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Effective Volume (effective + volume)

Distribution by Scientific Domains

Chemistry	40%

Selected Abstracts

The effective hard particle model provides a simple, robust, and broadly applicable description of nonideal behavior in concentrated solutions of bovine serum albumin and other nonassociating proteins

JOURNAL OF PHARMACEUTICAL SCIENCES, Issue 12 2007
Allen P. Minton
Abstract Published data on the concentration dependence of osmotic pressure of solutions of bovine serum albumin in 0.15 M NaCl at concentrations up to greater than 400 g/L are shown to be described to within experimental uncertainty by a simple one-parameter model in which protein molecules are represented by effective hard spherical particles. The volume of the effective hard particle reflects both steric and electrostatic repulsion and thus varies with pH and ionic strength. The pH dependence of the effective volume is shown to agree well with that previously obtained from analysis of the concentration dependence of sedimentation equilibrium and static light scattering. © 2007 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 96: 3466,3469, 2007 [source]

Luminous red galaxy clustering at z, 0.7 , first results using AAOmega

MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 3 2008
Nicholas P. Ross
ABSTRACT We report on the AAT-AAOmega LRG Pilot observing run to establish the feasibility of a large spectroscopic survey using the new AAOmega instrument. We have selected luminous red galaxies (LRGs) using single epoch SDSS riz -photometry to i < 20.5 and z < 20.2. We have observed in three fields including the COSMOS field and the COMBO-17 S11 field, obtaining a sample of ,600 redshift z, 0.5 LRGs. Exposure times varied from 1,4 h to determine the minimum exposure for AAOmega to make an essentially complete LRG redshift survey in average conditions. We show that LRG redshifts to i < 20.5 can be measured in ,1.5 h exposures and present comparisons with 2SLAQ and COMBO-17 (photo)redshifts. Crucially, the riz selection coupled with the three to four times improved AAOmega throughput is shown to extend the LRG mean redshift from z= 0.55 for 2SLAQ to z= 0.681 ± 0.005 for riz -selected LRGs. This extended range is vital for maximizing the signal-to-noise ratio for the detection of the baryon acoustic oscillations (BAOs). Furthermore, we show that the amplitude of LRG clustering is s0= 9.9 ± 0.7h,1 Mpc, as high as that seen in the 2SLAQ LRG Survey. Consistent results for this clustering amplitude are found from the projected and semi-projected correlation functions. This high amplitude is consistent with a long-lived population whose bias evolves as predicted by a simple ,high-peak' model. We conclude that a redshift survey of 360 000 LRGs over 3000 deg2, with an effective volume some four times bigger than previously used to detect BAO with LRGs, is possible with AAOmega in 170 nights. [source]

The UKIRT Infrared Deep Sky Survey (UKIDSS)

MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 4 2007
A. Lawrence
ABSTRACT We describe the goals, design, implementation, and initial progress of the UKIRT Infrared Deep Sky Survey (UKIDSS), a seven-year sky survey which began in 2005 May. UKIDSS is being carried out using the UKIRT Wide Field Camera (WFCAM), which has the largest étendue of any infrared astronomical instrument to date. It is a portfolio of five survey components covering various combinations of the filter set ZYJHK and H2. The Large Area Survey, the Galactic Clusters Survey, and the Galactic Plane Survey cover approximately 7000 deg2 to a depth of K, 18; the Deep Extragalactic Survey covers 35 deg2 to K, 21, and the Ultra Deep Survey covers 0.77 deg2 to K, 23. Summed together UKIDSS is 12 times larger in effective volume than the 2MASS survey. The prime aim of UKIDSS is to provide a long-term astronomical legacy data base; the design is, however, driven by a series of specific goals , for example, to find the nearest and faintest substellar objects, to discover Population II brown dwarfs, if they exist, to determine the substellar mass function, to break the z= 7 quasar barrier; to determine the epoch of re-ionization, to measure the growth of structure from z= 3 to the present day, to determine the epoch of spheroid formation, and to map the Milky Way through the dust, to several kpc. The survey data are being uniformly processed. Images and catalogues are being made available through a fully queryable user interface , the WFCAM Science Archive (http://surveys.roe.ac.uk/wsa). The data are being released in stages. The data are immediately public to astronomers in all ESO member states, and available to the world after 18 months. Before the formal survey began, UKIRT and the UKIDSS consortia collaborated in obtaining and analysing a series of small science verification (SV) projects to complete the commissioning of the camera. We show some results from these SV projects in order to demonstrate the likely power of the eventual complete survey. Finally, using the data from the First Data Release, we assess how well UKIDSS is meeting its design targets so far. [source]

Micelle and Solvent Relaxation in Aqueous Sodium Dodecylsulfate Solutions

CHEMPHYSCHEM, Issue 10 2003
Patrick Fernandez Dr.
Abstract Dielectric spectra have been measured for aqueous sodium dodecylsulfate (SDS) solutions up to 0.1 mol,L,1 at 25,°C over the frequency range 0.005,, GHz,1,89. The spectra exhibit two relaxation processes at approximately 0.03 GHz and 0.2 GHz associated with the presence of micelles in addition to the dominant solvent relaxation process at approximately 18 GHz and a small contribution at approximately 1.8 GHz due to H2O molecules hydrating the micelles. Detailed analysis reveals that the micelles bind 20 water molecules per SDS unit, but not as strongly as trimethylalkylammonium halide surfactants do. The relaxation times and amplitudes of both micelle relaxation processes can be simultaneously analysed with the theory of Grosse, yielding the effective volume of a SDS unit in the micelle and the lateral diffusion coefficient of the bound counterions. The findings of this investigation fully corroborate recent molecular dynamics simulations on structure and dynamics of SDS micelles. [source]

A probabilistic two-scale model for high-cycle fatigue life predictions

FATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 3 2005
C. DOUDARD
ABSTRACT It is proposed to develop and identify a probabilistic two-scale model for HCF that accounts for the failure of samples, but also for the thermal effects during cyclic loadings in a unified framework. The probabilistic model is based on a Poisson point process. Within the weakest link theory, the model corresponds to a Weibull law for the fatigue limits. The thermal effects can be described if one considers the same hypotheses apart from the weakest link assumption. A method of identification is proposed and uses temperature measurements to identify the scatter in an S/N curve. The validation of the model is obtained by predicting S/N curves for different effective volumes of a dual-phase steel. [source]