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Dimethyl Disulfide (dimethyl + disulfide)
Selected AbstractsSilicone oil: An effective absorbent for the removal of hydrophobic volatile organic compoundsJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 3 2010Guillaume Darracq Abstract BACKGROUND: Hydrophobic volatile organic compounds (VOCs), such as toluene, dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), are poorly soluble in water and classical air treatment processes like chemical scrubbers are not efficient. An alternative technique involving an absorption step in an organic solvent followed by a biodegradation phase was proposed. The solvent must fulfil several characteristics, which are key factors of process efficiency, and a previous study allowed polydimethylsiloxane (or PDMS, i.e. silicone oil) to be selected for this purpose. The aim of this paper was to determine some of its characteristics like absorption capacity and velocity performances (Henry's constant, diffusivity and mass transfer coefficient), and to verify its non-biodegradability. RESULTS: For the three targeted VOCs, Henry's constants in silicone oil were very low compared to those in water, and solubility was infinite. Diffusivity values were found to be in the range 10,10 to 10,11 m2 s,1 and mass transfer coefficients did not show significant differences between the values in pure water and pure silicone oil, in the range 1.0 × 10,3 to 4.0 × 10,3 s,1 for all the VOCs considered. Silicone oil was also found to be non-biodegradable, since its biological oxygen demand (BOD5) value was zero. CONCLUSION: Absorption performances of silicone oil towards toluene, DMS and DMDS were determined and showed that this solvent could be used during the first step of the process. Moreover, its low biodegradability and its absence of toxicity justify its use as an absorbent phase for the integrated process being considered. Copyright © 2010 Society of Chemical Industry [source] Changes of Headspace Volatiles in Milk with Riboflavin PhotosensitizationJOURNAL OF FOOD SCIENCE, Issue 7 2009J.H. Lee ABSTRACT:, Effects of fluorescent light, riboflavin, ascorbic acid, sodium azide, and butylated hydroxyanisole (BHA) on the volatiles in milk at 4 °C were determined using a combination of headspace-solid phase microextraction (HS-SPME), gas chromatography (GC), and mass spectrometry (MS). Pentanal, hexanal, heptanal, and dimethyl disulfide were formed only in the milk stored under light and increased significantly as the duration of light exposure increased from 0 to 8 h and the concentration of added riboflavin increased from 5 to 50 ppm (P,< 0.05). As fat content in milk increased, peak areas of pentanal, hexanal, and heptanal increased significantly (P,< 0.05) while those of dimethyl disulfide did not change significantly (P,> 0.05). Sodium azide prevented the formation of dimethyl disulfide in milk, implying that dimethyl disulfide can be formed through singlet oxygen oxidation (type II pathway). Addition of ascorbic acid and BHA reduced the formation of hexanal, heptanal, and dimethyl disulfide significantly (P,< 0.05). Generation mechanisms of pentanal seem to be different from those of hexanal and heptanal in milk. Both singlet oxygen oxidation (type II pathway) and free radicals (type I pathway) play important roles in the formation of light-induced volatiles in milk. [source] Antioxidant Properties of Far Infrared-treated Rice Hull Extract in Irradiated Raw and Cooked Turkey BreastJOURNAL OF FOOD SCIENCE, Issue 6 2003S.-C. Lee ABSTRACT: The antioxidant effect of far infrared-treated rice hull (FRH) extracts in irradiated turkey breast meat was compared with that of sesamol and rosemary oleoresin. The FRH extracts significantly decreased thiobarbituric acid-reactive substances values and volatile aldehydes (hexanal, pentanal, and propanal) and was effective in reducing the production of dimethyl disulfide responsible for irradiation off-odor in irradiated raw and cooked turkey meat during aerobic storage. The antioxidant activity of FRH extracts (0.1%, wt/wt) was as effective as that of rosemary oleoresin (0.1%). However, the addition of FRH extracts increased red and yellow color intensities and produced an off-odor characteristic to rice hull in raw and cooked meat. [source] Volatile Organic Compounds from Arctic Bacteria of the Cytophaga-Flavobacterium-Bacteroides Group: A Retrobiosynthetic Approach in Chemotaxonomic InvestigationsCHEMISTRY & BIODIVERSITY, Issue 3 2005Jeroen Volatile organic compounds emitted by different marine arctic strains of the Cytophaga-Flavobacterium-Bacteroides group were investigated by using a modified closed-loop stripping apparatus (CLSA). Seven of nine strains emitted volatiles, dominated by methyl ketones, in specific patterns. The methyl ketones were aliphatic saturated, or unsaturated, and comprised 12 to 18 C-atoms, sometimes with terminal Me branches. They were identified by GC/MS, retention-index calculations, derivatization with dimethyl disulfide for CC bond location, and GC/FTIR to elucidate their uniform (Z)-configuration. The proposed structures of all methyl ketones were subsequently confirmed by synthesis, while the absolute configuration of chiral volatiles was elucidated by stereoselective synthesis. From retrobiosynthetic considerations, it was found that strain ARK10267 uses mainly valine, and strain ARK10063 mainly isoleucine for formation of starters for the ketone biosynthesis, which is correlated to fatty acid biosynthesis. Four strains (ARK10223, ARK10044, ARK10141, and ARK10146) use leucine. These separations are supported by phylogenetic affiliations based on 16S rRNA. Strain ARK10255b, in the course of this study found to be not a member of the Cytophaga-Flavobacterium-Bacteroides phylum, did not emit aliphatic ketones of medium chain length, but methionine-derived 4-(methylsulfanyl)butan-2-one and corresponding 4-(methylsulfanyl)butan-2-ol. Most of the compounds described have not been reported previously from nature. [source] | ||||||||||