of a point source progradation. Internally, the descending trajectory consists of downward stepping, steeply dipping shelf-margin clinoforms that display extensive slumping and deposition of sediment on the lower slope indicative of rapid deposition. Furthermore, basin-floor fans and associated ,feeder' channels extend basinwards beyond toe of slope. The ascending trajectory reflects a shelf-slope break that is interpreted to have migrated seawards during steady or rising relative sea level. The ascending trajectory geometry is associated with significant lateral sediment dispersal along the shelf-edge, reflecting distributary systems that were less ,fixed' or a greater reworking and longshore drift of sediment. Accretion involving the ascending shelf-edge trajectory characteristically lacked significant basin-floor deposits. Variable ascending trajectories are recognised in this study, as read from the angle at which the shelf-slope break migrates. Horizontal to high angle ascending trajectories correspond to dominantly progradational and dominantly aggradational shelf-edge trajectories, respectively. The sequence stratigraphic analysis of the Porcupine deltaic complex reveals a long-term relative sea-level rise. [source] Investigating the surface process response to fault interaction and linkage using a numerical modelling approachBASIN RESEARCH, Issue 3 2006P.A. Cowie ABSTRACT In order to better understand the evolution of rift-related topography and sedimentation, we present the results of a numerical modelling study in which elevation changes generated by extensional fault propagation, interaction and linkage are used to drive a landscape evolution model. Drainage network development, landsliding and sediment accumulation in response to faulting are calculated using CASCADE, a numerical model developed by Braun and Sambridge, and the results are compared with field examples. We first show theoretically how the ,fluvial length scale', Lf, in the fluvial incision algorithm can be related to the erodibility of the substrate and can be varied to mimic a range of river behaviour between detachment-limited (DL) and transport-limited (TL) end-member models for river incision. We also present new hydraulic geometry data from an extensional setting which show that channel width does not scale with drainage area where a channel incises through an area of active footwall uplift. We include this information in the coupled model, initially for a single value of Lf, and use it to demonstrate how fault interaction controls the location of the main drainage divide and thus the size of the footwall catchments that develop along an evolving basin-bounding normal fault. We show how erosion by landsliding and fluvial incision varies as the footwall area grows and quantify the volume, source area, and timing of sediment input to the hanging-wall basin through time. We also demonstrate how fault growth imposes a geometrical control on the scaling of river discharge with downstream distance within the footwall catchments, thus influencing the incision rate of rivers that drain into the hanging-wall basin. Whether these rivers continue to flow into the basin after the basin-bounding fault becomes fully linked strongly depends on the value of Lf. We show that such rivers are more likely to maintain their course if they are close to the TL end member (small Lf); as a river becomes progressively more under supplied, i.e. the DL end member (large Lf), it is more likely to be deflected or dammed by the growing fault. These model results are compared quantitatively with real drainage networks from mainland Greece, the Italian Apennines and eastern California. Finally, we infer the calibre of sediments entering the hanging-wall basin by integrating measurements of erosion rate across the growing footwall with the variation in surface processes in space and time. Combining this information with the observed structural control of sediment entry points into individual hanging-wall depocentres we develop a greater understanding of facies changes associated with the rift-initiation to rift-climax transition previously recognised in syn-rift stratigraphy. [source] Origin, age and petrogenesis of Neoproterozoic composite dikes from the Arabian-Nubian Shield, SW JordanGEOLOGICAL JOURNAL, Issue 2 2004G. Jarrar Abstract The evolution of a Pan-African (c. 900,550,Ma) suite of composite dikes, with latite margins and rhyolite interiors, from southwest Jordan is discussed. The dikes cut the Neoproterozoic calc-alkaline granitoids and high-grade metamorphic rocks (c. 800,600,Ma) of the northern Arabian-Nubian Shield in Jordan and have been dated by the Rb-Sr isochron method at 566±7,Ma. The symmetrically distributed latite