Dispersion

Distribution by Scientific Domains
Distribution within Polymers and Materials Science

Kinds of Dispersion

  • anomalous dispersion
  • band dispersion
  • carbon nanotube dispersion
  • cavity dispersion
  • clay dispersion
  • colloidal dispersion
  • energy dispersion
  • enhanced dispersion
  • fiber dispersion
  • filler dispersion
  • fine dispersion
  • finer dispersion
  • flour dispersion
  • forecast dispersion
  • geographical dispersion
  • good dispersion
  • greater dispersion
  • growth rate dispersion
  • high dispersion
  • homogeneous dispersion
  • income dispersion
  • increased dispersion
  • interval dispersion
  • large dispersion
  • magnetic relaxation dispersion
  • multiple-wavelength anomalous dispersion
  • multiwavelength anomalous dispersion
  • nanoparticle dispersion
  • nanotube dispersion
  • numerical dispersion
  • optical rotatory dispersion
  • p dispersion
  • p wave dispersion
  • p-wave dispersion
  • particle dispersion
  • phase dispersion
  • pigment dispersion
  • polyurethane dispersion
  • powder dispersion
  • price dispersion
  • qt dispersion
  • qt interval dispersion
  • qtc dispersion
  • rate dispersion
  • repolarization dispersion
  • rice flour dispersion
  • rotatory dispersion
  • single-wavelength anomalous dispersion
  • solid dispersion
  • spatial dispersion
  • stable dispersion
  • stellar velocity dispersion
  • transmural dispersion
  • uniform dispersion
  • velocity dispersion
  • wage dispersion
  • wave dispersion

  • Terms modified by Dispersion

  • dispersion analysis
  • dispersion behavior
  • dispersion characteristic
  • dispersion coefficient
  • dispersion copolymerization
  • dispersion curve
  • dispersion data
  • dispersion effects
  • dispersion equation
  • dispersion experiment
  • dispersion force
  • dispersion index
  • dispersion interaction
  • dispersion law
  • dispersion mechanism
  • dispersion model
  • dispersion models
  • dispersion parameter
  • dispersion pattern
  • dispersion phase
  • dispersion phasing
  • dispersion polymerization
  • dispersion process
  • dispersion profile
  • dispersion property
  • dispersion relation
  • dispersion state
  • dispersion technique
  • dispersion term

  • Selected Abstracts


    PRICE DISPERSION, INFLATION, AND WELFARE*

    INTERNATIONAL ECONOMIC REVIEW, Issue 2 2005
    Allen Head
    We examine the implications of inflation for both price dispersion and welfare in a monetary search economy. In our economy, if the degree of buyers' incomplete information about prices is fixed, both price dispersion and real prices are increasing in inflation. As the inflation rate approaches the Friedman rule, both price dispersion and welfare losses vanish. If households choose the number of prices to observe, then the optimal inflation rate may exceed the Friedman rule as inflation induces search and, up to a point, raises welfare by eroding market power. [source]


    RHEOLOGICAL PROPERTIES OF NONCOHESIVE APPLE DISPERSION WITH HELICAL AND VANE IMPELLERS: EFFECT OF CONCENTRATION AND PARTICLE SIZE

    JOURNAL OF FOOD PROCESS ENGINEERING, Issue 5 2000
    DENIS CANTÚ-LOZANO
    ABSTRACT The proportionality constant, ks, between shear rate, ,, and agitation velocity, N, for a helical ribbon-screw (HRS) agitator was 17.8. Using the HRS agitator, values of consistency index K and the flow behavior index n of 14 apple pulp suspensions at seven different solids concentrations and two average particle diameters 0.71 mm and 1.21 mm were determined; in addition, values of the Casson viscosity ,c and yield stress ,OC were also calculated. The magnitudes of K increased and of n decreased with increase in pulp concentration. Experimental values of the vane yield stress, ,O,, measured with a six-blade vane increased with increase in pulp content. The values of ,OC obtained using the Casson model were close to the experimental values ,O,. The effect of particle size on the relative viscosity, ,r, was correlated with Peclet number. [source]


