Home About us Contact | |||
Diastereoselective Aldol Reactions (diastereoselective + aldol_reaction)
Selected AbstractsDiastereoselective Aldol Reaction of N,N-Dibenzyl-,-amino Aldehydes with Ketones Catalyzed by Proline.CHEMINFORM, Issue 30 2004Qiangbiao Pan Abstract For Abstract see ChemInform Abstract in Full Text. [source] Catalytic Enantio- and Diastereoselective Aldol Reactions of Glycine-Derived Silicon Enolate with Aldehydes: An Efficient Approach to the Asymmetric Synthesis of anti-,-Hydroxy-,-Amino Acid Derivatives.CHEMINFORM, Issue 47 2004Jun Kobayashi No abstract is available for this article. [source] Diastereoselective Aldol Reactions of Furaldehyde Using a Chiral Boronate as Auxiliary: Application to the Synthesis of Enantiomerically Pure and Highly Functionalized 2,3-Disubstituted Furanyl Alcohols.CHEMINFORM, Issue 19 2003Kin-Fai Chan Abstract For Abstract see ChemInform Abstract in Full Text. [source] Synthesis of Monocyclic and Bicyclic Imino SugarsEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 17 2003Markus Kummeter Abstract A diastereoselective aldol reaction between the chelated alanine ester enolate 5 and the protected threose derivative 6, followed by cyclization under Mitsunobu conditions, gave the pipecolinic acid derivative 9. This compound could easily be converted into the versatile protected derivative 11, which could be transformed in excellent yields either into the corresponding piperidine imino sugar 14 or into the unnatural amino acid 17. The imino alcohol 13, an intermediate in the synthesis of imino sugar 14, was also used in a straightforward approach to indolizidinone 19, involving an intramolecular Horner,Emmons reaction for ring-closure. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source] |