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Ceramic Membranes (ceramic + membrane)
Selected AbstractsRecovery of Homogeneous Polyoxometallate Catalysts from Aqueous and Organic Media by a Mesoporous Ceramic Membrane without Loss of Catalytic ActivityCHEMISTRY - A EUROPEAN JOURNAL, Issue 11 2006Sankhanilay Roy Chowdhury Dr. Abstract The recovery of homogeneous polyoxometallate (POM) oxidation catalysts from aqueous and non-aqueous media by a nanofiltration process using mesoporous ,-alumina membranes is reported. The recovery of Q12[WZn3(ZnW9O34)2] (Q=[MeN(n -C8H17)3]+) from toluene-based media was quantitative within experimental error, while up to 97,% of Na12[WZn3(ZnW9O34)2] could be recovered from water. The toluene-soluble POM catalyst was used repeatedly in the conversion of cyclooctene to cyclooctene oxide and separated from the product mixture after each reaction. The catalytic activity increased steadily with the number of times that the catalyst had been recycled, which was attributed to partial removal of the excess QCl that is known to have a negative influence on the catalytic activity. Differences in the permeability of the membrane for different liquid media can be attributed to viscosity differences and/or capillary condensation effects. The influence of membrane pore radius on permeability and recovery is discussed. [source] Ceramic Membranes: Microstructural Engineering of Hydroxyapatite Membranes to Enhance Proton Conductivity (Adv. Funct.ADVANCED FUNCTIONAL MATERIALS, Issue 24 2009Mater. The inside cover image showns a side view of a hydroxyapatite membrane with aligned crystal domains synthesized as described by Liu et al. on page 3941. The microstructure of the membrane is engineered to promote proton transport through orientation of the proton conducting paths. These novel structures have significantly higher proton conductivity than traditional hydroxyapatite ceramics and may offer improved performance in intermediate temperature fuel cells. [source] Untersuchungen zum Hochdruck-Permeationsverhalten reiner Gase durch mikroporöse keramische Membranen Teil 1.CHEMIE-INGENIEUR-TECHNIK (CIT), Issue 10 2010Messmethode und Einfluss der Adsorption auf den Permeatfluss. Adsorption; Ceramic membrane; Gas permeation; Testing method Abstract Zwei asymmetrische keramische Membranen wurden getestet: eine mesoporöse ZrO2 -Membran mit einem Porendurchmesser von 3,nm und eine mikroporöse TiO2 -Membran mit 0,9,nm Porendurchmesser. Der Permeatfluss reiner Gase bei 293,,,373,K und 1,,,10,MPa wurde mittels statischer und dynamischer Messmethoden gemessen, wobei beide Methoden übereinstimmende Ergebnisse lieferten. The permeation behaviour of single gases (He, H2, N2, Ar, CH4, CO2) through meso (ZrO2) and micro (TiO2) porous ceramic membranes was measured within a pressure range of 1,to 10,MPa and a temperature range of 293,to 373 K, using steady state and dynamic experimental methods. The TiO2 -membrane shows by adsorption affected permeation, whereas the ZrO2 -membrane is not influenced by these effects. [source] Ultrathin polymeric interpenetration network with separation performance approaching ceramic membranes for biofuelAICHE JOURNAL, Issue 1 2009Lan Ying Jiang Abstract Biofuel has emerged as one of the most strategically important sustainable fuel sources. The success of biofuel development is not only dependent on the advances in genetic transformation of biomass into biofuel, but also on the breakthroughs in separation of biofuel from biomass. The "separation" alone currently accounts for 60,80% of the biofuel production cost. Ceramic membranes made of sophisticated processes have shown separation performance far superior to polymeric membranes, but suffers fragility and high fabrication cost. We report the discovery of novel molecular engineering and membrane fabrication that can synergistically produce polymeric membranes exhibiting separation performance approaching ceramic membranes. The newly discovered Polysulfone/Matrimid composite membranes are fabricated by dual-layer coextrusion technology in just one step through phase inversion. An ultrathin dense-selective layer made of an interpenetration network of the two materials with a targeted and stable interstitial space is formed at the interface of two layers for biofuel separation. The combined molecular engineering and membrane fabrication approach may revolutionize future membrane research and development for purification and separation in energy, environment, and pharmaceuticals. © 2008 American Institute of Chemical Engineers AIChE J, 2009 [source] Ceramic membranes for ammonia recoveryAICHE JOURNAL, Issue 6 2006Olivier Camus Abstract An extensive screening program has been performed to find a suitable membrane configuration and operating conditions for the effective recovery of ammonia from the syngas loop. All the experiments have been performed at steady state. MFI zeolite membranes in tubular and multi-channel fiber configurations have been tested along with tubular silica membranes. At 80°C, a high ammonia permeance (2.1 × 10,7 mol.m,2.s,1.Pa,1), and a selectivity of about 10 were found with the tubular zeolite membrane, whereas for the silica