    A MODEL OF MONOPOLISTIC COMPETITION WITH PERSONAL INCOME DISPERSION

    METROECONOMICA, Issue 3 2005
    Corrado Benassi
    ABSTRACT We introduce non-homothetic preferences in the Dixit,Stiglitz model of monopolistic competition, and enquire about the effects of a change in income dispersion on the firms' optimal decisions and market equilibrium. Income dispersion, modeled as a mean preserving spread, is shown to affect only the degree of product differentiation under the standard negligibility hypothesis on the firms' decision making process, while it generates a positive co-movement of demand and demand elasticity, when this assumption is removed and the price index effect is taken into account. [source]


    UNSTEADY STATE DISPERSION OF AIR POLLUTANTS UNDER THE EFFECTS OF DELAYED AND NONDELAYED REMOVAL MECHANISMS

    NATURAL RESOURCE MODELING, Issue 4 2009
    MANJU AGARWAL
    Abstract In this paper, we present a two-dimensional time-dependent mathematical model for studying the unsteady state dispersion of air pollutants emitted from an elevated line source in the atmosphere under the simultaneous effects of delayed (slow) and nondelayed (instantaneous) removal mechanisms. The wind speed and coefficient of diffusion are taken as functions of the vertical height above the ground. The deposition of pollutants on the absorptive ground and leakage into the atmosphere at the inversion layer are also included in the model by applying appropriate boundary conditions. The model is solved numerically by the fractional step method. The Lagrangian approach is used to solve the advection part, whereas the Eulerian finite difference scheme is applied to solve the part with the diffusion and removal processes. The solutions are analyzed to observe the effects of coexisting delayed and nondelayed removal mechanisms on overall dispersion. Comparison of delayed and nondelayed removal processes of equal capacity shows that the latter (nondelayed) process is more effective than the former (delayed removal) in the removal of pollutants from the atmosphere. [source]


    INCOME DISPERSION AND PRICE DISCRIMINATION

    PACIFIC ECONOMIC REVIEW, Issue 1 2006
    Yong He
    We first derive the linear demand curve in each market under plausible conditions, and then show that more markets (and consumers) are excluded under uniform pricing the higher are the inter-market income differences. We also show that adding markets, even of lower income levels than those of existing markets, helps to decrease prices and thus cause more markets to be served. Implications of intra-market income dispersion are also explored. [source]


    GELLING BEHAVIOR OF RICE FLOUR DISPERSIONS AT DIFFERENT CONCENTRATIONS OF SOLIDS AND TIME OF HEATING

    JOURNAL OF TEXTURE STUDIES, Issue 3 2008
    ALKA KAPRI
    ABSTRACT Rice flour dispersions, under suitable conditions of processing, can form a gel. The effect of concentration of solids (10,18%) and time (0,75 min) of processing on textural attributes, and viscoelasticity were investigated along with sensory attributes. The textural attribute determined is gel strength, while viscoelasticity was determined in terms of mechanical spectra like storage modulus (G,), loss modulus (G,), complex viscosity (,*) and loss factor (tan ,) during a frequency sweep varying from 0.01 to 40 Hz at a constant stress of 25 Pa. Microstructural observation indicates the swelling of starch granules in the beginning of heating, while damaged granule and leached-out materials are visible at the end of the gelling process. Desirability function analysis has been applied to obtain a rice gel with acceptable textural attributes; a solid concentration of 15.2% and a heating time of 75 min can lead to the development of a gel with a satisfaction level of 0.6. PRACTICAL APPLICATIONS Rice flour gels in the form of hard-set gels, porridges and spreads are popular in several parts of the world particularly for feeding of infants and children. The application of the present study lies in understanding the role of major processing variables on the quality attributes and viscoelasticity of a product, characterization of cooked gels and for developing rice flour-based food gels. The findings may also be extended for the development of other cereal-based gels. [source]


    Anomalous Dispersion in Predictive Rendering

    COMPUTER GRAPHICS FORUM, Issue 4 2009
    Andrea Weidlich
    Abstract In coloured media, the index of refraction does not decrease monotonically with increasing wavelength, but behaves in a quite non-monotonical way. This behaviour is called anomalous dispersion and results from the fact that the absorption of a material influences its index of refraction. So far, this interesting fact has not been widely acknowledged by the graphics community. In this paper, we demonstrate how to calculate the correct refractive index for a material based on its absorption spectrum with the Kramers-Kronig relation, and we discuss for which types of objects this effect is relevant in practice. [source]


    Further Evidence on the Relation between Analysts' Forecast Dispersion and Stock Returns,

