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Crystalline Complexes (crystalline + complex)
Selected AbstractsAnalysis of landslide frequencies and characteristics in a natural system, coastal British ColumbiaEARTH SURFACE PROCESSES AND LANDFORMS, Issue 11 2004R. H. Guthrie Abstract Two hundred and one debris slides and debris ,ows were analyzed in a 286 km2 study area on the west coast of Vancouver Island, British Columbia, Canada. The study area remains essentially untouched by humans and therefore affords a natural setting in which to examine slope processes. Landslides were identi,ed and characterized on aerial photographs from 1:15 000 to 1:31 680, and were then mapped and transferred to a GIS for analysis. Based on detailed landslide surveys, we propose a new method to accurately determine volume of landslides of this type by measured total area. Results indicate average denudation rates of 56 m3 y,1 km,2, and higher natural rates of failure than analogous regions in coastal British Columbia. In contrast, the landslide rates are substantially less than those from forested watersheds. Landslide distribution is spatially clustered in air photograph epochs, and we propose intense storm cells within regional events as the causal mechanism. Further, failures occurred preferentially over the West Coast Crystalline Complex (by 1·4 times), a metamorphic assemblage of gabbros, schists and amphibolites, but 1·5 times less often over the Island Plutonic Suite, a granitic intrusive formation. The former result represents a new ,nding, while the latter corroborates ,ndings of previous authors. We examined magnitude,frequency relationships of the data set and present for the ,rst time a strong argument that the rollover effect is not merely an artefact, but is instead a consequence of the physical characteristics of the landslides themselves. We subsequently analyzed magnitude,frequency relationships from two other complete data sets from coastal British Columbia and produced a family of curves corroborating this result. Copyright © 2004 John Wiley & Sons, Ltd. [source] The syn-collisional Danac,obas, biotite leucogranite derived from the crustal thickening in central Anatolia (K,r,kkale), TurkeyGEOLOGICAL JOURNAL, Issue 5 2005bel Tatar Abstract The Behrekda, composite batholith, which crops out as a huge N,S-trending plutonic body in central Anatolia, Turkey, consists of five mappable granitoid units of Late Cretaceous age. They are (1) the S-type, peraluminous Danac,obas, biotite leucogranite, (2) the I-type, hybrid, metaluminous Konur K-feldspar megacrystic quartz monzonite, (3) the mafic A-type, alkaline Kizdede monzogabbro, (4) the felsic A-type, alkaline Hasandede quartz syenite/monzonite, and (5) the M-type, low-K tholeiitic Yeniköy tonalite. The S-type Danac,obas, biotite leucogranite constitutes the oldest intrusive unit in the mapped area. It has coarse- to medium-crystalline texture and consists of quartz, orthoclase and plagioclase, with variable amounts of biotite and accessory minerals, including apatite, zircon and opaque phases. K-Ar age dating of biotite separates, yields cooling ages of 69.1,±,1.42 and 71.5,±,1.45,Ma for the Danac,obas, biotite leucogranite. Major-element, trace-element, and rare-earth element geochemical data suggest an exclusively peraluminous, S-type, high-K calc-alkaline, upper crustal genesis for the Danac,obas, biotite leucogranite. This petrogenetic interpretation is also supported by oxygen-isotope data from quartz separates, with a mean value of 10.58,±,0.11 , of ,18OVSMOW value. The magma source of the Danac,obas, biotite leucogranite is proposed to have been a syn-collisional leucogranitic melt derived by anatexis of high-grade metasediments of the Central Anatolian Crystalline Complex during peak conditions of regional metamorphism. This metamorphic event was induced by crustal thickening which was a result of Late Cretaceous collision between the Eurasia and Tauride,Anatolide Platform along the ,zmir,Ankara,Erzincan Suture Zone in central Anatolia. Copyright © 2005 John Wiley & Sons, Ltd. [source] Sildenafil citrate (Viagra) complexes with bivalent ionsJOURNAL OF PHARMACEUTICAL SCIENCES, Issue 1 2006Petr Melnikov Abstract The interaction of Ca2+ -ions with sildenafil citrate (Viagra) leads to the precipitation of a new polymorph variety of sildenafil base. Under the same