Chloroaluminate Ionic Liquid (chloroaluminate + ionic_liquid)

Distribution by Scientific Domains
Chemistry100%

Selected Abstracts

ChemInform Abstract: Pechmann Reaction in Chloroaluminate Ionic Liquid.

CHEMINFORM, Issue 20 2002
Amit C. Khandekar
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]

Development of a Supported Ionic Liquid Phase (SILP) Catalyst for Slurry-Phase Friedel,Crafts Alkylations of Cumene

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 3 2009
J. Joni
Abstract A supported ionic liquid phase (SILP) catalyst material has been developed based on a silica support coated with an acidic chloroaluminate ionic liquid. Compared to the results in a liquid-liquid biphasic reaction these materials showed in the isopropylation of cumene a clearly different selectivity which was found to be related to a reduction of the ionic liquid's acidity by the untreated silica support. By pretreating the support with a defined amount of ionic liquid for neutralization and removal of surface hydroxy groups, a well defined, very active and also very selective SILP catalyst for slurry phase Friedel,Crafts alkylation was obtained. [source]

Biphasic oligomerization of ethylene with nickel complexes immobilized in organochloroaluminate ionic liquids

APPLIED ORGANOMETALLIC CHEMISTRY, Issue 11 2009
Lixia Pei
Abstract Ethylene was selectively oligomerized by nickel complexes such as (PPh3)2NiBr2 and (PPh3)2NiCl2 immobilized in chloroaluminate ionic liquid in biphasic catalytic reactions. The influence of reaction parameters such as reaction media, reaction temperature and Et2AlCl:Ni molar ratio was also evaluated. Turnover frequency up to 24000 mol C2H4/(mol Ni h) was achieved under mild reaction conditions (0.5 atm and 40 °C). GC-MS analyses showed that the obtained oligomers completely consist of C4 and C6. The olefinic products can be easily separated from the catalytic ionic liquid phase by simple decantation, and the nickel catalyst can be reused without a significant decrease in turnover frequency and change of the distribution of the olefinic products. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Electrodeposition of Metals and Semiconductors in Air- and Water-Stable Ionic Liquids

CHEMPHYSCHEM, Issue 1 2006
Sherif Zein El Abedin Prof. Dr.
Abstract In addition to their stability, the advantages of air- and water-stable ionic liquids over chloroaluminate ionic liquids, which were intensively investigated in the past, are that they are easy to dry, purify, and handle. Moreover, some of these ionic liquids have an extremely large electrochemical window of more than 5 V, and hence they give access to the electrodeposition of many metals and semiconductors, such as Ta, Ti, Si, and Ge. The results to date for the electrodeposition of metals and semiconductors in the most popular air- and water-stable ionic liquids are presented. [source]