    CONTEMPORARY ACCOUNTING RESEARCH, Issue 2 2009
    Orie E. Barron
    First page of article [source]


    Dispersion of Dust Acoustic Modes and Perturbations of Plasma Flux Balance

    CONTRIBUTIONS TO PLASMA PHYSICS, Issue 3 2007
    V. Tsytovich
    Abstract Previous considerations of dust acoustic waves is demonstrated to be inconsistent - the required equilibrium state for perturbations was not defined since balance of plasma fluxes was neglecting. The self-consistent treatment shows that plasma flux perturbations are accompanying any collective waves propagating in dusty plasmas and can play an important role in wave dispersion, wave damping and can create instabilities. This is illustrated by the derivation of dispersion relation for dust acoustic modes taking into account the plasma flux balances and plasma flux perturbations by waves. The result of this approach shows that the dust acoustic waves with linear dependence of wave frequency on the wave number exist only in restricted range of the wave numbers. Only for wave numbers larger than some critical wave number for low frequency modes the frequency can be have approximately a linear dependence on wave number and can be called as dust acoustic wave but the phase velocity of these waves is different from that which can be obtained neglecting the flux balance and depends on grain charge variations which are determined by the balance of fluxes. The presence of plasma fluxes previously neglected is the main typical feature of dusty plasmas. The dispersion relation in the range of small wave numbers is found to be mainly determined by the change of the plasma fluxes and is quite different from that of dust acoustic type, namely it is found to have the same form as the well known dispersion relation for the gravitational instability. This result proves in general way the existence of the collective grain attractions of negatively charged grains for for large distances between them and for any source of ionization. The attraction of grains found from dispersion relation of the dust acoustic branch coincides with that found previously for pair grain interactions using some models for the ionization source. For the existing experiments the effective Jeans length for such attraction is estimated to be about 8 , 10 times larger than the ion Debye length and the effective gravitational constant for the grain attraction is estimated to be several orders of magnitude larger than the usual gravitational constant. The grain attraction at large inter-grain distances described by the gravitationlike grain instability is considered as the simplest explanation for observed dust cloud clustering, formation of dust structures including the plasma crystals. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Micronization of the officinal component baicalin by SEDS-PA process

    CRYSTAL RESEARCH AND TECHNOLOGY, Issue 6 2007
    Wen Zhi He
    Abstract Application of micronizing technologies in processing Chinese herbal medicines is very important to improve the forms of prepared Chinese herbal medicines and promote their therapeutic efficacy. Baicalin, a major active component of the typical Chinese herb medicine Scullateria baicallensis Georgi, was micronized using the Solution Enhanced Dispersion by Supercritical fluids though Prefilming Atomization (SEDS-PA) process with the aim of evaluating the efficiency of applying supercritical fluid precipitation technologies in Chinese herb medicine. This study has shown that acicula or rod-like baicalin crystals with Particle Size (PS) of about 20×100 ,m were successfully micronized by the SEDS-PA process to long rod-like, twisted fiber-like or fibrous net-like microparticles with PS of 0.1-2.2 ,m in width within the range of experiments performed. It was found that a substantial reduction of baicalin microparticles' sizes could lead to a marked increase of adhesions among them and subsequent microparticles agglomeration. With the increase of supercritical CO2 flow rate and the decrease of solution concentration and solution flow rate, smaller and much more agglomerated microparticles were obtained. Increasing pressure led to formation of smaller microparticles. A larger tendency of particles agglomeration was produced at a higher temperature. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    The Relationship Between Left Ventricular Shape and QT Interval Dispersion

    ECHOCARDIOGRAPHY, Issue 8 2002
    F.A.C.C., Kishore J. Harjai M.D.
    Left ventricular geometry is suspected to affect heterogeneity of myocardial repolarization; therefore, it is plausible but unproven that increased sphericity of the left ventricle is associated with greater QT interval dispersion. In 60 patients with dilated cardiomyopathy with left ventricular ejection fraction , 30%, we found that spherical distortion of the left ventricle was associated with increased QT dispersion, implying increased heterogeneity of myocardial repolarization. [source]


    Dispersion of flightless adults of the Asian lady beetle, Harmonia axyridis, in greenhouses containing cucumbers infested with the aphid Aphis gossypii: effect of the presence of conspecific larvae

