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Cubic Symmetry (cubic + symmetry)
Selected AbstractsSpherical ordered mesoporous silicas and silica monoliths as stationary phases for liquid chromatographyJOURNAL OF SEPARATION SCIENCE, JSS, Issue 6 2006Anne Galarneau Abstract Ordered mesoporous silicas such as micelle-templated silicas (MTS) feature unique textural properties in addition to their high surface area (,1000 m2/g): narrow mesopore size distributions and controlled pore connectivity. These characteristics are highly relevant to chromatographic applications for resistance to mass transfer, which has never been studied in chromatography because of the absence of model materials such as MTS. Their synthesis is based on unique self-assembly processes between surfactants and silica. In order to take advantage of the perfectly adjustable texture of MTS in chromatographic applications, their particle morphology has to be tailored at the micrometer scale. We developed a synthesis strategy to control the particle morphology of MTS using the concept of pseudomorphic transformation. Pseudomorphism was recognized in the mineral world to gain a mineral that presents a morphology not related to its crystallographic symmetry group. Pseudomorphic transformations have been applied to amorphous spherical silica particles usually used in chromatography as stationary phases to produce MTS with the same morphology, using alkaline solution to dissolve progressively and locally silica and reprecipitate it around surfactant micelles into ordered MTS structures. Spherical beads of MTS with hexagonal and cubic symmetries have been synthesized and successfully used in HPLC in fast separation processes. MTS with a highly connected structure (cubic symmetry), uniform pores with a diameter larger than 6 nm in the form of particles of 5 ,m could compete with monolithic silica columns. Monolithic columns are receiving strong interest and represent a milestone in the area of fast separation. Their synthesis is a sol-gel process based on phase separation between silica and water, which is assisted by the presence of polymers. The control of the synthesis of monolithic silica has been systematically explored. Because of unresolved yet cladding problems to evaluate the resulting macromonoliths in HPLC, micromonoliths were synthesized into fused-silica capillaries and evaluated by nano-LC and CEC. Only CEC allows to gain high column efficiencies in fast separation processes. Capillary silica monolithic columns represent attractive alternatives for miniaturization processes (lab-on-a chip) using CEC. [source] Order-Disorder Phase Transition in Type-I Clathrate Cs8Sn44,2,EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 26 2007Andreas Kaltzoglou Abstract The clathrate compound ,-Cs8Sn44,2 has been synthesized from its elements under inert gas conditions and has been characterized by single-crystal and powder X-ray diffraction. At room temperature, it crystallizes with cubic symmetry [a = 24.256(3) Å, space group Iad, Z = 8] and adopts a 2,×,2,×,2 superstructure of the type-I clathrate and a high ordering of the vacancies (,) in the Sn framework. Single crystals of ,-Cs8Sn44,2 reversibly transform at 90 °C to the high-temperature , form with primitive symmetry [a = 12.135(1) Å, space group Pmn, Z = 1] and a lower ordering of the defects. Differential thermal analysis corroborates the reversible character of the phase transition, which occurs with an enthalpy change of approximately 0.38 J,g,1. An atom-migration mechanism describing the order-disorder transition involving spiro-connected six-membered rings only (scsr mechanism) is proposed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source] Prediction of the Elastic Properties of Polycrystalline Microcomponents by Numerical HomogenizationADVANCED ENGINEERING MATERIALS, Issue 3 2009Katja Jöchen Polycrystalline microcomponents made of Stabilor®G, a dental alloy mainly consisting of gold, are examined in terms of their elastic properties. Finite element calculations of uniaxial tensile tests are carried out with ABAQUS so as to identify the characteristic parameters of the distribution of Young's modulus. It is shown that the statistics of mechanical properties observed experimentally can be estimated by using the finite element method. The findings are generalized to microcomponents consisting of crystals with a cubic symmetry. [source] Spherical ordered mesoporous silicas and silica monoliths as stationary phases for liquid chromatographyJOURNAL OF SEPARATION SCIENCE, JSS, Issue 6 2006Anne Galarneau Abstract Ordered mesoporous silicas such as micelle-templated silicas (MTS) feature unique textural properties in addition to their high surface area (,1000 m2/g): narrow mesopore size distributions and controlled pore connectivity. These characteristics are highly relevant to chromatographic applications for resistance to mass transfer, which has never been studied in chromatography because of the absence of model materials such as MTS. Their synthesis is based on unique self-assembly processes between surfactants and silica. In order to take advantage of the perfectly adjustable texture of MTS in chromatographic applications, their particle morphology has to be tailored at the micrometer scale. We developed a synthesis strategy to control the particle morphology of MTS using the concept of pseudomorphic transformation. Pseudomorphism was recognized in the mineral world to gain a mineral that presents a morphology not related to its crystallographic symmetry group. Pseudomorphic transformations have been applied to amorphous spherical silica particles usually used in chromatography as stationary phases to produce MTS with the same morphology, using alkaline solution to dissolve progressively and locally silica and reprecipitate it around surfactant micelles into ordered MTS structures. Spherical beads of MTS with hexagonal and cubic symmetries have been synthesized and successfully used in HPLC in fast separation processes. MTS with a highly connected structure (cubic symmetry), uniform pores with a diameter larger than 6 nm in the form of particles of 5 ,m could compete with monolithic silica columns. Monolithic columns are receiving strong interest and represent a