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Composite Polymer (composite + polymer)
Selected AbstractsFrom Molecular Machines to Microscale Motility of Objects: Application as "Smart Materials", Sensors, and NanodevicesADVANCED FUNCTIONAL MATERIALS, Issue 5 2007I. Willner Abstract Machinelike operations are common functions in biological systems, and substantial recent research efforts are directed to mimic such processes at the molecular or nanoscale dimensions. The present Feature Article presents three complementary approaches to design machinelike operations: by the signal-triggered mechanical shuttling of molecular components; by the signal-triggering of chemical processes on surfaces, resulting in mechanical motion of micro/nanoscale objects; and by the fuel-triggered motility of biomolecule,metal nanowire hybrid systems. The shuttling of molecular components on molecular wires assembled on surfaces in semirotaxane configurations using electrical or optical triggering signals is described. The control of the hydrophilic/hydrophobic surface properties through molecular shuttling or by molecular bending/stretching processes is presented. Stress generated on microelements, such as cantilevers, results in the mechanical deflection of the cantilever. The deposition of a redox-active polyaniline film on a cantilever allows the reversible electrochemically induced deflection and retraction of the cantilever by the electrochemical oxidation or reduction of the polymer film, respectively. A micro-robot consisting of the polypyrrole (PPy) polymer deposited on a multi-addressable configuration of electrodes is described. Au magnetic core/shell nanoparticles are incorporated into a polyaniline film, and the conductivity of the composite polymer is controlled by an external magnet. Finally, the synthesis of a hybrid nanostructure consisting of two actin filaments tethered to the two ends of a Au nanowire is described. The adenosine triphosphate (ATP)-fueled motility of the hybrid nanostructure on a myosin monolayer associated with a solid support is demonstrated. [source] Tailored composite polymer,metal nanoparticles by miniemulsion polymerization and thiol-ene functionalizationJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 7 2010Kim Y. van Berkel Abstract A simple and modular synthetic approach, based on miniemulsion polymerization, has been developed for the fabrication of composite polymer,metal nanoparticle materials. The procedure produces well-defined composite structures consisting of gold, silver, or MnFe2O4 nanoparticles (,10 nm in diameter) encapsulated within larger spherical nanoparticles of poly(divinylbenzene) (,100 nm in diameter). This methodology readily permits the incorporation of multiple metal domains into a single polymeric particle, while still preserving the useful optical and magnetic properties of the metal nanoparticles. The morphology of the composite particles is retained upon increasing the inorganic content and also upon redispersion in organic solvents. Finally, the ability to tailor the surface chemistry of the composite nanoparticles and incorporate steric stabilizing groups using simple thiol-ene chemistry is demonstrated. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1594,1606, 2010 [source] Marginal Adaptation of Cerec 3 CAD/CAM Composite Crowns Using Two Different Finish Line Preparation DesignsJOURNAL OF PROSTHODONTICS, Issue 3 2006Jaber Hussain Akbar DDS Purpose: The purpose of this study was to compare marginal discrepancies of Cerec 3 CAD/CAM composite crowns, fabricated on human prepared teeth with two different finish line designs, chamfer and shoulder. Materials and Methods: Sixteen human molar teeth were used to prepare full crowns. Eight teeth were prepared with a 1-mm-wide chamfer finish line and the other eight with a 1.2- to 1.5-mm circumferential shoulder. Cerec 3 crowns were fabricated from optical impressions using Paradigm MZ100 composite polymer. Marginal adaptation was evaluated in two ways: (1) using modified United States Public Health Service (USPHS) criteria to evaluate eight preselected sites on each crown margin, and (2) using scanning electron microscopy (SEM) to measure marginal gaps on all four axial walls with 15 measurements on each wall (60 measurements per crown). An evaluation of the number of acceptable crowns, determined by having all measured sites per tooth with margin gap size less than 100 ,m, as a function of finish line design was also conducted. Results: In both chamfer and shoulder groups, there were only two crowns (out of eight) with clinically acceptable ratings for all eight measurement sites according to USPHS criteria. Fisher's chi-square analysis showed that there was no statistically significant difference in marginal adaptability as a function of finish line design ( p > 0.05). With SEM imaging, overall mean marginal gaps for the chamfer group were 65.9 ± 38.7 ,m (range 35.0 to 130.0 ,m), and for the shoulder group were 46.0 ± 9.2 ,m (range 26.3 to 55.6 ,m); this difference was not found to be statistically significant ( p > 0.05). While crown assessment based on mean marginal discrepancy measurements indicated that both the chamfer and shoulder groups were considered clinically acceptable (<100 ,m); crown acceptability based on all measurement sites being less than 100 ,m indicated that in the chamfer and shoulder groups there were four and three acceptable crowns out of eight, respectively. The Fisher's chi-square test indicated no statistically significant difference between the groups ( p > 0.05). An agreement rate of 81.2% was calculated between the two evaluation methods, modified USPHS criteria and SEM measurements. Conclusions: Based on mean marginal discrepancy measurements, the typical marginal assessment technique, Cerec 3 Paradigm MZ100 crown restorations appear to have acceptable marginal adaptability (mean discrepancies <100 ,m). Thus, the evidence from this investigation would suggest that the finish line preparation design had no effect on marginal adaptation for Cerec 3 composite crowns. [source] A Novel Route to Multiphase Polymer Systems Containing Nano-Droplets: Radical Polymerization of Vinylic Monomers in Gelled Water-in-Oil MiniemulsionsMACROMOLECULAR MATERIALS & ENGINEERING, Issue 10 2005Christian Holtze Abstract Summary: A new strategy for the synthesis of composite polymers with larger volume fraction of aqueous inclusions less than 1 µm in diameter is presented. A water-in-oil miniemulsion of aqueous droplets in a continuous, cross-linkable monomer phase is prepared. The addition of an organo-gelator allows the immobilization of the droplets in a solid gel, thus avoiding the usual demixing upon polymerization of the continuous phase. This pregelled system is then converted into a composite polymer by photoinitiated free radical polymerization. Such coatings may be used for an improved climate control of buildings or as a deposit for the controlled release of actives from polar nano-droplets. SEM image of a cross-linked composite polymer showing controlled droplet inclusions with a maximal diameter of 500 nm. [source] | ||||||||||