conditions, Mg2+, Zn2+, and Cd2+ ions form structurally related crystalline complexes of the composition Me2+C28H34N6O11S. Lattice parameters have been determined showing that magnesium compound belongs to an orthorhombic system, while the zinc and cadmium compounds are its monoclinic distortions. All three compounds are thermally stable, undergoing decomposition above 175°C with the consequent formation of carbonates Me2+CO3 and oxides. © 2005 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 95:225,227, 2006 [source] The role of specific interactions in crystalline complex formation.JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Issue 5 200210-bis(4-bromophenyl)-, 10-dihydroanthracene with dimethyl sulfoxide, 10-dihydroxy-, Structural, thermochemical analysis of inclusion compounds of cis -, trans - Abstract Referring to a crucial problem in crystal engineering and co-crystallization of host,guest complexes, whether the non-covalent supramolecular interactions existing in a pre-crystalline solution state may determine the subsequent crystal structure, the particular inclusion properties of host compounds 1, cis - and 2, trans -9,10-bis(4-bromophenyl)-9,10-dihydroxy-9,10-dihydroanthracene, with dimethyl sulfoxide (DMSO) were studied by using x-ray structure analysis and calorimetric methods. Both hosts form crystalline inclusion complexes with DMSO showing 2:3 (1·DMSO) and 1:4 (2·DMSO) host:guest composition. The crystal structure of 1·DMSO (2:3) is dominated by a strong bifurcated acceptor-type H bond interaction involving 1 and one of the DMSO molecules. Titration calorimetric investigations in solution also confirm the formation of a stable 1·DMSO (1:1) complex unit, suggesting that for crystal nuclei of 1·DMSO (2:3) the pre-formed 1:1 host,guest complex is the relevant building block while the additional molecules of DMSO fill lattice voids. In contrast, compound 2 with a trans configuration of the two hydroxy groups gives much weaker complexation with DMSO in solution, which is in agreement with single H-bond interaction, also realized in the crystal structure of the respective inclusion complex. Thermal decomposition (TG,DSC) measurements of the crystalline complexes supply supporting data for these findings. Copyright © 2002 John Wiley & Sons, Ltd. [source] X-ray studies on crystalline complexes involving amino acids and peptides.ACTA CRYSTALLOGRAPHICA SECTION B, Issue 6 2001XXXVIII. The complexes of glutaric acid with l -arginine and l -histidine (two crystal forms) exhibit different stoichiometries and ionization states. The aggregation patterns in two of the crystals are remarkably similar to those observed earlier in similar structures, while the pattern in the remaining one has not been seen earlier. The variability in the ionization state and stoichiometry observed in amino acid,dicarboxylic acid complexes appears to represent subtle differences in the response of a molecule to the presence in its neighbourhood of another type of molecule. The glutaric acid molecules (or glutarate or semiglutarate ions) in their complexes and in other crystals favour a fully extended conformation, albeit with frequent departures from it. The change in the chirality of the component molecules in the complex could lead to drastic changes in the aggregation pattern; alternatively, the effects of the change are accommodated through small adjustments in essentially the same pattern. [source] X-ray studies of crystalline complexes involving amino acids and peptides.ACTA CRYSTALLOGRAPHICA SECTION C, Issue 3 2006XLIII. The asymmetric unit of the dl -lysine complex of adipic acid [bis(dl -lysinium) adipate], 2C6H15N2O2+·C6H8O42,, contains a zwitterionic singly charged lysinium cation and half a doubly charged adipate anion (the complete anion has inversion symmetry). That of the l -lysine complex (lysinium hydrogen adipate), C6H15N2O2+·C6H9O4,, consists of a lysinium cation and a singly charged hydrogen adipate anion. In both structures, the lysinium cations organize into layers interconnected by adipate or hydrogen adipate anions. However, the arrangement of the molecular ions in the layer is profoundly different in the dl - and l -lysine complexes. The hydrogen adipate anions in the l -lysine complex form linear arrays in which adjacent ions are interconnected by a symmetric O,H,O hydrogen bond. [source] | |||||||||||||