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Complex Fluorides (complex + fluoride)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

Mechanochemical Synthesis of Nano-Sized Complex Fluorides from Pair of Different Constituent Fluoride Compounds.

CHEMINFORM, Issue 14 2003
Jinfeng Lu
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Structure-forming components in crystals of ternary and quaternary 3d -metal complex fluorides

ACTA CRYSTALLOGRAPHICA SECTION B, Issue 3 2003
E. V. Peresypkina
Crystallochemical analysis and classification were performed for 139 ternary and quaternary complex fluorides with the general formula M1nM2mM3F6, belonging to 33 structure types. Using coordination sequences and the uniformity criterion the structure-forming ionic sublattices or their combinations were found, which are responsible for the formation of stable periodic frameworks. Analysis of structure-forming motifs allows the interpretation of the crystal structures of complex fluorides as close packings of F ions with M1, M2 and M3 cations, partially occupying tetrahedral and octahedral voids, or as the packings of [M3F6] complex ions with M1 and M2 countercations in the voids. Cationic sublattices are noted to play an essential role, while forming crystal structures of complex fluorides. Relationships between the composition of structure-forming sublattices, the composition of compounds, and the size and charge of ions belonging to the sublattices were analysed under normal conditions, with thermal and high-pressure polymorphic transitions. Rules were formulated to predict the crystal structures of complex fluorides with a given chemical composition. [source]