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Selected AbstractsHierarchical ZnS-In2S3 -CuS Nanospheres with Nanoporous Structure: Facile Synthesis, Growth Mechanism, and Excellent Photocatalytic ActivityADVANCED FUNCTIONAL MATERIALS, Issue 19 2010Yingxuan Li Abstract Without using any templates or surfactants, hierarchical ZnS-In2S3 -CuS nanospheres with nanoporous structure are successfully synthesized via a simple and convenient process. The nanospheres are aggregations of densely packed nanoparticles and nanorods. Different to the oriented attachment (OA) mechanism reported in the literature, the formation of these nanorods is believed to follow a lateral OA mechanism (nanoparticles attach along the direction perpendicular to the crystallographic axes with lateral planes as the juncture) based on the experimental data. This process could be a general phenomenon and would provide a new insight into the OA mechanism. A detailed time-resolved TEM kinetic study of the formation of the complex structure is shown. The dipole mechanism and electric field-induced growth are found to be responsible for the final architecture. Photocatalytic activities for water splitting are investigated under visible-light irradiation (, > 400 nm) and an especially high photocatalytic activity (apparent yield of 22.6% at 420 nm) is achieved by unloaded ZnIn0.25Cu0.02S1.395 prepared at 180 °C for 18 h because of their high crystallinity, large pore volume, and the presence of nanorods with special microstructures. [source] Out-of-plane geometrical spreading in anisotropic mediaGEOPHYSICAL PROSPECTING, Issue 4 2002Norman Ettrich Two-dimensional seismic processing is successful in media with little structural and velocity variation in the direction perpendicular to the plane defined by the acquisition direction and the vertical axis. If the subsurface is anisotropic, an additional limitation is that this plane is a plane of symmetry. Kinematic ray propagation can be considered as a two-dimensional process in this type of medium. However, two-dimensional processing in a true-amplitude sense requires out-of-plane amplitude corrections in addition to compensation for in-plane amplitude variation. We provide formulae for the out-of-plane geometrical spreading for P- and S-waves in transversely isotropic and orthorhombic media. These are extensions of well-known isotropic formulae. For isotropic and transversely isotropic media, the ray propagation is independent of the azimuthal angle. The azimuthal direction is defined with respect to a possibly tilted axis of symmetry. The out-of-plane spreading correction can then be calculated by integrating quantities which describe in-plane kinematics along in-plane rays. If, in addition, the medium varies only along the vertical direction and has a vertical axis of symmetry, no ray tracing need be carried out. All quantities affecting the out-of-plane geometrical spreading can be derived from traveltime information available at the observation surface. Orthorhombic media possess no rotational symmetry and the out-of-plane geometrical spreading includes parameters which, even in principle, are not invertible from in-plane experiments. The exact and approximate formulae derived for P- and S-waves are nevertheless useful for modelling purposes. [source] Mobility of shear thinning viscous drops in a shear Newtonian carrying flow using DR-BEMINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 12 2009M. Giraldo Abstract The study of drop behaviour has attracted great interest in the last years due to its importance in different industrial and biological systems. Most available works focus on Newtonian drops, excluding some very important applications such as polymer mixing. Simulations of non-Newtonian drops have had only limited study, mostly in time-dependent rheologies or simple flow cases. This work presents a boundary-only formulation based on the dual reciprocity method to model the motion and deformation of non-Newtonian shear thinning drops due to a shear Newtonian unbounded carrying flow. Pair-wise interactions at low Reynolds number between two viscous shear thinning non-Newtonian drops are numerically simulated in order to obtain mobility magnitudes under linear shear flow of different strengths. Separation of the drops in the direction perpendicular to the imposed flow field at high capillary number (small surface tension) and low viscosity ratio was favoured by shear thinning, increasing in magnitude as the capillary number increases and the viscous ratio decreases. Higher values of this separation occur at higher values of the viscosity ratio when compared with the case of Newtonian drops. In order to obtain a good physical description of the non-Newtonian drop behaviour, while maintaining good computational performance, the non-Newtonian viscosity is made to obey the truncated power law model. Copyright © 2008 John Wiley & Sons, Ltd. [source] LES of the compressed Taylor vortex flow using a finite volume/finite element method on unstructured gridsINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 4 2006C. Le Ribault Abstract Large-eddy simulations (LES) have been performed of a compressed vortex flow undergoing transition to turbulence. The numerical method is based on a finite volume/finite element discretization of the compressible Navier,Stokes equations on unstructured grids and a Roe