margins constitute less than one-quarter of the whole dike thickness. The rhyolite intruded a median fracture within the latite, while the latter was still hot but completely solidified. The dikes are alkaline and bimodal in composition with a gap in SiO2 between 61 and 74,wt%. Both end members display similar chondrite-normalized rare earth element patterns. The rhyolites display the compositional signature of A-type granites. The (La/Lu)N values are 6.02 and 4.91 for latites and rhyolites, respectively, and the rhyolites show a pronounced negative Eu anomaly, in contrast to the slight negative Eu anomaly of the latites. The chemical variability (e.g. Zr/Y, Zr/Nb, K/Rb) within and between latites and rhyolites does not support a fractional crystallization relationship between the felsic and mafic members of the dikes. We interpret the magma genesis of the composite dikes as the result of intrusion of mantle-derived mafic magma into the lower crust in an extensional tectonic regime. The mafic magma underwent extensive fractional crystallization, which supplied the necessary heat for melting of the lower crust. The products of the initial stages of partial melting (5,10%) mixed with the fractionating mafic magma and gave rise to the latite melts. Further partial melting of the lower crust (up to 30%) produced a felsic melt, which upon 50% fractional crystallization (hornblende 15%, biotite 5%, feldspars 60%, and quartz 20%) gave rise to the rhyolitic magma. Copyright © 2004 John Wiley & Sons, Ltd. [source] Fluid-induced seismicity: Pressure diffusion and hydraulic fracturingGEOPHYSICAL PROSPECTING, Issue 2 2009S.A. Shapiro ABSTRACT Borehole fluid injections are common for the development of hydrocarbon and geothermic reservoirs. Often they induce numerous microearthquakes. Spatio-temporal dynamics of such induced microseismic clouds can be used to characterize reservoirs. However, a fluid-induced seismicity can be caused by a wide range of processes. Here we show that linear pore pressure relaxation and a hydraulic fracturing are two asymptotic end members of a set of non-linear diffusional phenomena responsible for seismicity triggering. To account for the whole range of processes we propose a rather general non-linear diffusional equation describing the pore pressure evolution. This equation takes into account a possibly strong enhancement of the medium permeability. Both linear pore pressure relaxation and hydraulic fracturing can be obtained as special limiting cases of this equation. From this equation we derive the triggering front of fluid induced seismicity, which is valid in the general case of non-linear pore pressure diffusion. We demonstrate corresponding seismicity signatures on different case studies. [source] Partitioning sources of soil respiration in boreal black spruce forest using radiocarbonGLOBAL CHANGE BIOLOGY, Issue 2 2006Edward A.G. Schuur Abstract Separating ecosystem and soil respiration into autotrophic and heterotrophic component sources is necessary for understanding how the net ecosystem exchange of carbon (C) will respond to current and future changes in climate and vegetation. Here, we use an isotope mass balance method based on radiocarbon to partition respiration sources in three mature black spruce forest stands in Alaska. Radiocarbon (,14C) signatures of respired C reflect the age of substrate C and can be used to differentiate source pools within ecosystems. Recently-fixed C that fuels plant or microbial metabolism has ,14C values close to that of current atmospheric CO2, while C respired from litter and soil organic matter decomposition will reflect the longer residence time of C in plant and soil C pools. Contrary to our expectations, the ,14C of C respired by recently excised black spruce roots averaged 14, greater than expected for recently fixed photosynthetic products, indicating that some portion of the C fueling root metabolism was derived from C storage pools with turnover times of at least several years. The ,14C values of C respired by heterotrophs in laboratory incubations of soil organic matter averaged 60, higher than the contemporary atmosphere ,14CO2, indicating that the major contributors to decomposition are derived from a combination of sources consistent with a mean residence time of up to a decade. Comparing autotrophic and heterotrophic ,14C end members with measurements of the ,14C of total soil respiration, we calculated that 47,63% of soil CO2 emissions were derived from heterotrophic respiration across all three sites. Our limited temporal sampling also observed no significant differences in the partitioning of soil respiration in the early season compared with the late season. Future work is needed to address the reasons for