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Concentration C (concentration + c)
Selected AbstractsThe Electrochemical Behavior of ,-Ketoglutarate at the Hanging Mercury Drop Electrode in Acidic Aqueous Solution and Its Practical Application in Environmental and Biological SamplesELECTROANALYSIS, Issue 12 2004Li Yang Abstract The voltammetric behavior of ,-ketoglutarate (,-KG) at the hanging mercury drop electrode (HMDE) has been investigated in acetate buffer solution. Under the optimum experimental conditions (pH,4.5, 0.2,M NaAc-HAc buffer solution), a sensitive reductive wave of ,-KG was obtained by linear scan voltammetry (LSV) and the peak potential was ,1.18,V (vs. SCE), which was an irreversible adsorption wave. The kinetic parameters of the electrode process were ,=0.3 and ks=0.72,1/s. There was a linear relationship between peak current ip, ,-KG and ,-KG concentration in the range of 2×10,6,8×10,4,M ,-KG. The detection limit was 8×10,7,M and the relative standard deviation was 2.0% (C,-KG=8×10,4,M, n=10). Applications of the reductive wave of ,-KG for practical analysis were addressed as follows: (1) It can be used for the quantitative analysis of ,-KG in biological samples and the results agree well with those obtained from the established ultraviolet spectrophotometric method. (2) Utilizing the complexing effect between ,-KG and aluminum, a linear relationship holds between the decrease of peak current of ,-KG ,ip and the added Al concentration C in the range of 5.0×10,6,2.5×10,4,M. The detection limit was 2.2×10,6,M and the relative standard deviation was 3.1% (C=4×10,5,M, n=10). It was successfully applied to the detection of aluminum in water and synthetic biological samples with satisfactory results, which were consistent with those of ICP-AES. (3) It was also applied to study the effect of AlIII on the glutamate dehydrogenase (GDH) activity in the catalytically reaction of ,-KG+NH+NADH,L -glutamate+NAD++H2O by differential pulse polarography (DPP) technique. By monitoring DPP reductive currents of NAD+ and ,-KG, an elementary important result was found that Al could greatly affect the activity of GDH. This study could be attributed to intrinsic understanding of the aluminum's toxicity in enzyme reaction processes. [source] Dynamics of suspended sediment transport at field-scale drain channels of irrigation-dominated watersheds in the Sonoran Desert, southeastern CaliforniaHYDROLOGICAL PROCESSES, Issue 16 2007Peng Gao Abstract Suspended sediment is a major source of pollution in irrigation-dominated watersheds. However, little is known about the process and mechanisms of suspended sediment transport in drain channels directly connected to agricultural fields. This paper explains sediment dynamics using averaged 5 min flow discharge Q (m3 s,1) and suspended sediment concentration C (mg l,1) collected during one crop season in a small catchment containing a first-order drain channel and its connected six agricultural fields within the Salton Sea watershed. The statistical properties and average trends of Q and C were investigated for both early (i.e. November) and late (i.e. January) stages of a crop season. Further in-depth analysis on sediment dynamics was performed by selecting two typical single-field irrigation events and two multiple-field irrigation events. For each set of irrigation events, the process of suspended sediment transport was revealed by examining hydrograph and sediment graph responses. The mechanisms underlying suspended sediment transport were investigated by analysing the types of corresponding hysteresis loop. Finally, sediment rating curves for both hourly and daily data at early and late stages and for the entire crop season were established to seek possible sediment-transport predictive model(s). The study suggests that the complicated processes of suspended sediment transport in irrigation-dominated watersheds require stochastic rather than deterministic forecasting. Copyright © 2007 John Wiley & Sons, Ltd. [source] Polymer hydration and microphase decomposition in poly(N -vinylcaprolactam),water complexJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 4 2003Vassili Lebedev Poly(N -vinylcaprolactam) (PVCL) is a synthetic analogue of biomolecules (enzymes, proteins). It demonstrates a specific hydration and undergoes a coil,globule transition. The PVCL,D2O system (PVCL mass M = 106) has been investigated by small-angle neutron scattering (SANS) at T = 296,316,K to identify the structural features of the collapse at concentration C = 0.5,wt% near the threshold of the coil overlap. (The collapse leads to the segregation of the phase enriched with polymer at T > 305,K). The SANS experiments at q = 0.1,5,nm,1 (scales from monomer unit to globule gyration radius RG, 16,nm) have revealed a stretched coil,globule transformation in the range 305,309,K. Using high-resolution SANS (q = 0.002,0.02 nm,1) the globule association to form fractal structures (sponge-like) of surface dimension DF, 2.4,2.6 was examined. The coexistence of globules and disordered chains (regions ,5,10,nm) was found. The growth of the content of globular phase was induced by the conformational transition in disordered molecular fragments from coiled (dimension D, 1.8) to stretched chains (D, 1.2). [source] Sieving mechanisms in polymeric matricesELECTROPHORESIS, Issue 3 2003Anna Sartori Abstract A critical review of the existing theoretical models and experimental evidences for sieving mechanisms during separation of macromolecules, paying particular attention to capillary electrophoresis applications is presented. Gel models (Ogston and reptation) have been successfully applied to highly entangled polymer solutions, where fast and efficient separations can occur. In order to account for the DNA/polymers collision-interaction mechanisms during separation in dilute solutions , characterized by a poorer resolution ,, approximated analytical models have been developed. An insight in the mechanism regulating the intermediate case of moderately entangled polymer solutions, for low fields and concentrations of small multiples of the overlap concentration c*, is given by the constraint release approach. This model proposes an upper limit of size separation, increasing with matrix concentration and molecular mass. Finally, the coupling between the reptative motion of the analytes and the effect of matrix constraint release very likely plays a fundamental role in the separation mechanism and requires therefore further and deeper investigation, both theoretically and experimentally. [source] Rheology of polyurethane solutions with different solventsPOLYMER INTERNATIONAL, Issue 1 2002L de Vasconcelos Abstract Hard segment hydrogen bonding interactions in a particular polyurethane segmented copolymer have been analysed through a viscometric approach to determine the behaviour of polyurethane solutions with different solvent compositions. Analysis of log,,spversus log c[,] master curves (solely comprising dilute and semidilute regimes) showed that these systems could be differentiated by the slope of the first part of the curve (dilute regime), the characteristic reduced concentration c*[,], and the slope of the second part of the curve (semidilute regime), differences which were related to a possible occurrence of polymer aggregates. Experiments with solutions in the concentrated regime, at different temperatures, were used to relate non-Newtonian behaviour to hydrogen bonding. © 2001 Society of Chemical Industry [source] Ultrasonic Spectrometry of Aqueous Solutions of Alkyl Maltosides: Kinetics of Micelle Formation and Head-Group IsomerizationCHEMPHYSCHEM, Issue 15 2009Julian Haller Abstract At frequencies between 100 kHz and 400 MHz, ultrasonic attenuation spectra are measured at 25,°C for aqueous solutions of hexyl-, heptyl-, octyl-, nonyl-, and decyl-,- D -maltopyranoside as well as of decyl-,- D -maltopyranoside. The spectra with surfactant concentration c above the relevant critical micelle concentration (cmc) display three relaxation terms with discrete relaxation times. That with a relaxation time between 0.1 and 1.2 ,s is due to exchange of monomers between micelles and the suspending phase. It is discussed in the light of the Teubner,Kahlweit,Aniansson,Wall model of the formation/decay kinetics of systems with Gaussian size distribution of micelles. The relaxation parameters are compared to those for solutions of other non-ionic surfactants, such as alkyl monoglycosides and poly(ethylene glycol) monoalkyl ethers. At c
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