milestone in the area of fast separation. Their synthesis is a sol-gel process based on phase separation between silica and water, which is assisted by the presence of polymers. The control of the synthesis of monolithic silica has been systematically explored. Because of unresolved yet cladding problems to evaluate the resulting macromonoliths in HPLC, micromonoliths were synthesized into fused-silica capillaries and evaluated by nano-LC and CEC. Only CEC allows to gain high column efficiencies in fast separation processes. Capillary silica monolithic columns represent attractive alternatives for miniaturization processes (lab-on-a chip) using CEC. [source] Nonlinear refractive index of ceramic laser media and perspectives of their usage in a high-power laser-driverLASER PHYSICS LETTERS, Issue 10 2004Yu. Senatsky Abstract At the recent years a technology of ceramic laser media on the base of crystals with a cubic symmetry has been developed. The perspective of the usage of ceramic materials in many different applications including high - power short pulse lasers stimulates the work on the systematic study of the properties of these new laser media. A nonlinear refractive index, n2 was studied for several garnet and sesquioxide laser ceramics using Z-scan method. n2 indices in the range of (2 , 6) × 10,13 were measured for YAG, Y2O3, Lu2O3, and Sc2O3 ceramic samples. These data together with the other laser and spectroscopic parameters of several Nd3+ and Yb3+ doped crystals of a cubic symmetry were used to estimate the properties of laser ceramics for the application in a high-power pulsed-repetitive laser - driver for inertial confinement fusion (ICF) program. A high heat conductivity of ceramic materials is a profitable characteristic for this application as compared to glasses, which are used now for experiments in ICF at single shots regime. Compared to single crystals, ceramic elements provide laser designers with a variety of new design options for the projects of laser-drivers. (© 2004 by ASTRO, Ltd. Published exclusively by WILEY-VCH Verlag GmbH & Co. KGaA) [source] Electron gyration modified in the magnetic field tilted to the symmetry species of a crystalline metalPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 8 2006S. Olszewski Abstract When a crystal electron is gyrating in the magnetic field being normal to the crystallographic plane, the calculation of the gyration frequency represents a relatively easy task. The paper approaches a more complicated problem of the gyration frequency in the case when the magnetic field is tilted to the crystallographic axes. The tightly-bound s-electrons in crystal lattices of cubic symmetry are considered as examples. Another problem concerns a metal plate for which the changes of the electron gyration frequency are examined as a function of the inclination angle of the magnetic field with respect to the planar boundaries of that plate. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] K2ScSn(AsO4)3: an arsenate-containing langbeiniteACTA CRYSTALLOGRAPHICA SECTION C, Issue 7 2010William T. A. Harrison The title compound, dipotassium tri-,-arsenato-scandium(III)tin(IV), is the first arsenate-containing langbeinite to be characterized by single-crystal methods and crystallizes in the aristotype P213 cubic symmetry for this structure type in which the K+ ions and the octahedral scandium and tin cations lie on crystallographic threefold axes. The ScIII and SnIV ions show a slight segregation over the two octahedral sites, with Sc/Sn populations of 0.582,(5):0.418,(5) on one site and 0.418,(5):0.582,(5) on the other. Bond-valence-sum calculations indicate that the K+ ions are significantly underbonded in this structure and the O atoms show large anisotropic displacement parameters, as also seen in other langbeinites. The crystal studied was found to be a merohedral twin with a 0.690,(16):0.310,(16) domain ratio. [source] Type II dehydroquinase: molecular replacement with many copiesACTA CRYSTALLOGRAPHICA SECTION D, Issue 1 2008Kirsty Anne Stewart Type II dehydroquinase is a small (150-amino-acid) protein which in solution packs together to form a dodecamer with 23 cubic symmetry. In crystals of this protein the symmetry of the biological unit can be coincident with the crystallographic symmetry, giving rise to cubic crystal forms with a single monomer in the asymmetric unit. In crystals where this is not the case, multiple copies of the monomer are present, giving rise to significant and often confusing noncrystallographic symmetry in low-symmetry crystal systems. These different crystal forms pose a variety of challenges for solution by molecular replacement. Three examples of structure solutions, including a highly unusual triclinic crystal form with 16 dodecamers (192 monomers) in the unit cell, are described. Four commonly used molecular-replacement packages are assessed against two of these examples, one of high symmetry and the other of low symmetry; this study highlights how program performance can vary significantly depending on the given problem. In addition, the final refined structure of the 16-dodecamer triclinic crystal form is analysed and shown not to be a superlattice structure, but rather an F -centred cubic crystal with frustrated crystallographic symmetry. [source] Crystallization and preliminary X-ray analysis of a cohesin-like module from AF2375 of the archaeon Archaeoglobus fulgidusACTA CRYSTALLOGRAPHICA SECTION F (ELECTRONIC), Issue 3 2009Milana Voronov-Goldman A cohesin-like module of 160 amino-acid residues from the hypothetical protein AF2375 of the noncellulolytic, hyperthermophilic, sulfate-reducing archaeon Archaeoglobus fulgidus was cloned, expressed, purified, crystallized and subjected to X-ray structural study in order to compare its structure with those of cellulolytic cohesins. The crystals had cubic symmetry, with unit-cell parameters a = b = c = 101.75,Å in space group P4332, and diffracted to 1.82,Å resolution. The asymmetric unit contained a single cohesin molecule. A model assembled from six cohesin structures (PDB entries 1anu, 1aoh, 1g1k, 1qzn, 1zv9 and 1tyj) of very low sequence identity to the cohesin-like module was used in molecular-replacement attempts, producing a marginal solution. [source] | |||||||||||||