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CO2 Separation (co2 + separation)

Distribution by Scientific Domains

Chemistry	50%

Selected Abstracts

Parametric study of chemical looping combustion for tri-generation of hydrogen, heat, and electrical power with CO2 capture

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 8 2005
J. Wolf
Abstract In this article, a novel cycle configuration has been studied, termed the extended chemical looping combustion integrated in a steam-injected gas turbine cycle. The products of this system are hydrogen, heat, and electrical power. Furthermore, the system inherently separates the CO2 and hydrogen that is produced during the combustion. The core process is an extended chemical looping combustion (exCLC) process which is based on classical chemical looping combustion (CLC). In classical CLC, a solid oxygen carrier circulates between two fluidized bed reactors and transports oxygen from the combustion air to the fuel; thus, the fuel is not mixed with air and an inherent CO2 separation occurs. In exCLC the oxygen carrier circulates along with a carbon carrier between three fluidized bed reactors, one to oxidize the oxygen carrier, one to produces and separate the hydrogen, and one to regenerate the carbon carrier. The impacts of process parameters, such as flowrates and temperatures have been studied on the efficiencies of producing electrical power, hydrogen, and district heating and on the degree of capturing CO2. The result shows that this process has the potential to achieve a thermal efficiency of 54% while 96% of the CO2 is captured and compressed to 110 bar. Copyright © 2005 John Wiley & Sons, Ltd. [source]

Recovery of CO2 with MEA and K2CO3 absorption in the IGCC system

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 6 2004
Baoqun Wang
Abstract Recovery of CO2 with monoethanolamine (MEA) and hot potassium carbonate (K2CO3) absorption processes in an integrated gasification combined cycle (IGCC) power plant was studied for the purpose of development of greenhouse gas control technology. Based on energy and exergy analysis of the two systems, improvement options were provided to further reduce energy penalty for the CO2 separation in the IGCC system. In the improvement options, the energy consumption for CO2 separation is reduced by about 32%. As a result, the thermal efficiency of IGCC system is increased by 2.15 percentage-point for the IGCC system with MEA absorption, and by 1.56 percentage-point for the IGCC system with K2CO3 absorption. Copyright © 2004 John Wiley & Sons, Ltd. [source]

Development of thin film composite for CO2 separation in membrane gas absorption application

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2009
A.L. Ahmad
Abstract The thin film composite (TFC) membrane based on polypropylene (PP) and polyvinylidenefluoride (PVDF) was prepared using glutaraldehyde as the selective layer. The percentages of glutaraldehyde were optimized to maximize the permeability of carbon dioxide (CO2) and selectivity as well. The TFC with 6% w/v of glutaraldehyde based on PVDF achieved the highest permeance of 881.70 GPU and 18.08 for selectivity through the increase in effective layer and skin layer thickness. This TFC promises to provide porous and hydrophobic membranes for use in membrane gas absorption (MGA) processes. The absorption of CO2 in deionized water was studied in MGA system in which the mass transfer coefficient (K) and CO2 flux decreased with increasing CO2 concentration in feed stream. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source]

A New Numerical Approach for a Detailed Multicomponent Gas Separation Membrane Model and AspenPlus Simulation

CHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 7 2005
M. H. Murad Chowdhury
Abstract A new numerical solution approach for a widely accepted model developed earlier by Pan [1] for multicomponent gas separation by high-flux asymmetric membranes is presented. The advantage of the new technique is that it can easily be incorporated into commercial process simulators such as AspenPlusTM [2] as a user-model for an overall membrane process study and for the design and simulation of hybrid processes (i.e., membrane plus chemical absorption or membrane plus physical absorption). The proposed technique does not require initial estimates of the pressure, flow and concentration profiles inside the fiber as does in Pan's original approach, thus allowing faster execution of the model equations. The numerical solution was formulated as an initial value problem (IVP). Either Adams-Moulton's or Gear's backward differentiation formulas (BDF) method was used for solving the non-linear differential equations, and a modified Powell hybrid algorithm with a finite-difference approximation of the Jacobian was used to solve the non-linear algebraic equations. The model predictions were validated with experimental data reported in the literature for different types of membrane gas separation systems with or without purge streams. The robustness of the new numerical technique was also tested by simulating the stiff type of problems such as air dehydration. This demonstrates the potential of the new solution technique to handle different membrane systems conveniently. As an illustration, a multi-stage membrane plant with recycle and purge streams has been designed and simulated for CO2 capture from a 500,MW power plant flue gas as a first step to build hybrid processes and also to make an economic comparison among different existing separation technologies available for CO2 separation from flue gas. [source]