    ENTOMOLOGIA EXPERIMENTALIS ET APPLICATA, Issue 1 2004
    Lionel Gil
    Abstract Most females of the Asian lady beetle, Harmonia axyridis Pallas (Coleoptera: Coccinellidae), stop laying eggs if conspecific larvae are present. We studied the effect of this inhibition on the dispersion of this insect in a greenhouse containing cucumbers uniformly infested with the aphid Aphis gossypii Glover (Homoptera: Aphididae). In the absence of conspecific larvae, the adults moved around at random, sinuously, and independently. They spent most of their time walking on the ground and only a little time on the aphid-infested plants. When the cucumber plants in one half of the greenhouse had conspecific larvae on them, the whole adult population migrated to the larva-free half of the greenhouse. Consequently, most eggs were laid in that part of the greenhouse which was devoid of larvae. The consequences of this spatio-temporal interaction between larvae and adults for the biological control of aphids is discussed. [source]


    Functionalized Multi-Wall Carbon Nanotubes for Lipase Immobilization,

    ADVANCED ENGINEERING MATERIALS, Issue 5 2010
    I. V. Pavlidis
    Abstract We examine the immobilization of lipase B from Candida antarctica on functionalized multi-wall carbon nanotubes (MWCNTs) through physical adsorption. MWCNTs functionalized with carboxyl-, amine- and ester- terminal groups on their surface are used as immobilization carriers. Dispersion of the nanotubes and the immobilization procedure take place in aqueous and low-water media. High enzyme loadings are attained, up to 25% of the weight of the carbon nanotubes. These novel biomaterials are characterized though FT-IR and Raman spectroscopy. The MWCNT,lipase bioconjugates exhibit high catalytic activity and increased storage and operational stability. The biomaterials retain more than 55% of their initial activity after 6 months at 4,°C, while they retain approximately 25% of their initial activity after 30 d of incubation in hexane at 60,°C. The catalytic behaviour of the immobilized enzyme depends on the terminal group of the carbon nanotubes, the concentration of the enzyme and the immobilization method employed. [source]


    High Performance SiC Oxidation Protective Coating with ZrO2 Particle Dispersion for Carbon/Carbon Composites,

    ADVANCED ENGINEERING MATERIALS, Issue 10 2008
    Y.-L. Zhang
    High performance SiC oxidation protective coating with ZrO2 particle dispersion for C/C composites was prepared by slurry and pack cementation. Isothermal oxidation tests at 1873,K in air showed that the as-prepared coating could effectively protect C/C composites from oxidation for 100,h. The excellent oxidation protective ability can be attributed to the introduction of ZrO2 particles in the SiC coating, which can baffle the enlargement of cracks and suppress the generation of the thermal stress. [source]


    Towards Efficient Dispersion of Carbon Nanotubes in Thermotropic Liquid Crystals

    ADVANCED FUNCTIONAL MATERIALS, Issue 19 2010
    Stefan Schymura
    Abstract Motivated by numerous recent reports indicating attractive properties of composite materials of carbon nanotubes (CNTs) and liquid crystals (LCs) and a lack of research aimed at optimizing such composites, the process of dispersing CNTs in thermotropic LCs is systematically studied. LC hosts can perform comparably or even better than the best known organic solvents for CNTs such as N -methyl pyrrolidone (NMP), provided that the dispersion process and choice of LC material are optimized. The chemical structure of the molecules in the LC is very important; variations in core as well as in terminal alkyl chain influence the result. Several observations moreover indicate that the anisotropic nematic phase, aligning the nanotubes in the matrix, per se stabilizes the dispersion compared to a host that is isotropic and thus yields random tube orientation. The chemical and physical phenomena governing the preparation of the dispersion and its stability are identified, taking into account enthalpic, entropic, as well as kinetic factors. This allows a guideline on how to best design and prepare CNT,LC composites to be sketched, following which tailored development of new LCs may take the advanced functional material that CNT,LC composites comprise to the stage of commercial application. [source]


    Molecular-Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites

    ADVANCED FUNCTIONAL MATERIALS, Issue 14 2009
    Jiajie Liang
    Abstract Despite great recent progress with carbon nanotubes and other nanoscale fillers, the development of strong, durable, and cost-efficient multifunctional nanocomposite materials has yet to be achieved. The challenges are to achieve molecule-level dispersion and maximum interfacial interaction between the nanofiller and the matrix at low loading. Here, the preparation of poly(vinyl alcohol) (PVA) nanocomposites with graphene oxide (GO) using a simple water solution processing method is reported. Efficient load transfer is found between the nanofiller graphene and matrix PVA and the mechanical properties of the graphene-based nanocomposite with molecule-level dispersion are significantly improved. A 76% increase in tensile strength and a 62% improvement of Young's modulus are achieved by addition of only 0.7,wt% of GO. The experimentally determined Young's modulus is in excellent agreement with theoretical simulation. [source]


