|
| ||
|
|
||
Ceramic Powders (ceramic + powder)
Selected AbstractsThick Nb-Doped Bismuth Titanate Film with Controllable Grain OrientationJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2006Weiwu Chen In the current work, we reported a potential approach to obtain thick ceramic films with controllable grain orientation based on magnetic alignment and polymerization techniques. The slurry containing 40 vol% Bi4Ti2.96Nb0.04O12 (BINT) ceramic powder, monomer, initiator, and catalyst was drop coated on a Pt substrate and then moved into a vertical 10 T magnetic field. In 1,2 min, the ceramic particles were aligned by a strong magnetic force in slurry and then in situ locked by polymerization on the substrate. After sintering at 1000°C, a BINT ceramic film (50,80 ,m in thickness) with a highly a/b plane orientation was obtained. Theoretically, the grain orientation in the films can be easily controlled by adjusting the magnetic field direction. This approach is readily applicable to other materials with a non-cubic structure and is expected to facilitate the fast preparation of grain-oriented thick films. [source] Direct Ink-Jet Printing of Vertical WallsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2002Xinglong Zhao Direct jet printing can assemble ceramic powder into a three dimensional shape by firing droplets of ink through a nozzle to build a multiple layered structure. As with stereolithography and selective laser sintering, the surface texture is expected to witness the layered assembly. The ability to create vertical walls by direct ink-jet printing was explored using a test piece based on a maze. The structure and topography are discussed in terms of droplet spreading and drying. [source] Toughened Oxide Composites Based on Porous Alumina-Platelet InterphasesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 4 2001Sang-Jin Lee A novel mechanism for debonding at a weak interphase in an all-oxide composite is introduced. This methodology involves the use of alumina platelets that have a diameter of 10,15 or 5,10 ,m and a thickness of 1 ,m. The platelets induce constrained sintering of the ceramic powder, which results in permanent porosity. For room-temperature properties, only minor additions (0,3 vol%) of matrix powder yield sufficiently weak debonding interphases. The platelets lie in random, three-dimensional orientations and provide a debonding mechanism that is independent of temperature, in chemically compatible matrixes. Laminated composites with two types of matrixes,mullite and alumina,have been fabricated with modified fibrous monoliths of alumina in a triple-layer "core/interphase/matrix" arrangement. In the laminated systems, the intimate mixing of strong versus tough microstructures has been tailored by alternating various matrix:interphase thickness ratios. Preliminary load,displacement curves clearly demonstrate characteristics of "graceful failure" and notable improvements in the work of fracture. Scanning electron microscopic observation of the crack paths confirms the viability of platelets for producing permanently porous, debondable interphases at elevated temperatures in air. [source] Characterization of Powder Beds by Thermal Conductivity: Effect of Gas Pressure on the Thermal Resistance of Particle Contact PointsPARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, Issue 4 2004Michael Shapiro Abstract The thermal conductivity of ceramic powder packed beds was measured at temperatures below 100,°C for various powder sizes and compositions and under different gas atmospheres. Measurements at low pressures (down to 10,Pa) combined with a theoretical model allowed the elucidation of geometrical and thermal resistance parameters for the contact points between granules. The gap thickness and contact point size were found to be well correlated with the mean particle size. The thermal conductivities of all powders at low pressure were found to differ at most by a factor of two, whereas the solid-phase conductivities of the powder materials differed by more than one order of magnitude. A theoretical model accounting for the size-dependence of contact point conductivity is incorporated to rationalize this trend. [source] Polymeric composites for use in electronic and microwave devicesPOLYMER ENGINEERING & SCIENCE, Issue 3 2004Alexandre Moulart The dielectric and conductive properties of thermoplastic (ABS) composites filled with ceramic powder (barium titanate), conductive powders (carbon black, copper) and conductive fibers (carbon, steel) were investigated for use in electromagnetic crystals and microwave devices. Barium titanate/ABS composites were produced that had dielectric constants over 8 and loss tangents of 0.01, which are the requirements for electromagnetic crystals. Carbon black/ABS and steel fiber/ABS composites were obtained with conductivities suitable for electromagnetic shielding (over 10,3 S/cm). Fused decomposition modeling was tested as a method for building electromagnetic crystals and showed promising results. Polym. Eng. Sci. 44:588,597, 2004. © 2004 Society of Plastics Engineers. [source] Microwave-Assisted Hydrothermal Synthesis of Structurally and Morphologically Controlled Sodium Niobates by Using Niobic Acid as a PrecursorEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 8 2008Amauri J. Paula Abstract There are many advantages to using a