second-order scheme with MUSCL extrapolation. A particular attention is paid to the dissipative character of the method, controlled by a coefficient related to the upwind part of the numerical scheme, and its interference with the subgrid model. The accuracy of the method is first checked in the case of decaying homogeneous isotropic turbulence. The investigation is then directed to a plane Taylor vortex flow submitted to compression, in a direction perpendicular to the vorticity vector. This flow is unstable with respect to three-dimensional perturbations and transition to turbulence is observed if the Reynolds number is large enough. The numerical method is used to simulate this vortex flow for two values of the Reynolds number. For the lower value, the flow is unstable but remains laminar and no subgrid model is used. For the higher one, the turbulence appears and the standard and the dynamic Smagorinsky models are tested. The LES results are compared to those obtained by direct numerical simulations (DNS) using a spectral Fourier method. Copyright © 2006 John Wiley & Sons, Ltd. [source] Effect of processing variables on texture development in a mica-based glass,ceramicJOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 2 2003I. L. Denry Abstract The purpose of this study was primarily to determine the feasibility of heat-pressing a mica-based glass,ceramic with the use of commercially available dental equipment, and secondly to evaluate the effect of various processing variables on the degree of crystal alignment in the pressed glass,ceramic. The hypotheses were that the mica-based glass,ceramic could be successfully heat-pressed and that some degree of crystal orientation would be obtained, depending on the processing variables. The glass composition was melted at 1400 °C for 2 h and cast into 12 × 60-mm rods. Ingots (10 × 12 mm) were cut from the glass rods, heat treated, and heat-pressed under various conditions. The microstructure of the pressed specimens was investigated by SEM and compared to that of heat-treated controls. The length of Vickers-induced cracks was measured on heat-pressed specimens and heat-treated controls. The results showed that mica-based glass-ceramics could be successfully pressed with the use of commercially available dental equipment. The resulting degree of crystal alignment (texture) along the direction of pressing varied between 35 ± 6 and 79 ± 6. There was a linear relationship between the degree of texture and the apparent aspect ratio of the mica platelets. A significant decrease in the length of the Vickers-induced cracks in the direction perpendicular to pressing was observed, associated with an increase in length in the direction of pressing. © 2002 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 64B: 70,77, 2002 [source] Three-dimensional visualization of the inner structure of single crystals by step-scanning white X-ray section topographyJOURNAL OF SYNCHROTRON RADIATION, Issue 6 2006Taihei Mukaide Visualization of the three-dimensional distribution of the crystal defects of large single crystals of calcium fluoride has been demonstrated by white X-ray section topography using sheet-like X-rays (BL28B2 at SPring-8). An image of the three-dimensional distribution of the crystal defects was reconstructed by stacking section topographs, which expressed the images of cross sections of the sample. The section topographs were recorded using a CMOS flat-panel imager or a CCD detector combined with scintillator (Gd2O2S:Tb) and relay lens system. The section topographs were measured by repeating cycles of exposure and sample translation along the direction perpendicular to the top face of the sample. Using high-brilliance and high-energy white X-rays (,60,keV) efficiently, visualization of the three-dimensional structure of subgrains of a sample of up to 60,mm in diameter was achieved. Furthermore, the three-dimensional distribution of the glide plane in the crystal was visualized by reconstructing the linear contrast of the glide plane. [source] Thoracic epidural catheters via the caudal and lumbar approaches using styletted multiple port catheters in pediatric patients: a report of three casesACTA ANAESTHESIOLOGICA SCANDINAVICA, Issue 4 2006B. C. H. Tsui Advancing catheters from the lumbar and caudal epidural spaces to the thoracic level has been reported to be an alternative to the direct thoracic approach. However, as children grow, the threading of catheters in the epidural space becomes increasingly difficult. This report describes three cases of thoracic epidural placement using a multiport catheter threaded from the caudal and lumbar spaces using electrical stimulation guidance. In the first case, a multiport catheter was threaded 22 cm from the lumbar space to T8 following a failed attempt with a single-port catheter in a 9-year-old boy scheduled to undergo a right nephrectomy. In the second case, a multiport catheter was threaded 26 cm from the caudal space to T9 in a 3-year-old girl undergoing fundoplication. In the last case, a multiport catheter was inserted at the completion of a fundoplication in a 2-year-old girl after it had been confirmed that the single-port catheter inserted prior to surgery had not advanced to the desired thoracic level. The multiport catheter was threaded 17 cm without resistance from the caudal space to T9. In all cases, electrical stimulation was used