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Different Yield (different + yield)

Distribution by Scientific Domains

Chemistry	40%

Selected Abstracts

Comparison of Structural and Chemical Properties of Black and Red Human Hair Melanosomes,

PHOTOCHEMISTRY & PHOTOBIOLOGY, Issue 1 2005
Yan Liu
ABSTRACT Melanosomes in black and red human hair are isolated and characterized by various chemical and physical techniques. Different yields of 4-amino-hydroxyphenolanaline by HI hydrolysis (a marker for pheomelanin) and pyrrole-2,3,5-tricarboxylic acid by KMnO4/H+ oxidation (a marker for eumelanin) indicate that the melanosomes in black hair are eumelanosomes, whereas those in red hair are mainly pheomelanosomes. Atomic force microscopy reveals that eumelanosomes and pheomelanosomes have ellipsoidal and spherical shapes, respectively. Eumelanosomes maintain structural integrity upon extraction from the keratin matrix, whereas pheomelanosomes tend to fall apart. The black-hair eumelanosomes have an average of 14.6 ± 0.5% amino acids content, which is attributed to the internal proteins entrapped in the melanosomes granules. The red-hair melanosomes contain more than 44% of amino acid content even after extensive proteolytic digestion. This high content of amino acids and the poorly reserved integrity of red-hair melanosomes suggest that some proteins are possibly covalently bonded with the melanin constituents in addition to those that are entrapped inside the melanin species. Soluene solubilization assay indicates the absorbance of melanin per gram of sample, adjusted for the amino acid content, is a factor of 2.9 greater for the black-hair melanosomes than the red-hair melanosomes. Metal analysis reveals significant amounts of diverse heavy metal ions bound to the two types of melanosomes. The amount of Cu(II) and Zn(II) are similar but Fe(III) content is four times higher in the red-hair melanosomes. 13C solid-state nuclear magnetic resonance spectra and infrared spectra are presented and are shown to be powerful techniques for discerning differences in the amino acid contents, the 5,6-dihydroxyindole-2-carboxylic acid:5,6-dihydroxyindole ratio, and the degree of cross-linking in the pigment. Excellent agreement is observed between these spectral results and the chemical degradation data. [source]

Fatigue performance of metallic reverse-bent joints

FATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 9 2009
G. FESSEL
ABSTRACT Adhesively bonded lap shear joints have been investigated widely and several ideas have been proposed for improving joint strength by reducing bondline stress concentrations. These include application of adhesive fillets at the overlap ends and use of adhesive with graded properties in the overlap area. Another, less common, approach is to deform the substrates in the overlap area in order to obtain a more desirable bondline stress distribution. Previous work carried out by the authors on a number of different substrate materials indicated that a reverse-bent joint geometry is useful for increasing joint strength. Results from static stress analysis and experimental testing demonstrated that significant improvements could be achieved. This paper presents results of further work carried out to assess the fatigue performance of reverse-bent joints. Substrates with different yield and plastic deformation characteristics were used and the effects of different overlap lengths on strength were examined. The results of this research show that the improvements obtained under static tests conditions translate to even higher benefits in fatigue. The paper also explains the failure mechanism of the joints under fatigue loading. [source]

Yield Responsiveness in Two- and Six-Rowed Barley Grown in Contrasting Nitrogen Environments

JOURNAL OF AGRONOMY AND CROP SCIENCE, Issue 3 2006
S. Arisnabarreta
Abstract Two- and six-rowed barley with different intrinsic ability to produce tillers and kernels per ear, would differ in responsiveness to nitrogen availability with environmental improvements. Two field experiments were carried out to elucidate how nitrogen supply (N40 and N150) affects yield and its components in two- and six-rowed barley. High nitrogen increased aboveground dry matter at anthesis, by improving cumulative solar radiation intercepted by the crop, determining an increased dry-matter production at maturity without changes in harvest index. In both barley types, variations in grain yield were explained by changes in kernels per unit land area rather than by differences in the average kernel weight. However, changes in the number of kernels were due to variations in the number of ears per m2 in two-rowed barley and the number of kernels per ear in six-rowed barley. Ears per unit area showed a greater responsiveness in two- than in six-rowed barley due to a higher nitrogen supply treatment, associated with their intrinsic higher tillering capacity, while the number of kernels per ear was more responsive in six- than in two-rowed types. The fact that responses to nitrogen by the number of kernels per unit land area in two- and six-rowed barley is better explained by different yield sub-components, allows the speculation that the critical period for yield determination would differ between barley types. [source]

Solid-State Adducts between C60 and Decamethylferrocene

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 6 2003
Aldo Arrais
Abstract Co-deposition from concentrated solutions of C60 and Fe[C5(CH3)5]2 affords two solid products in different yields. The major product 1, in the form of regular shaped crystals, has been investigated by X-ray diffraction, 13C CPMAS NMR and vibrational spectroscopy, which showed it to be a co-crystalline adduct of C60 and Fe[C5(CH3)5]2 with no significant electron charge transfer between the two building blocks. The minor product 2, in the form of an amorphous powder, has been investigated by vibrational techniques. Both IR and Raman spectra are consistent with a solid structure in which electron transfer between the two units appears to be possible. ((© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source]

Photosensitization and the Photocurrent Switching Effect in Nanocrystalline Titanium Dioxide Functionalized with Iron(II) Complexes: A Comparative Study

CHEMISTRY - A EUROPEAN JOURNAL, Issue 20 2007
Wojciech Macyk Dr.
Abstract Selected iron(II) complexes (ferrocene, ferrocenylboronic acid, hexacyanoferrate(II)) have been used as photosensitizers of titanium dioxide. Various types of electronic interactions between the surface complex and the semiconducting support are reflected in different yields of photocurrent generated upon visible-light irradiation and different efficiencies of the photosensitization effect. The studied systems, showing the photocurrent switching upon changes of electrode potential and energy of photons (the PEPS effect), are good models of simple photoelectrochemical logic devices. The mechanism of photosensitization and photocurrent switching is discussed with respect to the type of surface-complex,support interaction. Quantum-mechanical calculations support the proposed mechanisms. Wybrane kompleksy ,elaza(II) (ferrocen, kwas ferrocenyloboronowy i heksacyjano,elazian(II)) zosta,y u,yte jako fotosensybilizatory dwutlenku tytanu. Ró,ne typy oddzia,ywa, elektronowych pomi,dzy kompleksami powierzchniowymi a pod,o,em pó,przewodnikowym znajduj, odbicie w ró,nych wydajno,ciach generacji fotopr,du i ró,nym stopniu fotosensybilizacji materia,ów na ,wiat,o widzialne. Wszystkie badane uk,ady wykazuj, efekt fotoelektrochemicznego prze,,czenia fotopr,du na skutek zmian potencja,u fotoelektrody i zmian d,ugo,ci fali ,wiat,a padaj,cego (efekt PEPS), dlatego te, stanowi, bardzo dobre modele prostych prze,,czników fotoelektrochemicznych. Niniejsza praca szczegó,owo okre,la mechanizm fotosensybilizacji i prze,,czenia fotopr,du na podstawie analizy oddzia,ywa, pomi,dzy kompleksem a powierzchni, pó,przewodnika. Obliczenia kwantowo-mechaniczne potwierdzaj, postulowany mechanizm. [source]