microwave as a source of heat in hydrothermal reactions. Because it is a quick and homogeneous way to crystallize ceramic powders, it was used in this work for the production of antiferroelectric sodium niobate (NaNbO3) in a cubic-like form and its intermediary phase, disodium diniobate hydrate (Na2Nb2O6.H2O), with a fiber morphology. The syntheses were carried out by treating niobic acid (Nb2O5·nH2O) with NaOH. By changing the reaction time and the concentration of the reactants, particles with different structures and different morphologies could be obtained. The structural evolution of the products of this reaction was elucidated on the basis of the arrangement of the NbO6 octahedral units. Conclusive results were obtained with morphological and structural characterizations through XRD, TEM, MEV, and NMR and Raman spectroscopy. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source] Surface Activation of a Ferrimagnetic Glass,Ceramic for Antineoplastic Drugs GraftingADVANCED ENGINEERING MATERIALS, Issue 7 2010Enrica Vernè A ferrimagnetic glass,ceramic, belonging to the system SiO2,Na2O,CaO,P2O5,FeO,Fe2O3, has been studied as potential carrier for antineoplastic agents, in order to exploit the combination of hyperthermia and chemotherapy. Different material pre-treatments, such as ultrasonic washing, water, or simulated body fluid dipping, were evaluated to promote the surface activation of the glass,ceramic, i.e., the hydroxyl groups formation on it. X-ray photoelectron spectroscopy, scanning electron microscopy, energy dispersion spectrometry, and wettability measurements were performed to observe the samples surface modification. The best results in terms of free hydroxyl groups exposition were obtained by dipping the samples in distilled water for 7 days at 37,°C. Two different anticancer drugs were selected in order to test the reactivity of the activated surface: cisplatinum and doxorubicin. The uptake and release of doxorubicin and cisplatinum were evaluated on glass,ceramic powders, by using UV,Visible spectrometry and graphite furnace atomic absorption spectroscopy, respectively. After 1 day of uptake at 37,°C, the quantity of doxorubicin incorporated into the glass,ceramic is 77,±,7 wt%, while only 42,±,9.6 wt% of cisplatinum is grafted onto the material surface. For both antitumoral agents, the maximum drug release after soaking in aqueous solutions at 37,°C was obtained in few hours, with a randomly distributed kinetics trend. [source] Fabrication and Tunable Dielectric Properties of (Ba0.7Sr0.3)TiO3 -Glass-Based Thick-Film CapacitorsINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 2 2009Pulipparambil Vasu Divya Ferroelectric glass,ceramics of composition 0.90 (Ba0.7Sr0.3) TiO3,0.10(B2O3:SiO2) (0.90 BST:0.10 BS) synthesized by sol,gel method have been used for the preparation of dielectric thick-film inks. The particle dispersion of the glass,ceramic powders in the thick-film ink formulations have been studied through rheological measurements for fabricating thick-film capacitors by screen printing technique. The thick films derived from such glass,ceramics are found to sinter at considerably lower temperatures than the pure ceramic, and exhibit good dielectric characteristics with a tunability of 32% at 1 MHz under a dc bias field of 35 kV/cm. [source] Development of the powder reaction moulding processJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 3 2009Lei Zhao Abstract BACKGROUND: The powder reaction moulding process uses a reactive monomer as carrier and binder for the moulding of metal or ceramic powders. De-binding is achieved using thermal depolymerisation which is followed by sintering to give the finished component. Binder can be recovered for re-use. RESULTS: Moulding compounds, with various powder volume fractions, have been prepared using stainless steel, silicon nitride and alumina with n-butyl cyanoacrylate as binder, and the stability of the compounds established. Rheological properties of the compounds have been measured using both pressure flow and drag flow methods. Compounds are strongly pseudoplastic. Comparison of experimental results with theoretical models, describing suspension flow behaviour shows that experimental maximum volume fractions are close to the theoretical volume fraction of 0.42 for silicon nitride, 0.68 for alumina and 0.7 for stainless steel. Differential scanning calorimetry and thermogravimetry have been used to simulate de-binding and show a rapid loss of binder through depolymerisation. Post-sintering porosity of the ceramic materials is high but this is thought to arise from the low pressure moulding techniques used. Porosity of the stainless steel mouldings is much lower. CONCLUSIONS: The results validate the powder reaction moulding idea and demonstrate applicability to three widely different powder materials. Copyright © 2008 Society of Chemical Industry [source] Preparation of LiMn2O4 powders via spray pyrolysis and fluidized bed hybrid systemAICHE JOURNAL, Issue 7 2006Izumi Taniguchi Abstract A novel technique has been developed to directly produce fine ceramic powders from liquid solution using a spray pyrolysis and fluidized bed hybrid system. Using this technique, the preparation of lithium manganese oxides LiMn2O4, which are the most promising cathode materials for lithium-ion batteries, has been carried out for various superficial