high ,14C values in root respiration and issues of whether this method fully captures the contribution of rhizosphere respiration. [source] Quantifying contributions to storm runoff through end-member mixing analysis and hydrologic measurements at the Panola Mountain Research Watershed (Georgia, USA)HYDROLOGICAL PROCESSES, Issue 10 2001Douglas A. Burns Abstract The geographic sources and hydrologic flow paths of stormflow in small catchments are not well understood because of limitations in sampling methods and insufficient resolution of potential end members. To address these limitations, an extensive hydrologic dataset was collected at a 10 ha catchment at Panola Mountain Research Watershed near Atlanta, GA, to quantify the contribution of three geographic sources of stormflow. Samples of stream water, runoff from an outcrop, and hillslope subsurface stormflow were collected during two rainstorms in the winter of 1996, and an end-member mixing analysis model that included five solutes was developed. Runoff from the outcrop, which occupies about one-third of the catchment area, contributed 50,55% of the peak streamflow during the 2 February rainstorm, and 80,85% of the peak streamflow during the 6,7 March rainstorm; it also contributed about 50% to total streamflow during the dry winter conditions that preceded the 6,7 March storm. Riparian groundwater runoff was the largest component of stream runoff (80,100%) early during rising streamflow and throughout stream recession, and contributed about 50% to total stream runoff during the 2 February storm, which was preceded by wet winter conditions. Hillslope runoff contributed 25,30% to peak stream runoff and 15,18% to total stream runoff during both storms. The temporal response of the three runoff components showed general agreement with hydrologic measurements from the catchment during each storm. Estimates of recharge from the outcrop to the riparian aquifer that were independent of model calculations indicated that storage in the riparian aquifer could account for the volume of rain that fell on the outcrop but did not contribute to stream runoff. The results of this study generally indicate that improvements in the ability of mixing models to describe the hydrologic response accurately in forested catchments may depend on better identification, and detailed spatial and temporal characterization of the mobile waters from the principal hydrologic source areas that contribute to stream runoff. Copyright © 2001 John Wiley & Sons, Ltd. [source] Carbon and nitrogen stable isotopes as tracers of change in diet breadth during Middle and Upper Palaeolithic in EuropeINTERNATIONAL JOURNAL OF OSTEOARCHAEOLOGY, Issue 3-4 2004D. Drucker Abstract Carbon and nitrogen stable isotope ratios in fossil bone collagen have been used as evidence for an increase of diet breadth between Middle Palaeolithic Neanderthals and Early Upper Palaeolithic anatomically modern humans. In this paper, we revisit the rules of palaeodietary reconstruction using collagen stable isotopes and reassess the possible isotopic signatures of potential protein resources available to prehistoric humans. It appears that the interpretation of the human's isotopic signature does not necessarily imply a significant proportion of aquatic-derived protein in the diet neither for Neandertal nor for first anatomically modern humans in Europe. Exploitation of aquatic ecosystems by humans needs to be supported by further zooarchaeological evidence. Nevertheless, isotopic biogeochemistry of fossil human collagen can be very useful in palaeodietary reconstructions provided that basic rules are followed while selecting samples of coeval fauna, in order to establish the end members of different food resources. Significant progress investigating the evolution of subsistence strategies in fossil hominids is expected from a combination of zooarchaeological and isotopic data. Copyright © 2004 John Wiley & Sons, Ltd. [source] Microstructure and Microwave Dielectric Properties of xCa(Al0.5Nb0.5)O3+(1,x)SrTiO3 Solid SolutionsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2010Mingzhe Hu The crystal structure evolution and microwave (MW) dielectric properties of xCa(Al0.5Nb0.5)O3+(1,x)SrTiO3 (xCAN+(1,x)ST, 0,x,1.0, ) dielectric ceramics were investigated. X-ray diffraction patterns illustrated that a single perovskite solid solution could be formed between the two end members; however, minor amount of pyrochlore phase was also detected in the composition range of 0.5,x,0.9. With the increase of x value, the crystal structure gradually evolved from a simple Pm3m cubic to a monoclinic P21/n space group with the octahedral tilting and the B-site ordering structure transition subsequently developed. The