to confirm the location of the catheter tip at the time of insertion. The position of the catheters was later confirmed by X-ray. The multiport catheter incorporates a stylet, which extends to a closed distal tip, within a catheter body that ejects fluid from three lateral holes in a direction perpendicular to the advancing catheter. These properties may facilitate the reliable advancement of catheters in the epidural space. [source] Magnon energy gap and the magnetically structural symmetry in a three-layer ferrimagnetic superlatticePHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 8 2006Rong-ke Qiu Abstract The magnon energy band in a ferrimagnetic superlattice with three layers in a unit cell is studied by employing retarded Green's functions and the spin-wave method. Two modulated energy gaps ,,13 and ,,23 are evaluated systematically, which exist in the magnon energy band along the Kx -direction perpendicular to the plane of the superlattice. It is revealed that the energy gap ,,13 has a direct relation with the symmetry among the spin quantum numbers and the interlayer exchange couplings, while the energy gap ,,23 relates to the symmetry among these spin quantum numbers only. These symmetries differ from the symmetry of crystallographic point groups. We define the magnetically structural symmetry that is dominated mainly by the magnetic parameters. The absence of the energy gap at a certain condition means that the system has a high magnetically structural symmetry. The magnetically structural symmetry of the superlattice, which is an intrinsic property, strongly affects the magnon energy band structure and thus the magnetic behaviors of the system. Furthermore, two complete bandgaps are observed to extend through the Brillouin zone (referred to as "magnonic crystal") in this superlattice system. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Spontaneous and stimulated emission in InAs LEDs with cavity formed by gold anode and semiconductor/Air interfacePHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 2 2005B. Matveev Abstract The paper presents results on spectral and power measurements in InAsSbP/InAs double heterostructure flip-chip LEDs with cavity formed by bottom anode mirror and air/semiconductor interface in the temperature range of 77,573 K. Data on near and far field patterns in the 3 µm range together with the threshold characteristincs of the L-I curves are discussed with respect to resonant cavity effects at 77,573 K and stimulated emission at 77 K in the direction perpendicular to the p-n junction. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Phototropic bending of non-elongating and radially growing woody stems results from asymmetrical xylem formationPLANT CELL & ENVIRONMENT, Issue 5 2007JUN MATSUZAKI ABSTRACT Active phototropic bending of non-elongating and radially growing portion of stems (woody stems) has not been previously documented, whereas negative gravitropic bending is well known. We found phototropic bending in woody stems and searched for the underlying mechanism. We inclined 1-year-old Quercus crispula Blume seedlings and unilaterally illuminated them from a horizontal direction perpendicular to (,normal' illumination) or parallel to (,parallel' illumination) the inclination azimuth. With normal illumination, active phototropic bending and xylem formation could be evaluated separately from the negative gravitropic response and vertical deflection resulting from the weight of the seedlings. One-year-old stems with normal illumination bent significantly, with asymmetrical xylem formation towards the illuminated upper surface and side of the stem, whereas those with parallel illumination showed non-significant lateral bending, with asymmetrical xylem formation only on the upper side. A mechanical model was built on the assumption that a bending moment resulted from the asymmetrical xylem formation during phototropic bending of the woody stems. The model fitted the relationship between the observed spatial distributions of the xylem and the observed lateral bending, and thus supported the hypothesis that phototropic bending of woody stems results from asymmetrical xylem formation, as such occurs during gravitropism. [source] Metal enrichment of the intracluster medium: SN-driven galactic windsASTRONOMISCHE NACHRICHTEN, Issue 9-10 2009V. Baumgartner Abstract We investigate the role of supernova (SN)-driven galactic winds in the chemical enrichment of the intracluster medium (ICM). Such outflows on galactic scales have their origin in huge star forming regions and expel metal enriched material out ofthe galaxies into their surroundings as observed, for example, in the nearby starburst galaxy NGC 253. As massive stars in OB-associations explode sequentially, shock waves are driven into the interstellar medium (ISM) of a galaxy and merge, forming a superbubble (SB). These SBs expand in a direction perpendicular to the disk plane following the density gradient of the ISM. We use the 2D analytical approximation by Kompaneets (1960) to model the expansion of SBs in an exponentially stratified ISM. This is modified in order to describe the sequence of SN-explosions as a time-dependent process taking into account the main-sequence life-time of the SN-progenitors and using an initial mass function to get the number of massive stars per mass interval. The evolution of the bubble in space