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Corrosion Performance (corrosion + performance)
Selected AbstractsMechanical Properties and Environmental Behavior of a Magnesium Alloy with a Nano-/Sub-Micron StructureADVANCED ENGINEERING MATERIALS, Issue 9 2007E. Aghion Abstract Newly developed magnesium alloys with a consolidated nano/sub-micron structure and substantially higher specific strength may be considered as an interesting candidate for super-light high-strength applications. Consolidated nano/sub-micron structure applies to alloys with a combined microstructure of nano-crystalline and sub-micron grains. The aim of the present study was to explore the mechanical and environmental behavior of a consolidated nano/sub-micron magnesium alloy with the composition of AZ31. This was required in order to evaluate the applicability of this new structured alloy for practical applications. Although the nano/sub-micron structured alloy has more than twice the hardness and strength of the conventional alloy, its ductility and corrosion resistance were significantly lower. In addition, its stress corrosion characteristics were inferior. The significant limitation of the nano-structured alloy, in terms of ductility and corrosion performance, restricts its potential use as a structural material for practical applications. [source] Comparative corrosion performance of black oxide, sandblasted, and fine-drawn nitinol wires in potentiodynamic and potentiostatic tests: Effects of chemical etching and electropolishingJOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 2 2004Svetlana Shabalovskaya Abstract The corrosion performance of sandblasted (SB) and smooth fine-drawn (FD) medical-use nitinol wires was compared with the performance of wires with black oxide (BO) formed in air during their manufacture. Potentiodynamic and ASTM F746 potentiostatic tests in a 0.9 % NaCl solution were conducted on wires in their as-received, chemically etched, aged in boiling water, and electropolished states. As-received wires with various surface finishes revealed breakdown potentials in the range from ,100 mV to +500 mV; similar passive current density, 10,6 A/cm2; and a wide hysteresis on the reverse scan, demonstrating strong susceptibility to localized corrosion. Chemically etched wires with original black oxide displayed consistent corrosion performance and surpassed, in corrosion resistance, electropolished wires that showed significantly lower breakdown (400,700 mV) and localized corrosion potentials (,,50 to +113 mV). Sandblasted and fine-drawn wires exhibited rather inconsistent corrosion behavior. In potentiodynamic tests these wires could perform with equal probability either on the level of pretreated BO wires or rather similar to as-received wires. Both SB and FD wires revealed low breakdown potentials in the PS regime. SEM analysis performed before tests indicated that sandblasting was not efficient for the complete removal of the original scaling, and fine drawing aggravated the situation, resulting in a persistent scaling that contributed to the inferior corrosion performance. Inclusions (oxides, carbides, and oxidized carbides) inherited from the bulk and retained on electropolished surfaces are the cause of their inferior performance compared to chemically etched surfaces. In electropolished wires corrosion was initiated around inclusions. © 2004 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 69B: 223,231, 2004 [source] Effect of thermal exposure on the microstructure, tensile properties and the corrosion behaviour of 6061 aluminium alloy sheetMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 3 2005R. Braun Abstract Sheet material of the Al-Mg-Si alloy 6061 in the tempers T4 and T6 was thermally exposed at temperatures ranging from 85 to 120°C for 1000 h. The microstructure, tensile properties and the corrosion behaviour in the different heat treatment conditions were investigated using differential scanning calorimetry and transmission electron microscopy as well as performing tensile tests and various corrosion tests. The additional heat treatments, which should simulate aging during long-term service usage, caused an increase in strength of 6061-T4 sheet, associated with changes in the naturally aged microstructure. Thermal exposure at 120°C for 1000 h resulted in tensile and corrosion properties being similar to those obtained for peak-aged sheet. Alloy 6061 in the T6 temper exhibited microstructural stability when additionally heat treated at 85 and 120°C for 1000 h. No significant alterations in the microstructure, tensile properties, and corrosion performance were observed after exposure to slightly elevated temperatures. [source] Corrosion of magnesium alloys in commercial engine coolantsMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 1 2005G. Song Abstract A number of magnesium alloys show promise as engine block materials. However, a critical issue for the automotive industry is corrosion of the engine block by the coolant and this could limit the