MW dielectric properties of xCAN+(1,x)ST solid solutions were elaborately investigated and correlated to their crystal structures. The microscopic structure-related thermal parameters in the xCAN+(1,x)ST solid solution were analyzed in terms of the Claussius,Mossotti equation to reveal the original contributors in temperature coefficients. Temperature coefficient-compensated ceramic could be obtained in the xCAN+(1,x)ST system in the range of 0.5 Subsolidus Phase Relationships in the ZnO,In2O3,SnO2 SystemJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2008Steven P. Harvey The subsolidus phase relationships in the ZnO,InO1.5,SnO2 system were investigated at 1275°C using X-ray diffraction. Each of the end members of the ternary diagram is a transparent conducting oxide. There are two substantial solid solutions in the ternary phase space, the bixbyite solid solution In2,2xZnxSnxO3 (x=0,0.40), and the indium substituted zinc stannate spinel, Zn(2,x)Sn(1,x)In2xO4 (x=0,0.45). The bixbyite solid solution is an outstanding TCO, whereas the spinel is only moderately conducting. Along the ZnO,InO1.5 binary, there is a series of transparent conducting homologous compounds (ZnO)k·In2O3 (where k=3, 4, 5, 6, 7, 9, 11). Within ternary phase space, these homologous compounds were found to exhibit negligible Sn solubility, and were always found to be compatible with the spinel. Equilibrium was difficult to achieve in the phase space between the homologous series compounds and the spinel, owing to sluggish kinetics. A procedure involving mixtures of prereacted spinel and the Zn11In2O14 (k=11) compound was developed, which allowed for more rapid approach to thermodynamic equilibrium, thereby allowing for the establishment of phase relationships near the ZnO corner of the phase diagram. [source] Thermodynamic Properties and Phase Diagram for the System MoO2,TiO2JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2008K. Thomas Jacob The activity of molybdenum dioxide (MoO2) in the MoO2,TiO2 solid solutions was measured at 1600 K using a solid-state cell incorporating yttria-doped thoria as the electrolyte. For two compositions, the emf was also measured as a function of temperature. The cell was designed such that the emf is directly related to the activity of MoO2 in the solid solution. The results show monotonic variation of activity with composition, suggesting a complete range of solid solutions between the end members and the occurrence of MoO2 with a tetragonal structure at 1600 K. A large positive deviation from Raoult's law was found. Excess Gibbs energy of mixing is an asymmetric function of composition and can be represented by the subregular solution model of Hardy as follows The temperature dependence of the emf for two compositions is reasonably consistent with ideal entropy of mixing. A miscibility gap is indicated at a lower temperature with the critical point characterized by Tc (K)=1560 and. Recent studies indicate that MoO2 undergoes a transition from a monoclinic to tetragonal structure at 1533 K with a transition entropy of 9.91 J·(mol·K),1. The solid solubility of TiO2 with rutile structure in MoO2 with a monoclinic structure is negligible. These features give rise to a eutectoid reaction at 1412 K. The topology of the computed phase diagram differs significantly from that suggested by Pejryd. [source] Thermochemistry of Glasses in the Y2O3 -Al2O3 -SiO2 SystemJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2003Yahong Zhang Enthalpies of drop solution in molten 2PbO-B2O3 at 1078 K were measured for glasses along the 2YAlO3 -3SiO2 and return ½Y3Al5O12 -3SiO2 joins. The onset glass transition temperature increases slightly with increasing silica content and Y/Al. Enthalpies of mixing were calculated on the basis of amorphous end members. Strongly negative heats of mixing support the absence of miscibility gaps except possibly for very high silica content, consistent with experimental phase analyses, which indicate much narrower miscibility gaps compared with the phase diagrams calculated on the basis of previous data and the CALPHAD formalism. [source] Properties of Ionic-Conducting ,-Bi2O3 Containing Mixed DopantsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2002Stephen D. Nunn ,-Bi2O3 compositions were prepared to evaluate the effect on properties of using mixed dopants. Baseline compositions containing 28 mol% of the alkaline-earth oxides CaO, SrO, or BaO were used for comparison. When the alkaline earths were combined in pairs to dope the bismuth oxide, the resulting properties were intermediate between the baseline end members. The data suggest that the transformation temperature for forming the high-conductivity ,1 phase can be varied continuously over a temperature