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Constant Concentration (constant + concentration)
Selected AbstractsThe emulsifying properties of a polysaccharide isolated from the fruit of Cordia abyssinicaINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 5 2004Mudadi Albert Nhamoiesu Benhura Summary Polysaccharide was isolated from Cordia abyssinica and its effect, at differing concentrations, on its emulsifying ability was determined. Emulsions of vegetable oil containing up to 1% of the polysaccharide in phosphate pH 7.4 buffer, were prepared by using a hand piston homogenizer. Emulsification was assessed by diluting samples of the emulsions in sodium dodecyl sulphate and measuring absorbance at 500 nm. Addition of increasing concentrations of the polysaccharide up to 1% enhanced emulsification and emulsion stability. Above 1% concentration the polysaccharide solutions were too viscous for making emulsions conveniently. At a constant concentration of the polysaccharide, addition of up to a 1% concentration of salt enhanced emulsion formation. Further addition of salt above 1% resulted in no further changes in emulsifying ability, but the stability of the emulsions formed decreased on increasing the concentration of salt above 1%. The effect of pH on emulsifying ability was investigated by preparing emulsions using buffers of different pH, from pH 3 to pH 13. The polysaccharide had poor emulsifying ability below pH 7. Emulsifying ability increased with pH between pH 7 and 11. At pH above 11 there was a decrease in emulsifying ability. [source] CONCENTRATION BOUNDARY CONDITIONS IN THE THEORETICAL ANALYSIS OF CONVECTIVE DRYING PROCESSJOURNAL OF FOOD PROCESS ENGINEERING, Issue 5 2007AHMET KAYA ABSTRACT In the theoretical analysis of convective drying process, two boundary conditions are common for concentration: constant concentration and convection. In this study, these two boundary conditions were comparatively examined by comparing theoretical results obtained with regard to experimental ones. Pumpkin (Cucurbita pepo) was considered as the product to be dried while air was the drying medium. The drying characteristics of pumpkin were determined for various values of drying air parameters, including temperature, velocity and relative humidity. Sorption isotherms of the dried pumpkin were also determined for different temperatures and water activities. The values of the effective moisture diffusivity, Deff, and the convective mass transfer coefficient, hm, were predicted, and these values were found to agree fairly well with those available in the existing literature. PRACTICAL APPLICATIONS Convective drying as well as other drying techniques are used in order to preserve and store agricultural products for longer periods by removing some of their moisture content. Drying is a complicated process involving simultaneous heat and mass transfer under transient conditions. Understanding the heat and mass transfer in the product will help to improve drying process parameters and hence the quality. [source] Inactivation Kinetics of Foodborne Spoilage and Pathogenic Bacteria by OzoneJOURNAL OF FOOD SCIENCE, Issue 3 2000J.-G. Kim ABSTRACT: Ozone was tested against Pseudomonas fluorescens, Escherichia coli O157:H7, Leuconostoc mesenteroides, and Listeria monocytogenes. When kinetic data from a batch reactor were fitted to a dose-response model, a 2-phased linear relationship was observed. A continuous ozone reactor was developed to ensure a uniform exposure of bacterial cells to ozone and a constant concentration of ozone during the treatment. Survivors plots in the continuous system were linear initially, followed by a concave downward pattern. Exposure of bacteria to ozone at 2.5 ppm for 40 s caused 5 to 6 log decrease in count. Resistance of tested bacteria to ozone followed this descending order: E. coli O157:H7, P. fluorescens, L. mesenteroides, and L. monocytogenes. [source] Ceric(IV) ion-induced graft copolymerization of acrylamide and ethyl acrylate onto cellulosePOLYMER INTERNATIONAL, Issue 2 2006Prof. Kailash C Gupta Abstract Graft copolymerization of acrylamide (AAm) and ethyl acrylate (EA) onto cellulose has been carried out from their binary mixtures using ceric ammonium nitrate (CAN) as an initiator in the presence of nitric acid at 25 ± 1 °C. The extent of acrylamide grafting increased in the presence of the EA comonomer. The composition of the grafted chains (FAAm = 0.52) was found to be constant during the feed molarity variation from 7.5 × 10,2 to 60.0 × 10,2 mol L,1, whereas the composition of the grafted chains (FAAm) was found to be dependent on feed composition (fAAm) and reaction temperature. The effects of ceric(IV) ion concentration, reaction time and temperature on the grafting parameters have been studied. The grafting parameters showed an increasing trend up to 6.0 × 10,3 mol L,1 concentration of CAN at a feed molarity of 30.0 × 10,2 mol L,1 and showed a decreasing trend on further increasing the concentration of CAN (>6.0 × 10,3 mol L,1) at a constant concentration of nitric acid (5.0 × 10,2 mol L,1). The composition of the grafted chains (FAAm) was determined by IR spectroscopy and nitrogen content and the data obtained then used to determine the reactivity ratios of the acrylamide (r1) and ethyl acrylate (r2) comonomers by using a Mayo and Lewis plot. The reactivity ratios of acrylamide and ethyl acrylate were found to be r1 = 0.54 and r2 = 1.10, respectively, and hence the sequence lengths of acrylamide (m,M1) and ethyl acrylate (m,M2) in the grafted chains are arranged in an alternating form, as the product of the reactivity ratios of acrylamide and ethyl acrylate (r1 × r2) is less than unity. The rate of graft copolymerization of the comonomers onto cellulose was found to be dependant on the ,squares' of the concentrations of the comonomers and on the ,square root' of the concentration of ceric ammonium nitrate. The energy of activation (,Ea) of graft copolymerzation was found to be 5.57 kJ mol,1 within the temperature range from 15 to 50 °C. On the basis of the results, suitable reaction steps have been proposed for the graft copolymerzation of acrylamide and ethyl acrylate comonomers