use of magnesium engine blocks. This work assesses the corrosion performance of conventional magnesium alloy AZ91D and a recently developed engine block magnesium alloy AM-SC1 in several commercial coolants. Immersion testing, hydrogen evolution measurement, galvanic current monitoring and the standard ASTM D1384 test were employed to reveal the corrosion performance of the magnesium alloys subjected to the coolants. The results show that the tested commercial coolants are corrosive to the magnesium alloys in terms of general and galvanic corrosion. The two magnesium alloys exhibited slightly different corrosion resistance to the coolants with AZ91D being more corrosion resistant than AM-SC1. The corrosivity varied from coolant to coolant. Generally speaking, an organic-acid based long life coolant was less corrosive to the magnesium alloys than a traditional coolant. Among the studied commercial coolants, Toyota long life coolant appeared to be the most promising one. In addition, it was found that potassium fluoride effectively inhibited corrosion of the magnesium alloys in the studied commercial coolants. Both general and galvanic corrosion rates were significantly decreased by addition of KF, and there were no evident side effects on the other engine block materials, such as copper, solder, brass, steel and aluminium alloys, in terms of their corrosion performance. The ASTM D 1384 test further confirmed these results and suggested that Toyota long life coolant with 1%wt KF addition is a promising coolant for magnesium engine blocks. [source] Influence of testing parameters on the corrosion rate of magnesium alloysMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 6 2004M. Kühlein Abstract In sodium chloride solutions alloy composition, phases, microstructure and grain size influence the corrosion behaviour of magnesium alloys. Concentration and distribution of the critical impurities iron, nickel and copper affect the corrosion performance strongly. Salt spray tests according to ASTM B 117 or DIN 50021 are used to control quality of magnesium alloys. Results of these tests often estimate alloy subcontractors and are therefore very important to placing. Standards specify test solution, test temperature and position of specimens during test in the salt spray chamber. Standards not prescribe preparation of test specimens, exposure period, handling of the specimens after salt spray test nor the interpretation of the results. Results of salt spray tests can be only compared, provided that test conditions are exactly given. Whether the standards fulfil the above described criteria, will be shown by extensive investigations. Therefore the influence of exposure period, surface condition and microstructure was investigated. [source] Influence of microstructural changes on corrosion behaviour of thermally aged Ti-6Al-7Nb alloyMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 5 2004L. Thair Abstract Solution treatment and ageing (STA) is an effective strengthening method for , + , titanium alloys. This paper reports the effect of solution treatment and aging on the corrosion behaviour of Ti-6Al-7Nb alloy in a simulated body fluid (Ringer's solution). Ti-6Al-7Nb alloy is hot rolled in the , + , field and subjected to solution treatment above and below its beta transus temperature (1283 K). The solution treated specimens are water quenched (WQ), air-cooled (AC), and furnace cooled (FC) at three different rates, and subsequently aged at 823 K for 4 h. Microstructural changes were examined using optical microscopy and phases developed were analyzed using XRD. The influence of microstructure on the corrosion performance of the alloys are discussed in detail based on the Open Circuit Potential (OCP), passive current density and area of repassivation loop values obtained from the cyclic polarization study in Ringer's solution. The passive current density was low (0.5 ,A/cm2) for the specimen with duplex microstructure obtained for specimen solution treated at 1223 K, air-cooled, and aged, in comparison with that for as-rolled specimen (1.5 ,A/cm2). The corrosion aspects resulting from various heat treatments are discussed in detail. [source] Structure and Corrosion of Magnetron Sputtered Pure Mg Films on Silicon SubstratesPLASMA PROCESSES AND POLYMERS, Issue S1 2007Michael Störmer Abstract Physical vapor deposition (PVD) was used to prepare pure magnesium coatings on silicon substrates at various argon pressures and deposition angles. The film morphology was observed to depend on the deposition conditions. The approximately 3 µm thick Mg films exhibited columnar growth with voided boundaries and a fiber texture of the basal planes parallel to the substrate surface, which is typical of low temperature deposition. At low pressure and angle, the films were more compact, the surface roughness was lower, the texture was stronger, and the corrosion performance was improved. A free corrosion potential of ,1,735 mV and a corrosion rate of 335 µm per year were determined. [source] | ||||||||||