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Device Properties (device + property)
Selected AbstractsSynthesis, Photophysical, and Electroluminescent Device Properties of Zn(II)-Chelated Complexes Based on Functionalized Benzothiazole DerivativesADVANCED FUNCTIONAL MATERIALS, Issue 10 2009Soo-Gyun Roh Abstract New Zn(II)-chelated complexes based on benzothiazole derivatives, including substituted functional groups such as methyl (MeZn), methoxy (MeOZn), or fluorenyl unit (FuZn), are investigated to produce white-light emission. 2-(2-Hydroxyphenyl)benzothiazole derivatives in toluene and DMSO exhibit excited-state intramolecular proton transfer (ESIPT), leading to a large Stokes shift of the fluorescence emission. However, in methanol they exhibit no ESIPT due to the intermolecular hydrogen bonding between the 2-(2-hydroxyphenyl)benzothiazole derivative and methanol. Their Zn(II)-chelated complexes exhibit the absorption band red-shifted at 500,nm in nonpolar solvent and the absorption band blue-shifted at about 420,nm in protic solvent. In multilayer electroluminescent devices, methyl-substituted Zn(II)-chelated complex (MeZn) exhibits excellent power efficiency and fluorene-substituted Zn(II)-chelated complex (FuZn) has a high luminance efficiency (1,cd,m,2 at 3.5,V, 10,400,cd,m,2 at 14,V). The EL spectra of Zn(II)-chelated complexes based on benzothiazole derivatives exhibit broad emission bands. In addition, their electron-transport property for red,green,blue (RGB) organic light-emitting diodes (OLEDs) is systematically studied, in comparison with that of Alq3. The results demonstrate the promising potential of MeZn as an electron-transporting layer (ETL) material in preference to Alq3, which is widely used as an ETL material. [source] Induced Sensitivity and Selectivity in Thin-Film Transistor Sensors via Calixarene LayersADVANCED MATERIALS, Issue 21 2010Anatoliy N. Sokolov Sensors based on organic field-effect transistors (OFETs) must overcome challenges in reproducibility, sensitivity, and selectivity. Here we describe an approach to increase the sensitivity and induce selectivity within an existing (OFET) through the incorporation of an evaporated sensor layer based on a calix[n]arene molecule. The mild method does not influence device properties, and is amendable to incorporation into reproducible, commercial transistors. [source] Reliability aspects of SiC Schottky diodesPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 10 2009Matthias Holz Abstract In recent years, silicon carbide (SiC) high-voltage power devices have gained an ever-increasing market share. The fast development of new device concepts and technologies, e.g. for SiC Schottky diodes, has led to devices with superior switching behaviour, which renders SiC power devices especially favourable for high-frequency applications. As of today, SiC devices enter various fields like, e.g. server power supplies, solar inverters, and drives. These applications pose quite different requirements not only on the electrical properties, but also on the long-term reliability of the devices. In this paper, we describe in detail how Infineon's SiC Schottky diodes excel the reliability requirements. We point out how material properties, device design and packaging technology affect the overall device reliability and how they can be optimized. In addition, we describe measurement results after stress tests that go far beyond standard stress tests according to JEDEC. E.g., we show that SiC devices can safely be operated at high voltage slopes of 120 V/ns. In addition, we show that the use of high performance die attach further improves the device properties and reliability. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Influence of barrier thickness on AlInN/AlN/GaN heterostructures and device propertiesPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue S2 2009H. Behmenburg Abstract We report on structural and device properties of AlInN/AlN/GaN transistor heterostructures grown by metal organic vapour phase epitaxy (MOVPE) on 2, sapphire substrates with AlInN barriers of thicknesses between 4 nm and 10 nm. The In content and thickness of the thin AlInN barrier is shown to be well determinable by high-resolution X-ray diffraction (HRXRD). Room temperature Hall measurements yielded similar mobility between 1400 cm2V,1s,1 and 1520 cm2V,1s,1 on all samples and increasing sheet carrier concentration ns with rising barrier thickness resulting in a minimum sheet resistance value of 200 Ohm/,. The effect of surface passivation with Si3N4 on the electrical properties is investigated and found to strongly increase sheet carrier concentration ns of the two-dimensional electron gas (2DEG) to values above 2×1013cm,2. Characterization of transistors with gate length Lg of 1.5 ,m produced from the grown samples reveals high transconductance (gm) and a maximum drain current (ID) of 300 mS/mm and ,1 A/mm, respectively. For the sample with 4.6 nm barrier thickness, a reduced gate leakage current (IGL) and a absolute value of the threshold voltage (Vth) of -1.2 V is detected. Radio frequency (RF) measurements of passivated samples lead to maximum current gain cut-off frequencies ft of 11 GHz and maximum oscillating frequencies fmax of 25 GHz. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] High potential of thin (<1,µm) a-Si: H/µc-Si:H tandem solar cellsPROGRESS IN PHOTOVOLTAICS: RESEARCH & APPLICATIONS, Issue 2 2010S. Schicho Abstract Silicon based thin tandem solar cells were fabricated by plasma enhanced chemical vapor deposition (PECVD) in a 30,×,30,cm2 reactor. The layer thicknesses of the amorphous top cells and the microcrystalline bottom cells were significantly reduced compared to standard tandem cells that are optimized for high efficiency (typically with a total absorber layer thickness from 1.5 to 3,µm). The individual absorber layer thicknesses of the top and bottom cells were chosen so that the generated current densities are similar to each other. With such thin cells, having a total absorber layer thickness varying from 0.5 to 1.5,µm, initial efficiencies of 8.6,10.7% were achieved. The effects of thickness variations of both absorber layers on the device properties have been separately investigated. With the help of quantum efficiency (QE) measurements, we could demonstrate that by reducing the bottom cell thickness the top cell current density increased which is addressed to back-reflected light. Due to a very thin a-Si:H top cell, the thin tandem cells show a much lower degradation rate under continuous illumination at open circuit conditions compared to standard tandem and a-Si:H single junction cells. We demonstrate that thin tandem cells of around 550,nm show better stabilized efficiencies than a-Si:H and µc-Si:H single junction cells of comparable thickness. The results show the high potential of thin a-Si/µc-Si tandem cells for cost-effective photovoltaics. Copyright © 2010 John Wiley & Sons, Ltd. [source] |