gas velocities U0 = 0.30-0.91 m/s, static bed heights Ls = 50-150 mm, and medium particle sizes dpm,g = 294-498 ,m. The resulting powders had spherical nanostructured particles that comprised primary particles with a few tens of nanometer in size, and they exhibited a pure cubic spinel structure without any impurities in the XRD patterns. Moreover, the as-prepared powders showed better crystallinity and smaller specific surface area than those by conventional spray pyrolysis. The effects of process parameters on powder properties, such as specific surface area and crystallinity, were investigated for a wide range of superficial gas velocities and static bed heights. An as-prepared sample was used as cathode active materials for lithium-ion batteries and the cell performance has been investigated. Test experiments in the electrochemical cell Li/1M LiClO4 in PC/LiMn2O4 demonstrated that the sample prepared by the present technique was superior to that by the conventional spray pyrolysis and solid-state reaction method. © 2006 American Institute of Chemical Engineers AIChE J, 2006 [source] Versatile Crack-Free Ceramic Micropatterns Made by a Modified Molding TechniqueJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 9 2010Marzellus Grosse Holthaus Crack-free ceramic micropatterns made of oxidic ceramic powders, e.g. alumina, titania, zirconia, and nonoxidic calciumphosphate ceramic powders were fabricated by a novel, simple, and low-cost modified micromolding (m-,M) technique via polydimethylsiloxane stamps. By means of this m-,M technique it is possible to fabricate monolithic ceramic bodies with a micropatterned surface with very high accuracy on surface detail. Our produced micropatterns can feature various geometries, e.g. cylinders, holes, channels, and struts with diameters ranging from 8 to 140 ,m in diameter or widths and from 8 to 30 ,m in depth or height. The oxidic and nonoxidic ceramic micropatterns could be removed from the molds and dried without any cracks. Even after sintering, these micropatterned samples showed no cracks or fissures. The reported technique has a very high potential for fully automatized up-scale fabrication of micropatterned ceramic surfaces. [source] Fabrication of Millimeter-Wave Electromagnetic Bandgap Crystals Using Microwave Dielectric PowdersJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2009Xuesong Lu Electromagnetic bandgap (EBG) structures active in the 90,110 GHz region widely used by security imaging radar were created using different ceramics by a rapid prototyping method informed by finite difference time domain modeling. This solid free-forming method uses a high volatility solvent-based ceramic paste extruded through fine nozzles allowing ceramic powders to be assembled on a multiaxis building platform avoiding machining, etching, or the alignment of loose rods and created to designs downloaded directly from a computer file. Lattices were made from two high dielectric constant ceramics: La(Mg0.5, Ti0.5)O3 and (Zr0.8, Sn0.2)TiO4 and compared with those of Al2O3 demonstrating three EBG structures with different dimensions and dielectric constants but with the same bandgap. The effects of manufacturing tolerances on bandgap frequency are investigated by simulation. [source] Emission of Pollutants from Glycine,Nitrate Combustion Synthesis ProcessesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 12 2007Thomas Pine Four ceramic powders were produced using the glycine,nitrate process: lanthanum-doped barium cobaltite, ceria, magnesia, and strontium-doped lanthanum chromite (LSC). Glycine-to-nitrate ratios from 0.25 to 1 were investigated. During the combustion synthesis process, careful collection of process off-gas was followed by detailed gas analyses to determine product gas composition. All of the synthesis processes produced pure phase ceramic powders, but also produced criteria pollutant emissions levels that were significant enough (up to 4500 ppm of NOx and 9000 ppm of carbon monoxide) to warrant consideration. Equilibrium and chemical kinetic computations are used to determine the implications of the current findings. [source] Synthesis and Characterization of Nanoscaled Cerium (IV) Oxide via a Solid-State Mechanochemical MethodJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 3 2006Jun Lu Solid-state reactions have the potential for direct preparation of ceramic powders and offer a low-temperature and low-cost alternative to conventional techniques for production of oxide powders. This paper describes a simple and effective mechanochemical method based on solid-state reactions during ball milling for synthesis of nanoscaled ceria (CeO2) particles. By using an organic base instead of an inorganic base, metal-ion-free nanoscaled CeO2 can also be made. The effects of annealing temperature on particle sizes and lattice strain are investigated. The results show that the average particle sizes of the particles increases and the average crystal lattice distortion decreases with the annealing temperature. Transmission electron microscopy examinations demonstrate that the CeO2 particles synthesised by this method are near-spherical shaped. [source] Determination of the Thermal Resistance of the Polymer,Ceramic Interface of Alumina-Filled Polymer CompositesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2004Richard F. Hill To model the