and time is calculated analytically, from which the onset of Rayleigh-Taylor instabilities in the shell can be determined. In its further evolution, the shell will break up and high-metallicity gas will be ejected into the halo ofthe galaxy and even into the ICM. We derive the number of stars needed for blow-out depending on the scale height and density ofthe ambient medium, as well as the fraction of alpha- and iron peak elements contained in the hot gas. Finally, the amount of metals injected by Milky Way-type galaxies to the ICM is calculated confirming the importance ofthis enrichment process (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Crystallization and preliminary X-ray analysis of clade I catalases from Pseudomonas syringae and Listeria seeligeriACTA CRYSTALLOGRAPHICA SECTION D, Issue 8 2001Xavier Carpena Haem-containing catalases are homotetrameric molecules that degrade hydrogen peroxide. Phylogenetically, the haem-containing catalases can be grouped into three main lines or clades. The crystal structures of seven catalases have been determined, all from clades II and III. In order to obtain a structure of an enzyme from clade I, which includes all plant, algae and some bacterial enzymes, two bacterial catalases, CatF from Pseudomonas syringae and Kat from Listeria seeligeri, have been crystallized by the hanging-drop vapour-diffusion technique, using PEG and ammonium sulfate as precipitants, respectively. Crystals of P. syringae CatF, with a plate-like morphology, belong to the monoclinic space group P21, with unit-cell parameters a = 60.6, b = 153.9, c = 109.2,Å, , = 102.8°. From these crystals a diffraction data set to 1.8,Å resolution with 98% completeness was collected using synchrotron radiation. Crystals of L. seeligeri Kat, with a well developed bipyramidal morphology, belong to space group I222 (or I212121), with unit-cell parameters a = 74.4, b = 121.3, c = 368.5,Å. These crystals diffracted beyond 2.2,Å resolution when using synchrotron radiation, but presented anisotropic diffraction, with the weakest direction perpendicular to the long c axis. [source] Evaluation of electroosmotic drag coefficient of water in hydrated sodium perfluorosulfonate electrolyte polymerJOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 9 2009Liuming Yan Abstract The electroosmotic drag coefficient of water molecules in hydrated sodium perfluorosulfonate electrolyte polymer is evaluated on the basis of the velocity distribution functions of the sodium cations and water molecules with an electric field applied using molecular dynamics simulations. The simulation results indicate that both velocity distribution functions of water molecules and of sodium cations agree well with the classic Maxwellian velocity distribution functions when there is no electric field applied. If an electric field is applied, the distribution functions of velocity component in directions perpendicular to the applied electric field still agree with the Maxwellian velocity distribution functions but with different temperature parameters. In the direction of the applied electric field, the electric drag causes the velocity distribution function to deviate from the Maxwellian velocity distribution function; however, to obey the peak shifted Maxwellian distribution function. The peak shifting velocities coincide with the average transport velocities induced by the electric field, and could be applied to the evaluation of the electroosmotic drag coefficient of water. By evaluation of the transport velocities of water molecules in the first coordination shells of sodium cations, sulfonate anion groups, and in the bulk, it is clearly shown that the water molecules in the first coordination shell of sodium cations are the major contribution to the electroosmotic drag and momentum transfer from water molecules within the first coordination shell to the other water molecules also contributes to the electroosmotic drag. © 2008 Wiley Periodicals, Inc. J Comput Chem 2009 [source] The coordination polymers poly[,-4,4,-bipyridyl-di-,-formato-copper(II)] and catena -poly[[[diaqua(1-benzofuran-2,3-dicarboxylato)copper(II)]-,-1,2-di-4-pyridylethane] dihydrate]ACTA CRYSTALLOGRAPHICA SECTION C, Issue 5 2009Rajesh Koner The title compounds, [Cu(CHO2)2(C10H8N2)]n, (I), and {[Cu(C10H4O5)(C12H12N2)(H2O)2]·2H2O}n, (II), are composed of one-dimensional linear coordination polymers involving copper(II) ions and bidentate bipyridyl species. In (I), the polymeric chains are located on twofold rotation axes at (x, x, 0) and are arranged in layered zones centered at z = 0, , ½ and parallel to the ab plane of the tetragonal crystal. Weak coordination of the formate anions of one layer to the copper centers of neighboring layers imparts a three-dimensional connectivity to this structure. In (II), the polymeric chains propagate parallel to the a axis of the crystal. Noncoordinated water molecules link the chains through O,H...O hydrogen bonding in directions perpendicular to c, imparting to the entire structure three-dimensional connectivity. The metal ions adopt distorted octahedral and square-based pyramidal environments in (I) and (II), respectively. This study indicates that, under the given conditions, extended coordination involves CuII centers associating with the bipyridyl ligands rather than with the competing benzofurandicarboxylate entities. [source] | ||||||||||||||||