    A Family of Location Models for Multiple-Type Discrete Dispersion

    GEOGRAPHICAL ANALYSIS, Issue 3 2006
    Kevin M. Curtin
    One of the defining objectives in location science is to maximize dispersion. Facilities can be dispersed for a wide variety of purposes, including attempts to optimize competitive market advantage, disperse negative impacts, and optimize security. With one exception, all of the extant dispersion models consider only one type of facility, and ignore problems where multiple types of facilities must be located. We provide examples where multiple-type dispersion is appropriate and based on this develop a general class of facility location problems that optimize multiple-type dispersion. This family of models expands on the previously formulated definitions of dispersion for single types of facilities, by allowing the interactions among different types of facilities to determine the extent to which they will be spatially dispersed. We provide a set of integer-linear programming formulations for the principal models of this class and suggest a methodology for intelligent constraint elimination. We also present results of solving a range of multiple-type dispersion problems optimally and demonstrate that only the smallest versions of such problems can be solved in a reasonable amount of computer time using general-purpose optimization software. We conclude that the family of multiple-type dispersion models provides a more comprehensive, flexible, and realistic framework for locating facilities where weighted distances should be maximized, when compared with the special case of locating only a single type of facility. [source]


    Dispersion of Nodes Added to a Network

    GEOGRAPHICAL ANALYSIS, Issue 4 2005
    Michael Kuby
    For location problems in which optimal locations can be at nodes or along arcs but no finite dominating set has been identified, researchers may desire a method for dispersing p additional discrete candidate sites along the m arcs of a network. This article develops and tests minimax and maximin models for solving this continuous network location problem, which we call the added-node dispersion problem (ANDP). Adding nodes to an arc subdivides it into subarcs. The minimax model minimizes the maximum subarc length, while the maximin model maximizes the minimum subarc length. Like most worst-case objectives, the minimax and maximin objectives are plagued by poorly behaved alternate optima. Therefore, a secondary MinSumMax objective is used to select the best-dispersed alternate optima. We prove that equal spacing of added nodes along arcs is optimal to the MinSumMax objective. Using this fact we develop greedy heuristic algorithms that are simple, optimal, and efficient (O(mp)). Empirical results show how the maximum subarc, minimum subarc, and sum of longest subarcs change as the number of added nodes increases. Further empirical results show how using the ANDP to locate additional nodes can improve the solutions of another location problem. Using the p-dispersion problem as a case study, we show how much adding ANDP sites to the network vertices improves the p-dispersion objective function compared with (a) network vertices only and (b) vertices plus randomly added nodes. The ANDP can also be used by itself to disperse facilities such as stores, refueling stations, cell phone towers, or relay facilities along the arcs of a network, assuming that such facilities already exist at all nodes of the network. [source]