thermal conductivity of polymer composites that are filled with ceramic powders, the conductivity of each component as well as the interfacial resistance at each ceramic,polymer boundary must be known. An indirect method to determine this interfacial boundary resistance is proposed by preparing large-scale "macromodel" simulations of the polymer,ceramic interface. Macromodels, prepared by spin-coating a polymer layer onto sapphire wafers, were formed in a sapphire,polymer,sapphire sandwich type structure. The interfacial boundary thermal resistance was calculated from thermal resistance measurements made on the macromodels. [source] Silicon Nitride Colloidal Probe Measurements: Interparticle Forces and the Role of Surface-Segment Interactions in Poly(acrylic acid) Adsorption from Aqueous SolutionJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2001Eric Laarz Direct measurements of forces between silicon nitride surfaces in the presence of poly(acrylic acid) (PAA) are presented. The force-distance curves were obtained at pH > pHiep with an atomic force microscopy (AFM) colloidal-probe technique using a novel spherical silicon nitride probe attached to the AFM cantilever. We found that PAA adsorbs onto the negatively charged silicon nitride surface, which results in an increased repulsive surface potential. The steric contribution to the interparticle repulsion is small and the layer conformation remains flat even at high surface potentials or high ionic strength. The general features of the stabilization of ceramic powders with PAA are discussed; we suggest that PAA adsorbs onto silicon nitride by sequential adsorption of neighboring segments ("zipping"), which results in a flat conformation. In contrast, the long-range steric force found in the ZrO2/PAA system at pH > pHiep arises because the stretched equilibrium bulk conformation of the highly charged polymer is preserved via the formation of strong, irreversible surface-segment bonds on adsorption. [source] Preparation of Ba6,3xNd8+2xTi18O54 via Ethylenediaminetetraacetic Acid PrecursorJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2000Yebin Xu Ba6,3xNd8+2xTi18O54 ceramic powders were synthesized by the modified Pechini method using ethylenediaminetetraacetic acid (EDTA) as a chelating agent. A purplish red, molecular-level, homogeneously mixed gel was prepared, and transferred into a porous resin intermediate through charring. Single-phase and well-crystallized Ba6,3xNd8+2xTi18O54 powders were obtained from pulverized resin at a temperature of 900°C for 3 h, without formation of any intermediate phases. Meanwhile, the molar ratio of EDTA to total metal cation concentration had a significant influence on the crystallization behavior of Ba6,3xNd8+2xTi18O54. The Ba6,3xNd8+2xTi18O54 (x= 2/3) ceramics prepared via EDTA precursor have excellent microwave dielectric characteristics: ,= 87, Qf= 8710 GHz. [source] Low-Temperature Synthesis of Bismuth Titanate Niobate (Bi7Ti4NbO21) Nanoparticles from a Metal-organic Polymeric PrecursorJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 5 2000Pedro Durán This paper describes the preparation of homogeneous Bi7Ti4NbO21 single-phase ceramic powders of ,55 nm crystallite size, at temperatures as low as 400°,500°C using a metal citrate complex method based on the Pechini-type reaction route. The thermal decomposition/oxidation of the polymerized resin, as investigated by TG/DTA, XRD, and SEM, led to the formation of a well-defined orthorhombic Bi7Ti4NbO21 compound with lattice parameters a= 0.544, b= 0.540, and c= 2.905 ± 0.0005 nm. Reaction takes place through an intermediate binary phase with a stoichiometry close to Bi20TiO32 which forms between 300° and 375°C. The metal-organic precursor synthesis method, where Bi, Ti, and Nb ions are first chelated to form metal complexes and then polymerized to give a gel, allows control of the Bi/Ti/Nb stoichiometric ratio leading to the rapid formation of nanosized bismuth titanate niobate (Bi7Ti4NbO21) ceramic powders, at temperatures much lower than usually needed by conventional processing of mixed-oxide powders. [source] Fabrication of multilayer ceramic membranesASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2009V.V. Zyryanov Abstract The development of multilayer mixed conducting oxide membranes on macroporous dead-end tubular composite glass/ceramic substrates is presented. Sol modification of glass/ceramic substrate enhances the performance of catalytic membrane reactor (CMR) with reduced thickness of ceramic layers. The shrinkage misfit between support and ceramic layers can be regulated by different processing steps including sol modification of substrate and preliminary annealing of ceramic powders. Nanopowders of compatible complex perovskites as membrane materials were obtained by mechanochemical synthesis. Porous and dense ceramic layers were supported onto the internal wall of substrate by slip casting of slurries comprised of the narrow fractions of agglomerated powders dispersed in organic media with addition of surfactants. For SrFeO3 -based dense perovskite ceramics, both dynamics of oxygen loss at high temperatures and mechanical properties were found to be affected by the presence of SrSO4 surface inclusions formed due to sulfur admixture in starting reactants. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] | |||||||||||||||||||||||||