membrane an even higher ammonia permeance was measured (7.6 x 10,7 mol.m,2.s,1.Pa,1) with a selectivity of about 7. For both silica and zeolite membranes, the selectivity was found to increase with increasing temperature up to 80°C. This is a combined effect of weaker adsorption of ammonia and increased diffusion at higher temperature. The results have been modeled using both the well-mixed reactor and the log mean pressure difference approaches. To overcome their limitations in addressing changes in feed concentration along the membrane surface, a segmental model has been used to obtain suitable operating conditions and membrane areas required for an industrial application. © 2006 American Institute of Chemical Engineers AIChE J, 2006 [source] Evaluation of mixed-conducting lanthanum-strontium-cobaltite ceramic membrane for oxygen separationAICHE JOURNAL, Issue 10 2009Lei Ge Abstract In this study, La0.4Sr0.6CoO3-, (LSC) oxide was synthesized via an EDTA-citrate complexing process and its application as a mixed-conducting ceramic membrane for oxygen separation was systematically investigated. The phase structure of the powder and microstructure of the membrane were characterized by XRD and SEM, respectively. The optimum condition for membrane sintering was developed based on SEM and four-probe DC electrical conductivity characterizations. The oxygen permeation fluxes at various temperatures and oxygen partial pressure gradients were measured by gas chromatography method. Fundamental equations of oxygen permeation and transport resistance through mixed conducting membrane were developed. The oxygen bulk diffusion coefficient (Dv) and surface exchange coefficient (Kex) for LSC membrane were derived by model regression. The importance of surface exchange kinetics at each side of the membrane on oxygen permeation flux under different oxygen partial pressure gradients and temperatures were quantitatively distinguished from the oxygen bulk diffusion. The maximum oxygen flux achieved based on 1.6-mm-thick La0.4Sr0.6CoO3-, membrane was ,4.0 × 10,7 mol cm,2 s,1at 950°C. However, calculation results show theoretical oxygen fluxes as high as 2.98 × 10,5 mol cm,2 s,1 through a 5-,m-thick LSC membrane with ideal surface modification when operating at 950°C for air separation. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Microporous Niobia,Silica Membrane with Very Low CO2 PermeabilityCHEMSUSCHEM CHEMISTRY AND SUSTAINABILITY, ENERGY & MATERIALS, Issue 5 2008Vittorio Boffa Dr. Abstract A sol,gel-derived microporous ceramic membrane with an exceptionally low permeability for CO2 from gaseous streams was developed and characterized. The sols were prepared from a mixture of niobium and silicon alkoxide precursors by acid-catalyzed synthesis. Microporous films were formed by coating asymmetric ,-alumina disks with the polymeric sol (Si/Nb=3:1), followed by calcination at 500,°C. The membrane consists of a 150-nm-thick layer with a Si/Nb atomic ratio of about 1.5. The single-gas permeance of small gas molecules such as H2, CH4, N2, and SF6 decreases steadily with kinetic diameter. Hydrogen, helium, and carbon dioxide follow an activated transport mechanism through the membrane. The permeance of CO2 in this membrane is much lower than that in pure silica, and its behavior deviates strongly from the general trend observed with the other gases. This is attributed to a relatively strong interaction between CO2 and adsorption sites in the niobia,silica membrane. [source] CLARIFICATION AND PURIFICATION OF AQUEOUS STEVIA EXTRACT USING MEMBRANE SEPARATION PROCESSJOURNAL OF FOOD PROCESS ENGINEERING, Issue 3 2009M.H.M. REIS ABSTRACT Stevia rebaudiana Bertoni is a native plant from South America and its active constituents have been considered the "sweeteners of the future."Stevia is a natural diet-sweetening source, safe to health and without calories. However, the obtained raw extract is foul smelling, bitter tasting, dark brown colored, and presents suspension matter due to organic and inorganic compounds. Therefore, further purification/clarification is essential in order to get a product of commercial quality. In this work ceramic membranes were applied in the stevia extract clarification process. The process was carried out under different membrane pore sizes and at different pressure values. The best clarification result was obtained with the membrane of 0.1 µm at 4 bar. On the other hand, the best condition for the flux was obtained with the membrane of 0.2 µm at 6 bar. The process with all the tested membranes and conditions achieved recovery of sweeteners higher than 90%. Finally, a filtration mathematical model was applied to describe the flux behavior, showing that the main fouling phenomenon during the process occurred because of the complete blocking of pores. PRACTICAL APPLICATION Stevia is the world's only all-natural sweetener with zero calories, zero carbohydrates and a zero glycemic index. However, the obtained stevia extract has a dark brown appearance, mainly because of the presence of impurities. In this work the membrane separation process was studied for stevia extract clarification and purification in order to get a product