    Theoretical and Applied Case Studies of Seismic Imaging in Tunnelling

    GEOMECHANICS AND TUNNELLING, Issue 5 2008
    Thomas Dickmann Dr.
    Seismic measurements during tunnel operations aim at images of maximum spatial resolution. However, there are still principal limitations of the method applied in the tunnel with regard to spatial resolution by the signal frequency and attenuation and by the small angular illumination coverage. A finite-difference simulation of elastic wave propagation had been performed to compute a synthetic tunnel seismic reflection survey. Synthetic data are used optimizing the best practice tunnel data processing sequence for both P- and S-waves because every step between the acquisition of the seismic data and the derivation of the final image influences the final seismic resolution. Here, especially the use of attenuation models compensate amplitude loss as well as dispersion by an inverse Q-filtering and the use of a spatially variable velocity model yielding the right image position of a reflecting geological element in space. The transfer and capability of this practice to real tunnel application is finally demonstrated by the case study of the tunnel seismic prediction method in the Koralm tunnel project in Austria. Theoretische und praktische Fallbeispiele der seismischen Abbildung im Tunnelbau Seismische Messungen während der Tunnelbauausführungen sollen eine Abbildung von maximaler räumlicher Auflösung erzielen. Allerdings gibt es immer noch grundsätzliche Einschränkungen hinsichtlich räumlicher Auflösung aufgrund von Signalfrequenz und -dämpfung und aufgrund des eingeschränkten Winkelbereichs des Beleuchtungsraums, wenn die Methode aus dem Tunnel heraus nach vorne angewendet wird. Es wurde eine Finite-Differenzen Simulation der elastischen Wellenausbreitung durchgeführt, um synthetische tunnelseismische Reflexionsdaten zu erhalten. Diese synthetischen Daten dienten dazu, die optimale Bearbeitungsfolge von P- und S-Wellendaten aus dem Tunnel abzuleiten, da jeder einzelne Bearbeitungsschritt zwischen der seismischen Datenaufnahme und der Endabbildung die endgültige seismische Auflösung beeinflusst. Hierbei kompensiert besonders die Anwendung eines Dämpfungsmodels mittels eines inversen Q-Filters und eines räumlich variablen Geschwindigkeitsmodels den Verlust von Amplitudenstärke und die Dispersion, was zu einer richtigen räumlichen Abbildungsposition des Reflektors eines geologischen Elementes führt. Die Leistungsfähigkeit dieser Vorgehensweise und deren Übertragung auf die wirkliche Tunnelanwendung werden schließlich durch das Beispiel der tunnelseismischen Vorauserkundung am Koralmtunnel in Österreich demonstriert. [source]


    Dispersion and radial depth of investigation of borehole modes

    GEOPHYSICAL PROSPECTING, Issue 4 2004
    Bikash K. Sinha
    ABSTRACT Sonic techniques in geophysical prospecting involve elastic wave velocity measurements that are performed by placing acoustic transmitters and receivers in a fluid-filled borehole. The signals recorded at the receivers are processed to obtain compressional- and shear-wave velocities in the surrounding formation. These velocities are generally used in seismic surveys for the time-to-depth conversion and other formation parameters, such as porosity and lithology. Depending upon the type of transmitter used (e.g. monopole or dipole) and as a result of eccentering, it is possible to excite axisymmetric (n= 0), flexural (n= 1) and quadrupole (n= 2) families of modes propagating along the borehole. We present a study of various propagating and leaky modes that includes their dispersion and attenuation characteristics caused by radiation into the surrounding formation. A knowledge of propagation characteristics of borehole modes helps in a proper selection of transmitter bandwidth for suppressing unwanted modes that create problems in the inversion for the compressional- and shear-wave velocities from the dispersive arrivals. It also helps in the design of a transmitter for a preferential excitation of a given mode in order to reduce interference with drill-collar or drilling noise for sonic measurements-while-drilling. Computational results for the axisymmetric family of modes in a fast formation with a shear-wave velocity of 2032 m/s show the existence of Stoneley, pseudo-Rayleigh and anharmonic cut-off modes. In a slow formation with a shear-wave velocity of 508 m/s, we find the existence of the Stoneley mode and the first leaky compressional mode which cuts in at approximately the same normalized frequency ,a/VS= 2.5 (a is the borehole radius) as that of the fast formation. The corresponding modes among the flexural family include the lowest-order flexural and anharmonic cut-off modes. For both the fast and slow formations, the first anharmonic mode cuts in at a normalized frequency ,a/VS= 1.5 approximately. Cut-off frequencies of anharmonic modes are inversely proportional to the borehole radius in the absence of any tool. The borehole quadrupole mode can also be used for estimating formation shear slownesses. The radial depth of investigation with a quadrupole mode is marginally less than that of a flexural mode because of its higher frequency of excitation. [source]


    Plasma Nanoparticle Synthesis: Luminescent Colloidal Dispersion of Silicon Quantum Dots from Microwave Plasma Synthesis: Exploring the Photoluminescence Behavior Across the Visible Spectrum (Adv. Funct.

