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Chemical Character (chemical + character)
Selected AbstractsChemical modification of pyroclastic rock by hot water: an experimental investigation of mass transport at the fluid,solid interfaceGEOFLUIDS (ELECTRONIC), Issue 1 2009J. HARA Abstract Hydrothermal water,(pyroclastic) rock interactions were examined using flow-through experiments to deduce the effect of mass transport phenomena on the reaction process. A series of experiments were conducted over the temperature range 75,250°C, with a constant temperature for each experiment, and at saturated vapour pressure, to estimate the apparent rate constants as a function of temperature. Based on the chemistry of analysed solutions, the water,rock interaction in the experiments was controlled by diffusion from the reaction surface and by the existence of a surface layer at the rock,fluid interface, which regulated the chemical reaction rate. The reaction progress depended to a high degree on flow velocity and temperature conditions, with element abundances in the fluid significantly affected by these factors. Mass transport coefficients for diffusion from the rock surface to the bulk solution have been estimated. Ca is selectively depleted under lower temperature conditions (T < 150°C), whereas Na is greatly depleted under higher temperature conditions (T > 150°C), and K reaction rates are increased when flow velocity increases. Using these conditions, specific alkali and alkali earth cations were selectively leached from mineral surfaces. The ,surface layer' comprised a 0.5,1.8 mm boundary film on the solution side (the thickness of this layer has no dependence on chemical character) and a reaction layer. The reaction layer was composed of a Si, Al-rich cation-leached layer, whose thickness was dependent on temperature, flow velocity and reaction length. The reaction layer varied in thickness from about 10,4 to 10,7 mm under high temperature/low fluid velocity and low temperature/high fluid velocity conditions, respectively. [source] Hillslope-swamp interactions and flow pathways in a hypermaritime rainforest, British ColumbiaHYDROLOGICAL PROCESSES, Issue 15 2003D. F. Fitzgerald Abstract The process of water delivery to a headwater stream in a hypermaritime rainforest was examined using a variety of physical techniques and tracing with dissolved organic carbon (DOC) and the stable isotopes of water. Headwater swamps, often the major discharge zones for water draining off steep forest slopes, strongly affect the physical and chemical character of streamflow in the region. The headwater swamp selected for detailed investigation was sustained by relatively constant groundwater input from the steep colluvial slopes that maintained the water table above the ground surface. During significant storm events the water table rose quickly and the swamp expanded to engulf marginal pools that developed rapidly on the adjacent ground surfaces. The corresponding release of surface water directly to the stream typically comprised up to 95% of total stream discharge. The proportion of groundwater seepage to the stream by matrix flow (<1%) and via macropore-fed springs (up to 73%) increased during the recession period, but could not be sustained over the longer term. In more protracted drying periods, deep groundwater contributions to the stream were routed first to the headwater swamp. Dissolved organic carbon (DOC) in the stream, measured daily or more frequently during storm events, was found to be directly proportional to discharge, owing to the domination of DOC-rich headwater-swamp water sources. Although ,18O and ,2H composition of rainwater, groundwater and stream flow were found to be similar, deuterium excess (d ,2H , 8,18O) of water components was often found to be distinct, and suggested short water residence times of roughly 12 days for one event. Overall, observations of a typical headwater swamp reveal that the groundwater regime is dominated by rapid infiltration and short, emergent flow paths. With a relatively short turnover time, potential disturbances to the system by harvesting of upslope areas can be expected to occur rapidly. Forest managers can mitigate some of the harmful effects of logging operations by respecting the integrity of headwater wetland systems. The nature and magnitude of such perturbations will require further study. Copyright © 2003 John Wiley & Sons, Ltd. [source] Effect of coverage density and structure of chemically bonded silica stationary phases on the separation of compounds with various propertiesJOURNAL OF SEPARATION SCIENCE, JSS, Issue 6 2006Bogus, aw Buszewski Abstract The chemical character, geometry, and architecture of chemically formed surface layers determine interactions between stationary phase, analyte, and mobile phase, and therefore the retention mechanisms (partitioning, adsorption, ion exchange, steric exclusion) of separated analytes. These interactions also depend on the structure and chemical character of the solutes and the composition of the mobile phase. High-molecular-weight