with higher commercial acceptability. The obtained results showed that total clarification and recuperation of sweeteners was almost achieved. Nonetheless, membrane fouling is an inevitable problem during membrane filtration. The mathematical analysis of the fouling occurrences showed that the complete blocking of pores is the main cause for the membrane permeability decrease. [source] Analysis of clogging behaviors of diatomaceous ceramic membranes during membrane filtration based upon specific depositAICHE JOURNAL, Issue 7 2010Eiji Iritani Abstract Fouling behaviors in membrane filtration of dilute suspension of polystyrene latex (PSL) were examined under constant-pressure conditions using diatomaceous ceramic membranes which are semi-permeable to the PSL. Flux decline behaviors were evaluated in consideration of the effect of the solid permeation through the membrane. The conventional characteristic filtration equation was modified by applying the Kozeny-Carman equation to the filtrate flow through the membrane pores. In the model, the porosity and specific surface area of the membrane were represented by unique functions of the solid deposit retained in the membrane pores. The variations of the filtration rate and filtrate volume with the filtration time were accurately described based upon the modified characteristic filtration equation. It was revealed that the extent of the membrane blocking per unit deposit load increased with the decrease in the pore size of the membrane and with decreasing pressure, but was little influenced by the suspension concentration. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Ultrathin polymeric interpenetration network with separation performance approaching ceramic membranes for biofuelAICHE JOURNAL, Issue 1 2009Lan Ying Jiang Abstract Biofuel has emerged as one of the most strategically important sustainable fuel sources. The success of biofuel development is not only dependent on the advances in genetic transformation of biomass into biofuel, but also on the breakthroughs in separation of biofuel from biomass. The "separation" alone currently accounts for 60,80% of the biofuel production cost. Ceramic membranes made of sophisticated processes have shown separation performance far superior to polymeric membranes, but suffers fragility and high fabrication cost. We report the discovery of novel molecular engineering and membrane fabrication that can synergistically produce polymeric membranes exhibiting separation performance approaching ceramic membranes. The newly discovered Polysulfone/Matrimid composite membranes are fabricated by dual-layer coextrusion technology in just one step through phase inversion. An ultrathin dense-selective layer made of an interpenetration network of the two materials with a targeted and stable interstitial space is formed at the interface of two layers for biofuel separation. The combined molecular engineering and membrane fabrication approach may revolutionize future membrane research and development for purification and separation in energy, environment, and pharmaceuticals. © 2008 American Institute of Chemical Engineers AIChE J, 2009 [source] Modeling of air separation in a LSCF hollow-fiber membrane moduleAICHE JOURNAL, Issue 7 2002Xiaoyao Tan Mixed ion-conducting ceramic membranes are promising in oxygen separation from air due to their infinite permselectivity. Hollow-fiber-shaped membranes can provide a high surface area for such an application. A mathematical model for a hollow-fiber La0.6Sr0.4Co0.2F0.8O3,,(LSCF) membrane module for air separation was developed and a performance of the module at various operating conditions was studied theoretically. The simulation results reveal that the cocurrent is a better operating flow pattern than the countercurrent flow pattern. The vacuum operation on the lumen side of the membrane module is preferable to the elevated pressure operation on the shell side for achieving high oxygen productivity. A high vacuum level and a desired membrane area are essential to produce the pure oxygen and nitrogen simultaneously. Experimental results and kinetic parameters in the literature obtained from the LSCF membrane for air separation agreed satisfactorily with the theoretical solutions. [source] Indirect Raman identification of the proton insertion in the high-temperature [Ba/Sr][Zr/Ti]O3 -modified perovskite protonic conductors,JOURNAL OF RAMAN SPECTROSCOPY, Issue 5 2009Aneta Slodczyk Abstract OH, and H3O+ species in hydrates and simple oxides are rather well characterised from their IR, Raman and inelastic neutron points of view. For the H+ (H2O) species in solid state the variability is well established and assignment remains discussed. The question of the vibrational signature of isolated proton (e.g. the ionic proton, a proton sharing its interaction with more than two acceptors) and its dynamic nature (proton gas, polaron,,) is open. H+ -containing modified perovskites A(Ba,Sr,,) B(Zr,Ce,Ti,,) O3 are potential ceramic membranes for fuel cell and medium temperature water electrolysis (300,800 °C). Comparison studies of the protonated and non-protonated lanthanide/rare earth-modified perovskites of type Ba(Sr)Zr(Ti)O3 