    ADVANCED FUNCTIONAL MATERIALS, Issue 5 2009
    Mater.
    The cover picture shows a view into the plasma zone of a microwave plasma reactor, which is used to synthesize macroscopic quantities of single crystalline silicon nanoparticles with a very high production rate. These nanoparticles exhibit bright luminescence across the visible spectrum. On page 696, the authors report that the emission of such silicon nanoparticles can be tuned by changing their size and surface chemistry. [source]


    Luminescent Colloidal Dispersion of Silicon Quantum Dots from Microwave Plasma Synthesis: Exploring the Photoluminescence Behavior Across the Visible Spectrum

    ADVANCED FUNCTIONAL MATERIALS, Issue 5 2009
    Anoop Gupta
    Abstract Aiming for a more practical route to highly stable visible photoluminescence (PL) from silicon, a novel approach to produce luminescent silicon nanoparticles (Si-NPs) is developed. Single crystalline Si-NPs are synthesized by pyrolysis of silane (SiH4) in a microwave plasma reactor at very high production rates (0.1,10,g,h,1). The emission wavelength of the Si-NPs is controlled by etching them in a mixture of hydrofluoric acid and nitric acid. Emission across the entire visible spectrum is obtained by varying the etching time. It is observed that the air oxidation of the etched Si-NPs profoundly affects their optical properties, and causes their emission to blue-shift and diminish in intensity with time. Modification of the silicon surface by UV-induced hydrosilylation also causes a shift in the spectrum. The nature of the shift (red/blue) is dependent on the emission wavelength of the etched Si-NPs. In addition, the amount of shift depends on the type of organic ligand on the silicon surface and the UV exposure time. The surface modification of Si-NPs with different alkenes results in highly stable PL and allows their dispersion in a variety of organic solvents. This method of producing macroscopic quantities of Si-NPs with very high PL stability opens new avenues to applications of silicon quantum dots in optoelectronic and biological fields, and paves the way towards their commercialization. [source]


    Polymer-Mediated Dispersion of Gold Nanoparticles: Using Supramolecular Moieties on the Periphery

    ADVANCED MATERIALS, Issue 38-39 2009
    Adam D. Celiz
    A novel method of dispersing gold nanoparticles (Au NPs) is described. Thiol-terminated ureido-pyrimidinone (UPy)-functionalized polymers are attached to Au NPs to create a polymeric shell with quadruple hydrogen-bonding units on the periphery. By increasing the amount of UPy loading on the Au NPs, self-assembly into aggregates is observed with both 1H NMR spectroscopy and transmission electron microscopy. [source]


    Some questions on dispersion of human exhaled droplets in ventilation room: answers from numerical investigation

    INDOOR AIR, Issue 2 2010
    C. Chen
    Abstract, This study employs a numerical model to investigate the dispersion characteristics of human exhaled droplets in ventilation rooms. The numerical model is validated by two different experiments prior to the application for the studied cases. Some typical questions on studying dispersion of human exhaled droplets indoors are reviewed and numerical study using the normalized evaporation time and normalized gravitational sedimentation time was performed to obtain the answers. It was found that modeling the transient process from a droplet to a droplet nucleus due to evaporation can be neglected when the normalized evaporation time is <0.051. When the normalized gravitational sedimentation time is <0.005, the influence of ventilation rate could be neglected. However, the influence of ventilation pattern and initial exhaled velocity on the exhaled droplets dispersion is dominant as the airflow decides the droplets dispersion significantly. Besides, the influence of temperature and relative humidity on the dispersion of droplets can be neglected for the droplet with initial diameter <200 ,m; while droplet nuclei size plays an important role only for the droplets with initial diameter within the range of 10 ,m,100 ,m. Practical Implications Dispersion of human exhaled droplets indoor is a key issue when evaluating human exposure to infectious droplets. Results from detailed numerical studies in this study reveal how the evaporation of droplets, ventilation rate, airflow pattern, initial exhaled velocity, and particle component decide the droplet dispersion indoor. The detailed analysis of these main influencing factors on droplet dispersion in ventilation rooms may help to guide (1) the selection of numerical approach, e.g., if the transient process from a droplet to a droplet nucleus due to evaporation should be incorporated to study droplet dispersion, and (2) the selection of ventilation system to minimize the spread of pathogen-laden droplets in an indoor environment. [source]


    Dispersion of Graphene Sheets in Organic Solvent Supported by Ionic Interactions

    ADVANCED MATERIALS, Issue 17 2009
    Yanyu Liang
    Organic solution-processable graphene sheets were prepared using a large-scale novel approach based on a transfer process assisted by ionic interactions. Smooth monolayer graphene sheets were easily fabricated on a substrate from organic solution. Such a noncovalent functionalization preserves the extended aromatic conjugation of reduced graphene sheets, giving rise to high-conductivity cast films. [source]