fullerenes (C60 and C70) and water-soluble selenium-containing peptides (833 and 2607 Da) were used for the evaluation of laboratory-prepared octadecyl stationary phases with high and low coverage density before and after end-capping. The aim of this work was to study differences in surface coverage density and homogeneity and conformational changes of chemically bonded moieties and the influence of these parameters on the separation of mixtures of selenopeptides and fullerenes with significantly different molecular masses. A topographical model of the chemically modified stationary surface is presented. [source] Combined XBIC/,-XRF/,-XAS/DLTS investigation of chemical character and electrical properties of Cu and Ni precipitates in siliconPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 8 2009M. Trushin The cover picture of this issue of Phys. Status Solidi C has been taken from the article [1]. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Medium molecular weight polar substances of the cuticle as tools in the study of the taxonomy, systematics and chemical ecology of tropical hover wasps (Hymenoptera: Stenogastrinae)JOURNAL OF ZOOLOGICAL SYSTEMATICS AND EVOLUTIONARY RESEARCH, Issue 2 2010David Baracchi Abstract The Stenogastrinae wasps have been proposed as a key group for an understanding of social evolution in insects, but the phylogeny of the group is still under discussion. The use of chemical characters, in particular cuticular hydrocarbons, for insect taxonomy is relatively recent and only a few studies have been conducted on the cuticular polar substances. In this work, we ascertain, by the matrix-assisted laser desorption ionization-time of flight mass spectrometry technique, that different species of primitively eusocial hover wasps have different compositions of the epicuticular polar compounds ranging from 900 to 3600 Da. General linear model analysis and discriminant analysis showed that the average spectral profiles of this fraction can be diagnostic for identification of the species. Moreover, for the first time we show population diversification in the medium MW polar cuticular mixtures in insects. In conclusion, the results demonstrate that the chemical characters are consistent with the physical characters and the study support the importance of medium MW polar substances as powerful tools for systematics (chemosystematics) and chemical ecology (fertility signal and population characterization) in a primitively social insect taxon. Riassunto Le vespe primitivamente eusociali della sottofamiglia delle Stenogastrinae sono state proposte come gruppo chiave per lo studio dell'evoluzione della socialità negli insetti. Ancora oggi, però, la filogenesi del gruppo rimane incerta e discussa. Sebbene l'uso dei caratteri chimici, e in particolare degli idrocarburi cuticolari, negli studi tassonomici sugli insetti sia ben noto, seppur di recente applicazione, sono ancora pochi gli studi condotti sulle sostanze cuticolari di natura polare. In questo lavoro abbiamo saggiato, mediante tecniche di spettrometria di massa (MALDI-TOF MS), la presenza di composti polari cuticolari di massa compresa tra i 900 e i 3600 (probabilmente provenienti dal veleno) sulla cuticola di alcune specie di vespe stenogastrine. Analisi statistiche multivariate hanno dimostrato che lo spettro medio dei profili chimici nel range da noi indagato può essere utilizzato per l'identificazione delle specie e la nostra ricerca propone questo metodo come un potente strumento non solo per studi di tassonomia (chemotassonomia) ma anche per studi di sistematica e di ecologia chimica (es. segnali di fertilità e differenze intra-popolazioni) nei taxon di insetti primitivamente eusociali. [source] The construction of web database server-client system for functional food factorsBIOFACTORS, Issue 1-4 2004Xing-Gang Zhuo Abstract In food, other than known nutrients, such as lipid, carbohydrate, protein, vitamins, and minerals, many substances with physiological function and medicinal action exist, and it is contributing to healthy improvement and/or prevention of illness. Although carotenoid, flavonoid and polyphenol, terpenoid, volatile substance and sulfur compounds, peptide, etc. have the function of illness prevention, and research of those non-nutrient functional food factors (FFF) became globally active, the research of this field is not yet done systematically. We evaluate function of FFF and reappraise known knowledge, and this knowledge is standardized and accumulated, aimed at building a web database server-client system which is easy to use for the people and nutritional research. We also collected related data such as chemical characters of FFF from literatures and other source, and formatted them into the database. We constructed the web database server-client system with MySQL database server and Apache web server based on Linux, and used Tomcat JSP engine for data connecting since they were reliable in stability and speed. We are opening the database at http://www.life-science.jp/FFF for test now. [source] | ||||||||||