range of about 565° to 750°C. Utilization of additional additives having different ionic size or valence charge compared with the alkaline earths resulted in no observed property changes that could be attributed to the additive alone. The most important variables influencing the conductivity level and phase transformation temperature of ,-Bi2O3 were the type and the amount of the alkaline-earth dopant in the composition. [source] Searching for the source regions of martian meteorites using MGS TES: Integrating martian meteorites into the global distribution of igneous materials on MarsMETEORITICS & PLANETARY SCIENCE, Issue 6 2003Victoria E. HAMILTON We deconvolved the TES data set using laboratory spectra of 6 martian meteorites (Los Angeles, Zagami, ALH A77005, Nakhla, ALH 84001, and Chassigny) as end members, along with atmospheric and surface spectra previously derived from TES data. Global maps (16 pixels/degree) of the distribution of each meteorite end member show that meteorite-like compositions are not present at or above TES detectability limits over most of the planet's dust-free regions. However, we have confidently identified local-scale (100s-1000s km2) concentrations of olivine- and orthopyroxene-bearing materials similar to ALH A77005, Chassigny, and ALH 84001 in Nili Fossae, in and near Ganges Chasma, in the Argyre and Hellas basin rims, and in Eos Chasma. Nakhla-like materials are identified near the detection limit throughout the eastern Valles Marineris region and portions of Syrtis Major. Basaltic shergottites were not detected in any spatially coherent areas at the scale of this study. Martian meteorite-like lithologies represent only a minor portion of the dust-free surface and, thus, are not representative of the bulk composition of the ancient crust. Meteorite-like spectral signatures identified above TES detectability limits in more spatially restricted areas ( Revised ,34S reference values for IAEA sulfur isotope reference materials S-2 and S-3,RAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 8 2009Jacqueline L. Mann Revised ,34S reference values with associated expanded uncertainties (95% confidence interval (C.I.)) are presented for the sulfur isotope reference materials IAEA-S-2 (22.62,±,0.16,) and IAEA-S-3 (,32.49,±,0.16,). These revised values are determined using two relative-difference measurement techniques, gas source isotope ratio mass spectrometry (GIRMS) and double-spike multi-collector thermal ionization mass spectrometry (MC-TIMS). Gas analyses have traditionally been considered the most robust for relative isotopic difference measurements of sulfur. The double-spike MC-TIMS technique provides an independent method for value-assignment validation and produces revised values that are both unbiased and more precise than previous value assignments. Unbiased ,34S values are required to anchor the positive and negative end members of the sulfur delta (,) scale because they are the basis for reporting both ,34S values and the derived mass-independent ,33S and ,36S values. Published in 2009 by John Wiley & Sons, Ltd. [source] The structure of orange HgI2.ACTA CRYSTALLOGRAPHICA SECTION B, Issue 6 2002The metastable orange crystals of HgI comprise three different crystal structures, all of which are built from corner-linked HgI supertetrahedra. Two of them are end members with the maximum degree of order (MDO) of a polytypic layer structure; the third shows a three-dimensional linkage. This paper presents the determination from X-ray diffraction data of the tetragonal polytypic structures and their stacking disorder. Diffraction patterns show sharp Bragg reflections and rods of diffuse intensity with pronounced maxima. In a first step, the diffuse intensity was neglected and all maxima were treated as Bragg reflections. The crystal was supposed to be a conglomerate of the two MDO structures diffracting independently, and their parameters and volume ratio were refined against the single data set. The geometries and anisotropic displacement parameters of the layers in the two structures are shown to be nearly identical. Layer contacts in the two stacking modes are identical. The structures are fractal complications of the stable red form of HgI. In a second step, the stacking disorder has been quantitatively analyzed with a Markov chain model. Two probabilities describing next-nearest-layer interactions were visually adjusted to observed intensity profiles extracted from image-plate detector data. Results consistently show that the crystal comprises nearly equal volumes of MDO structures with an average domain thickness of about 5 layers or 30,Å. [source] The structure of orange HgI2.ACTA CRYSTALLOGRAPHICA SECTION B, Issue 6 2002The metastable orange