as well as Al-modified BaTiO3 show that a broad component centred at 2500 cm,1 is observed after ,proton insertion'. Its intensity is correlated to the protonic species content as well as to the conductivity of the materials. The mixed nature of this feature is discussed: fluorescence related to the dangling bonds, A, B, C bands or new phenomena related to the ionic protons and associated electronic defect. Copyright © 2008 John Wiley & Sons, Ltd. [source] From Chelating Precursor to Perovskite Oxides and Hollow Fiber MembranesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 1 2007S. Liu Perovskite Ba0.5Sr0.5Co0.8Fe0.2O3-, (BSCF) is a promising mixed-conducting ceramic membrane material in addition to being a good electrode catalyst for solid oxide fuel cells. In this study, BSCF powder was synthesized via a chelated water-soluble complex method at relatively low temperatures. The combined ethylenediaminetetraacetic acid and citric acid was used for the synthesis of a complex-based precursor, followed by thermal decomposition of the precursor at high temperatures. Thermal behavior, crystal phases, and structures of the prepared powders were characterized by thermogravimetric analysis/differential scanning calorimetry, XRD, and scanning electron microscopic (SEM) techniques, respectively. Pure and single-phase perovskite could be obtained after sintering at a temperature higher than 800°C for 5 h. The soft precursor powder synthesized at lower temperatures, i.e., 600°C, is water insoluble and more appropriate for use as a membrane material to prepare gas-tight tubular or hollow fiber ceramic membranes. By contrast, the hollow fibers prepared via the traditional techniques where the perovskite powder is used as the starting membrane materials display gas leakage. The fibers were characterized by SEM, XRD, and tested for air separation at ambient pressure and temperatures between 700° and 950°C. The oxygen flux measured in this work reached 3.90 mL·(min·cm2),1 and compares favorably with any experimental values reported in the open literature. [source] Fabrication of multilayer ceramic membranesASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2009V.V. Zyryanov Abstract The development of multilayer mixed conducting oxide membranes on macroporous dead-end tubular composite glass/ceramic substrates is presented. Sol modification of glass/ceramic substrate enhances the performance of catalytic membrane reactor (CMR) with reduced thickness of ceramic layers. The shrinkage misfit between support and ceramic layers can be regulated by different processing steps including sol modification of substrate and preliminary annealing of ceramic powders. Nanopowders of compatible complex perovskites as membrane materials were obtained by mechanochemical synthesis. Porous and dense ceramic layers were supported onto the internal wall of substrate by slip casting of slurries comprised of the narrow fractions of agglomerated powders dispersed in organic media with addition of surfactants. For SrFeO3 -based dense perovskite ceramics, both dynamics of oxygen loss at high temperatures and mechanical properties were found to be affected by the presence of SrSO4 surface inclusions formed due to sulfur admixture in starting reactants. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Fuel Cells, Advanced Reactors and Smart Catalysis: The Exploitation of Ceramic Ion-Conducting MembranesCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 8 2003I.S. Metcalfe Abstract Membrane reactors are of great interest in the chemical industries because they offer the possibility of improved yields, improved selectivities and more compact plant. However, a significant barrier to their uptake is the unavailability of membrane systems having the required performance at an acceptable cost. In this paper we will explore the use of one class of membrane that has the potential to deliver high performance at reasonable cost. Ion-conducting ceramic membranes can be used in a wide range of high temperature applications including fuel cells, advanced reactors and even smart catalytic systems. [source] Untersuchungen zum Hochdruck-Permeationsverhalten reiner Gase durch mikroporöse keramische Membranen Teil 1.CHEMIE-INGENIEUR-TECHNIK (CIT), Issue 10 2010Messmethode und Einfluss der Adsorption auf den Permeatfluss. Adsorption; Ceramic membrane; Gas permeation; Testing method Abstract Zwei asymmetrische keramische Membranen wurden getestet: eine mesoporöse ZrO2 -Membran mit einem Porendurchmesser von 3,nm und eine mikroporöse TiO2 -Membran mit 0,9,nm Porendurchmesser. Der Permeatfluss reiner Gase bei 293,,,373,K und 1,,,10,MPa wurde mittels statischer und dynamischer Messmethoden gemessen, wobei beide Methoden übereinstimmende Ergebnisse lieferten. The permeation behaviour of single gases (He, H2, N2, Ar, CH4, CO2) through meso (ZrO2) and micro (TiO2) porous ceramic membranes was measured within a pressure range of 1,to 10,MPa and a temperature range of 293,to 373 K, using steady state and dynamic experimental methods. The TiO2 -membrane shows by adsorption affected permeation, whereas the ZrO2 -membrane is not influenced by these effects. [source] | |||||||||||||