    Monopoly Price Dispersion Under Demand Uncertainty

    INTERNATIONAL ECONOMIC REVIEW, Issue 3 2001
    James D. Jr. DanaArticle first published online: 23 DEC 200
    When a monopolist sets its price before its demand is known, then it may set more than one price and limit the availability of its output at lower prices. This article adds demand uncertainty and price rigidities to the standard model of monopoly pricing. When there are two states of demand and the ex post monopoly price is greater when demand is high then the monopolist's optimal ex ante pricing strategy is to set two prices and limit purchases at the lower price. [source]


    Equilibrium Search with Continuous Productivity Dispersion: Theory and Nonparametric Estimation

    INTERNATIONAL ECONOMIC REVIEW, Issue 2 2000
    Christian Bontemps
    In this article we develop an equilibrium search model with a continuous distribution of firm productivity types within a given labor market. We characterize equilibrium, derive expressions for the endogenous equilibrium wage distributions, and characterize the set of wage distributions that can be generated by the model. We develop a structural nonparametric estimation method for the productivity distribution. We estimate the model using French longitudinal survey data on labor supply, and we compare the results with those from a French panel data set of firms. The results are informative on the degree to which firms exploit search frictions. [source]


    Nanorod-Driven Orientational Control of Liquid Crystal for Polarization-Tailored Electro-Optic Devices

    ADVANCED MATERIALS, Issue 9 2009
    Somobrata Acharya
    Dispersion of ultranarrow ZnS nanorods of molecular dimensions encapsulated by a fluid-like soft organic layer in the nematic liquid crystal (LC ZLI-4792) results in a novel soft-matter-type blend with previously unachieved electro-optic properties. The local ordering of the nanorods significantly affects the global ordering of the blend, allowing a more rapid response. [source]


    Dispersion and stability analyses of the linearized two-dimensional shallow water equations in boundary-fitted co-ordinates

    INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 7 2003
    S. Sankaranarayanan
    Abstract In the present investigation, a Fourier analysis is used to study the phase and group speeds of a linearized, two-dimensional shallow water equations, in a non-orthogonal boundary-fitted co-ordinate system. The phase and group speeds for the spatially discretized equations, using the second-order scheme in an Arakawa C grid, are calculated for grids with varying degrees of non-orthogonality and compared with those obtained from the continuous case. The spatially discrete system is seen to be slightly dispersive, with the degree of dispersivity increasing with an decrease in the grid non-orthogonality angle or decrease in grid resolution and this is in agreement with the conclusions reached by Sankaranarayanan and Spaulding (J. Comput. Phys., 2003; 184: 299,320). The stability condition for the non-orthogonal case is satisfied even when the grid non-orthogonality angle, is as low as 30° for the Crank Nicolson and three-time level schemes. A two-dimensional wave deformation analysis, based on complex propagation factor developed by Leendertse (Report RM-5294-PR, The Rand Corp., Santa Monica, CA, 1967), is used to estimate the amplitude and phase errors of the two-time level Crank,Nicolson scheme. There is no dissipation in the amplitude of the solution. However, the phase error is found to increase, as the grid angle decreases for a constant Courant number, and increases as Courant number increases. Copyright © 2003 John Wiley & Sons, Ltd. [source]


    Dispersion of nanoscale BaTiO3 suspensions by a combination of chemical and mechanical grinding/mixing processes

    JOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2007
    Kuo-Liang Ying
    Abstract The colloidal stability of aqueous nanometer- and micrometer-scale barium titanate (BaTiO3) utilizing poly (methacrylic acid) (PMAA-Na) and polyacrylamide/(,- N,N -dimethyl- N -acryloyloxyethyl)ammonium ethanate (PDAAE) was investigated. In addition to chemical dispersants, the effects of mechanical milling using either conventional ball milling or nanogrinding/-mixing on the dispersion of BaTiO3 suspensions were also studied. Characterization of the particle size distribution (d50), viscosity, and morphology of BaTiO3 particles in the suspensions revealed that a sole chemical dispersant or mechanical milling was insufficient to achieve nanometer-scale dispersion. The best dispersion results were obtained with a combination of PMAA-Na dispersant and nanogrinding/-mixing, which could provide sufficient electronic repulsive force and shear force to disperse the 80-nm BaTiO3 powders uniformly in the aqueous suspension. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source]