crystals of HgI comprise three different crystal structures all of which are built from corner-linked HgI supertetrahedra. Two of the structures are end members with the maximum degree of order (MDO) of a polytypic layer structure. In this paper, the third structure (D) determined from X-ray diffraction, a crystal chemical discussion of the four known tetrahedral HgI structures, and a twinning model are presented. All the various diffraction results published during the past 70 years are now explained. The HgI supertetrahedra of the tetragonal structure D are corner-linked into two interpenetrating diamond-type networks. The stable red form and the three orange structures show the same cubic densest packing of I atoms and differ only in the distribution of Hg atoms in the tetrahedral voids. Transformations between the structures may involve only movements of Hg atoms, as implied by larger thermal displacement parameters of Hg than of I. A multiply twinned conglomerate of MDO1, MDO2 and D, each structure occurring in three orientations, results in metrically cubic crystals whose Bragg reflections are very close to reciprocal lattice points. [source] Three-dimensional seismic characterisation of large-scale sandstone intrusions in the lower Palaeogene of the North Sea: completely injected vs. in situ remobilised sandbodiesBASIN RESEARCH, Issue 4 2010Ewa Szarawarska ABSTRACT A large number of km-scale, saucer-shaped sandstone bodies of enigmatic origin have recently been documented in the North Sea and the Faroe Shetland Basin. This study utilises three-dimensional seismic data, calibrated by well data, to examine two such bodies that exhibit very similar saucer-shaped geometries in cross-section. The Volund and Danica structures, located 250 km apart are interpreted as end members of a spectrum of large-scale remobilised and injected sandstones present in the North Sea Palaeogene. Both are characterised by a central 1,2 km-wide low area surrounded by a discordant, 2,300 m tall inclined dyke complex, that tips out into a bedding concordant body interpreted as a shallow-level sill and/or partly extruded sandstone. The origin of the central concordant sandstone body as either injected (laccolith) or depositional is of key importance to a complete understanding of the origin and prospectivity of these structures. The key criteria for recognising an injected vs. depositional origin for the central concordant sandbody are: (1) a flat, nonerosional base; (2) ,jack-up' of the overburden equal to the underlying sand thickness; (3) equally thick layers of encasing mudstones; and (4) paleogeographic context. This study suggests that the Danica structure was deposited as a channel sandstone and remobilised in situ; this led to the formation of wing-like intrusions along the channel margins. In contrast, the Volund structure overburden displays a forced-fold geometry, arguably a diagnostic feature of an intrusive origin. The ability to recognise and differentiate completely injected vs. in situ remobilised sandbodies is important both from a basin analysis, hydrocarbon exploration and rock mechanics points of view. An improved understanding of these aspects will lead to a reduction of risks associated with the exploration and development of such a sandbody and an enhanced understanding of sediment remobilisation and fluid flow on a basin scale. [source] Assembling the stratigraphic record: depositional patterns and time-scales in an experimental alluvial basinBASIN RESEARCH, Issue 3 2002B. A. Sheets ABSTRACT Our understanding of sedimentation in alluvial basins is best for very short and very long time-scales (those of bedforms to bars and basinwide deposition, respectively). Between these end members, the intermediate time-scales of stratigraphic assembly are especially hard to constrain with field data. We address these ,mesoscale' fluvial dynamics with data from an experimental alluvial system in a basin with a subsiding floor. Observations of experimental deposition over a range of time-scales illustrate two important properties of alluvial systems. First, ephemeral flows are disproportionately important in basin filling. Lack of correlation between flow occupation and sedimentation indicates that channelized flows serve mainly as conduits for sediment, while most deposition occurs via short-lived unchannelized flow events. Second, there is a characteristic time required for individual depositional events to average to basin-scale stratal patterns. This time can be scaled in terms of the time required for a single channel-depth of aggradation, and in this form is constant through a four-fold variation of experimental subsidence rate. [source]
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