from their mixtures. Copyright © 2005 Society of Chemical Industry [source] The effects of phosphatidylserine-dependent antiprothrombin antibody on thrombin generationARTHRITIS & RHEUMATISM, Issue 8 2009Yoshie Sakai Objective Antibodies to prothrombin (APTs) and to ,2 -glycoprotein I are the major autoantibodies responsible for lupus anticoagulant (LAC) activity. APTs comprise antibodies against prothrombin alone as well as antibodies against phosphatidylserine/prothrombin complex (anti-PS/PT), the latter being highly associated with the antiphospholipid syndrome (APS). The effect of anti-PS/PT on thrombin generation has not been elucidated, and the paradoxical effect of LAC (an anticoagulant in vitro, but a procoagulant in vivo) remains an enigma. The purpose of this study was to investigate the effects of anti-PS/PT on thrombin generation and to examine the LAC paradox. Methods We evaluated 36 anti-PS/PT,positive APS patients and 127 healthy subjects. Markers of in vivo thrombin/fibrin generation, including prothrombin fragment F1+2, thrombin,antithrombin III complex, soluble fibrin monomer, D -dimer, and fibrin degradation products, were measured. Mouse monoclonal anti-PS/PT antibody 231D was established, and its effects on in vitro thrombin generation were investigated by chromogenic assay. Results Significantly elevated levels of markers of thrombin/fibrin generation were observed in anti-PS/PT,positive patients, regardless of the presence or absence of anticardiolipin antibodies, as compared with healthy subjects. In the presence of low concentrations of human activated factor V (FVa), monoclonal antibody 231D increased thrombin generation in a dose-dependent manner. In contrast, when high concentrations of FVa were added, monoclonal antibody 231D decreased thrombin generation. Under a constant concentration of FVa, a high concentration of human FXa enhanced the effect of 231D. Conclusion The presence of anti-PS/PT greatly correlated with increased thrombin generation in APS patients. The in vitro effects of monoclonal antibody 231D on thrombin generation are "biaxial" according to the FVa/FXa balance. These data may serve as a clue to understanding the LAC paradox and the thrombogenic properties of anti-PS/PT. [source] Physicochemical factors controlling the release of dissolved organic carbon from columns of forest subsoilsEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2002J.-M. Münch Summary Retention of dissolved organic carbon in soil depends on the chemical and physical environment. We studied the release of organic carbon from three carbonate-free forest subsoil materials (Bs1, Bs2, Bg) in unsaturated column experiments as influenced by (i) variations of the flow regime and (ii) varied chemical properties of the irrigation solution. We investigated the effect of flow initiation, constant irrigation, interruptions to flow, and variation in the effective pore water velocity on the release of organic C. The influence of ionic strength and cation valence in the irrigation solution was studied by stepped pulses of NaCl and CaCl2. The release of C from all materials was characterized by an initial large output and a decline to constant concentrations under long-term irrigation. Interrupting the flow increased its release when flow was resumed. The release from the Bs1 material was not related to the duration of the interruption. The Bs2 material, in contrast, released organic carbon in a way that was successfully described by a kinetic first-order model. Increased pore water velocity decreased the concentrations of C in the effluent from it. The pH of the irrigation solution had negligible effects on the mobilization of C. Increased ionic strength reduced the release, whereas rinsing with distilled water increased the concentrations of C in the effluent. The response of dissolved C to pulses of weak solutions, however, was sensitive to the type of cation in the previous step with strong solutions. The results suggest that the release of organic matter in the soils depends on its colloidal properties. [source] Development and simulation studies of an unsteady state biofilter model for the treatment of cyclic air emissions of an ,-pinene gas streamJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 7 2005Christina Dirk-Faitakis Abstract This paper describes the development and simulation of an unsteady state biofilter model used to predict dynamic behaviour of cyclically-operated biofilters and compares it with experimental results obtained from three, parallel, bench-scale biofilters treating both periodically fluctuating concentrations and constant concentrations of an ,-pinene-laden gas stream. The dynamic model, using kinetic parameters estimated from the constant concentration biofilter, was able to predict the performance of cyclic biofilters operating at short cycle periods (ie, in the order of minutes and hours). Steady state kinetic data from a constant concentration biofilter can be used to predict unsteady state biofilter operation. At a 24 h cycle period, the dynamic model compared well with experimental results. For long cycle periods (ie, hours and days), removal efficiency decreased after periods of non-loading: the longer the period of non-loading, the poorer the biofilter's performance at the re-commencement of pollutant loading. At longer time scales the model did not effectively predict transient behaviour, as adsorption and changes in kinetic parameters were not accounted for. Modelling results showed that similar biofiltration performance for the cyclic and constant concentration biofiltration of ,-pinene is expected for biofilters operating solely in the first order kinetics regime. Poorer performance for cyclic biofilters following Monod kinetics spanning the entire kinetics range is expected as the cycle amplitude increases. The most important parameters affecting the performance of a cyclically-operated biofilter with short cycle periods are: amplitude of cyclic fluctuations, Cg, max/Cg, relative value of the half-saturation constant in the Monod expression, Ks, and effective diffusivity of ,-pinene in the biofilm, De. Copyright © 2005 Society of Chemical Industry [source] | ||||||||||